David K. Hamara

The Major-Element Composition of Mercury’s Surface from MESSENGER X-ray Spectrometry

Geochemical data show that the major rock-forming components of Mercury are characterized by high sulfur content. X-ray fluorescence spectra obtained by the MESSENGER spacecraft orbiting Mercury indicate that the planet’s surface differs in composition from those of other terrestrial planets. Relatively high Mg/Si and low Al/Si and Ca/Si ratios rule out a lunarlike feldspar-rich crust. The sulfur abundance is at least 10 times higher than that of the silicate portion of Earth or the Moon, and this observation, together with a low surface Fe abundance, supports the view that Mercury formed from highly reduced precursor materials, perhaps akin to enstatite chondrite meteorites or anhydrous cometary dust particles. Low Fe and Ti abundances do not support the proposal that opaque oxides of these elements contribute substantially to Mercury’s low and variable surface reflectance.

Evidence for Calcium Carbonate at the Mars Phoenix Landing Site

Phoenix Ascending The Phoenix mission landed on Mars in March 2008 with the goal of studying the ice-rich soil of the planets northern arctic region. Phoenix included a robotic arm, with a camera attached to it, with the capacity to excavate through the soil to the ice layer beneath it, scoop up soil and water ice samples, and deliver them to a combination of other instruments—including a wet chemistry lab and a high-temperature oven combined with a mass spectrometer—for chemical and geological analysis. Using this setup, Smith et al. (p. 58) found a layer of ice at depths of 5 to 15 centimeters, Boynton et al. (p. 61) found evidence for the presence of calcium carbonate in the soil, and Hecht et al. (p. 64) found that most of the soluble chlorine at the surface is in the form of perchlorate. Together these results suggest that the soil at the Phoenix landing site must have suffered alteration through the action of liquid water in geologically the recent past. The analysis revealed an alkaline environment, in contrast to that found by the Mars Exploration Rovers, indicating that many different environments have existed on Mars. Phoenix also carried a lidar, an instrument that sends laser light upward into the atmosphere and detects the light scattered back by clouds and dust. An analysis of the data by Whiteway et al. (p. 68) showed that clouds of ice crystals that precipitated back to the surface formed on a daily basis, providing a mechanism to place ice at the surface. The action of liquid water may have helped to form the calcium carbonate found in the soils around the Phoenix landing site. Carbonates are generally products of aqueous processes and may hold important clues about the history of liquid water on the surface of Mars. Calcium carbonate (approximately 3 to 5 weight percent) has been identified in the soils around the Phoenix landing site by scanning calorimetry showing an endothermic transition beginning around 725°C accompanied by evolution of carbon dioxide and by the ability of the soil to buffer pH against acid addition. Based on empirical kinetics, the amount of calcium carbonate is most consistent with formation in the past by the interaction of atmospheric carbon dioxide with liquid water films on particle surfaces.

The Mars Odyssey Gamma-Ray Spectrometer Instrument Suite

The Mars Odyssey Gamma-Ray Spectrometer is a suite of three different instruments, a gamma subsystem (GS), a neutron spectrometer, and a high-energy neutron detector, working together to collect data that will permit the mapping of elemental concentrations on the surface of Mars. The instruments are complimentary in that the neutron instruments have greater sensitivity to low amounts of hydrogen, but their signals saturate as the hydrogen content gets high. The hydrogen signal in the GS, on the other hand, does not saturate at high hydrogen contents and is sensitive to small differences in hydrogen content even when hydrogen is very abundant. The hydrogen signal in the neutron instruments and the GS have a different dependence on depth, and thus by combining both data sets we can infer not only the amount of hydrogen, but constrain its distribution with depth. In addition to hydrogen, the GS determines the abundances of several other elements. The instruments, the basis of the technique, and the data processing requirements are described as are some expected applications of the data to scientific problems.

Soil Water Content on Mars as Estimated from Neutron Measurements by the HEND Instrument Onboard the 2001 Mars Odyssey Spacecraft

We present the results of 20 months of observations of Mars by the Russian HEND instrument onboard the NASA 2001 Mars Odyssey spacecraft. We show that there are two extended subpolar regions with a soil water content of several tens of percent in the northern and southern hemispheres of Mars. The southern subpolar region is well described by a two-layer model, according to which a soil with a water content of up to 55% by mass lies under a relatively dry soil with a water mass fraction of 2% and a thickness of 15–20 g/cm2. The distribution of water in Martian regolith northern subpolar region is in good agreement with the homogeneous model and does not require invoking the more complex two-layer soil model. The water-ice content in the subsurface layer of the northern subpolar region reaches 53 % by mass. We show that there are two regions with a relatively high water content near the Martian equator. These are Arabia Terra and the Medusae Fossae formation region southwest of Olympus Mons. In these regions, a lower layer with 9–10% of water by mass may underlie the upper layer of relatively dry material ∼30 g/cm2 in thickness. The “moistest” spot near the equator is at about 30° E and 10° N. Its lower-layer soil may contain more than 16% of water by mass.

Thermal and Evolved Gas Analyzer: Part of the Mars Volatile and Climate Surveyor integrated payload

The Thermal and Evolved Gas Analyzer (TEGA) on the Mars Polar Lander spacecraft is composed of two separate components which are closely coupled: a Differential Scanning Calorimeter (DSC) and an Evolved Gas Analyzer (EGA). TEGA has the capability of performing differential scanning calorimetry on eight small (0.038 mL) soil samples selected in the vicinity of the lander. The samples will be heated in ovens to temperatures up to 950°C, and the volatile compounds water and carbon dioxide, which are released during the heating, will be analyzed in the EGA. The power required by the sample oven is continuously monitored during the heating and compared to that required to heat simultaneously a similar, but empty, oven. The power difference is the output of the DSC. Both endothermic and exothermic phase transitions can be detected, and the data can be used in the identification of the phases present. By correlating the gas release with the calorimetry, the abundance of the volatile compounds associated with the different phases can be determined. The EGA may also be able to detect the release of oxygen associated with any superoxide that may be on the surface of the soil grains. The instrument can detect the melting of ice in the DSC down to abundances on the order of 0.2% of the sample, and it can detect the decomposition of calcite, CaCO3, down to abundances of 0.5%. Using the EGA, TEGA can detect small amounts of water, down to 8 ppm in the sample, and it can detect the associated release of CO2 down to the equivalent abundances of 0.03%. The EGA also has the ability to determine the 13C/12C ratio in the evolved CO2, but it is not clear if the accuracy of this ratio will be sufficient to address the scientific issues.

Search for Water in Martian Soil Using Global Neutron Mapping by the Russian HEND Instrument Onboard the US 2001 Mars Odyssey Spacecraft

We present the first results of the global neutron mapping of Mars by the Russian High-Energy Neutron Detector (HEND) onboard the US 2001 Mars Odyssey spacecraft. Global neutron maps of Mars in various spectral ranges allow the content of water ice and adsorbed and bound water in a near-surface layer of the planet 1 to 2 m in thickness to be estimated. Huge regions of permafrost with a high (several tens of percent by weight) content of water ice are shown to be present in the north and the south of Mars. The continuous observations of Mars for 12 months, from February 18, 2002, through February 8, 2003, are indicative of significant seasonal variations on Mars where the transition from northern winter to northern summer occurred.

Seasonal Carbon Dioxide Depositions on the Martian Surface as Revealed from Neutron Measurements by the HEND Instrument Onboard the 2001 Mars Odyssey Spacecraft

We present the results of eighteen months of observations of the seasonal caps of Mars based on data from the neutron spectroscopy of the surface by the Russian HEND Instrument mounted aboard the NASA 2001 Mars Odyssey spacecraft. A four-dimensional model of the Martian seasonal caps was developed on the basis of these observation data. The model shows how the thickness of the frozen carbon dioxide changes in different surface regions. Using the results of the model, we estimated the total mass of the seasonal caps for the period of maximal accumulation of seasonal depositions and the rates of condensation and sublimation of the seasonal cover.

Aluminum abundance on the surface of Mercury: Application of a new background-reduction technique for the analysis of gamma-ray spectroscopy data

[1] A new technique has been developed for characterizing gamma-ray emission from a planetary surface in the presence of large background signals generated in a spacecraft. This technique is applied to the analysis of Al gamma rays measured by the MESSENGER Gamma-Ray Spectrometer to determine the abundance of Al on the surface of Mercury. The result (Al/Si = 0.29� 0.13 +0.05 ) is consistent with Al/Si ratios derived from the MESSENGER X-Ray Spectrometer and confirms the finding of low Al abundances. The measured abundance rules out a global, lunar-like feldspar-rich crust and is consistent with previously suggested analogs for surface material on Mercury, including terrestrial komatiites, low-iron basalts, partial melts of CB chondrites, and partial melts of enstatite chondrites. Additional applications of this technique include the measurement of other elements on Mercury’s surface as well as the analysis of data from other planetary gamma-ray spectrometer experiments.

Mars Odyssey Joins the Third Interplanetary Network

The Mars Odyssey spacecraft carries two experiments that are capable of detecting cosmic gamma-ray bursts and soft gamma repeaters. Since 2001 April they have detected over 275 bursts and, in conjunction with the other spacecraft of the interplanetary network, localized many of them rapidly and precisely enough to allow sensitive multiwavelength counterpart searches. We present the Mars Odyssey mission and describe the burst capabilities of the two experiments in detail. We explain how the spacecraft timing and ephemeris have been verified in-flight using bursts from objects whose precise positions are known by other means. Finally, we show several examples of localizations and discuss future plans for the Odyssey mission and the network as a whole.

Seasonal Neutron-Flux Variations in the Polar Caps of Mars as Revealed by the Russian HEND Instrument Onboard the NASA 2001 Mars Odyssey Spacecraft

We analyze the flux of epithermal neutrons from the Martian surface recorded by the Russian High-Energy Neutron Detector (HEND) from February 19 through December 19, 2002. The HEND was installed onboard the NASA 2001 Mars Odyssey spacecraft and is designed to measure neutron fluxes with energies above 1 eV. Over the period of observations, statistically significant variations in the flux of epithermal (10–100 keV) neutrons were found in the northern and southern polar caps. The largest neutron-flux variations were found at subpolar latitudes, where the relative difference between the summer and winter values can reach severalfold. This correlation becomes weaker with increasing distance from the poles. Thus, the relative change in the neutron flux near the 60° parallel is slightly more than 10%. We assume that the detected variations result from the global circulation of atmospheric carbon dioxide in subpolar Martian regions. To additionally test this assumption, we compared the HEND neutron measurements onboard 2001 Mars Odyssey and the seasonal variations in the CO2-layer thickness as observed by the Mars Orbital Laser Altimeter (MOLA) onboard Mars Global Surveyor (MGS).