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Dive into the research topics where Denis Garoli is active.

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Featured researches published by Denis Garoli.


Optics Letters | 2014

Bilayer holey plasmonic vortex lenses for the far field transmission of pure orbital angular momentum light states

Pierfrancesco Zilio; Giuseppe Parisi; Denis Garoli; M. Carli; Filippo Romanato

We report the design of a holey plasmonic vortex lens (PVL) structure able to couple circularly polarized impinging light to a plasmonic vortex in the form of the fundamental TM mode of a metal-insulator-metal plasmonic waveguide. The field transmitted through the hole milled at the center of the second metal layer of the structure is characterized by a well-defined spiral harmonic, entirely determined by the spin of impinging light and by the chirality of the PVL structure. Scattering finite elements simulations are presented for single layer standard PVLs and for bilayer ones, comparing the spiral spectra of the transmitted field and the efficiencies of the architectures.


Optics Letters | 2012

Focusing dynamics on circular distributed tapered metallic waveguides by means of plasmonic vortex lenses

T. Ongarello; Giuseppe Parisi; Denis Garoli; Elettra Mari; Pierfrancesco Zilio; Filippo Romanato

We investigate the focusing effect on circularly distributed planar tapered plasmonic waveguides by means of three-dimensional (3D) finite elements simulations. The proposed configuration allows nanofocusing on four faced planar nanotips, showing efficient condensation of surface plasmons polaritons (SPPs) at the silver/air interface toward the endpoint of the tips. By means of a plasmonic vortex lens it is possible to illuminate the tips with SPP waves carrying orbital angular momentum (OAM), namely plasmonic vortices. Our 3D simulations show that by acting on the topological charge of the plasmonic vortex the electric field charge distribution at the tips apex can be controlled accordingly to the input electric field phase distribution. The results for three particular OAM values are shown, along with a generalization for arbitrary plasmonic vortex angular momentum values.


Journal of Applied Physics | 2008

Transmittance and optical constants of Ce films in the 6–1200eV spectral range

Mónica Fernández-Perea; José A. Aznárez; Juan I. Larruquert; José A. Méndez; Luca Poletto; Denis Garoli; A. Marco Malvezzi; Angelo Giglia; Stefano Nannarone

The optical constants of Ce films were obtained in the 6–1200eV range from transmittance measurements obtained at room temperature. Thin films of Ce were deposited by evaporation in ultrahigh vacuum conditions and their transmittance was measured in situ. Ce films were deposited onto grid-supported, thin C films. Transmittance measurements of various film thicknesses were used to obtain the extinction coefficient k of Ce films at each individual photon energy investigated. The refractive index n of Ce was calculated with the Kramers–Kronig analysis using the current k data, which were extended toward smaller and larger energies with available data from literature and extrapolations. Ce has a low-absorption band right below O2,3 edge, with lowest absorption at 16.1eV. This makes Ce a promising material for the development of new filters and multilayer coatings below Ce O2,3 edge, in which few developments have been performed due to the lack of low-absorption materials. A good consistency of the data was ev...


Journal of The Optical Society of America A-optics Image Science and Vision | 2007

Optical constants of Yb films in the 23-1700 eV range

Mónica Fernández-Perea; Juan I. Larruquert; José A. Aznárez; José A. Méndez; Luca Poletto; Denis Garoli; A. Marco Malvezzi; Angelo Giglia; Stefano Nannarone

The optical constants of Yb films have been determined in the 23-1700 eV spectral range from transmittance measurements performed in situ on Yb films deposited by evaporation in ultrahigh vacuum conditions. Yb films were deposited over grids coated with a thin carbon film. Transmittance measurements were used to obtain the extinction coefficient of Yb films at each individual photon energy investigated. The energy range investigated encompasses Yb edges from M(4,5) to O(2,3). The current results, along with data in the literature, show that Yb has an interesting low-absorption band in the approximately 12-24 eV range, which may be useful for the development of transmittance filters and multilayer coatings. The current data along with literature data and extrapolations were used to obtain n, the real part of the complex refractive index, using a Kramers-Krönig analysis. The application of the sum rules showed a good consistency of the results.


Journal of Applied Physics | 2008

Transmittance and optical constants of Pr films in the 4–1600eV spectral range

Mónica Fernández-Perea; Manuela Vidal-Dasilva; José A. Aznárez; Juan I. Larruquert; José A. Méndez; Luca Poletto; Denis Garoli; A. Marco Malvezzi; Angelo Giglia; Stefano Nannarone

The optical constants of Pr films were obtained in the 4–1600eV range from transmittance measurements performed at room temperature. Thin films of polycrystalline Pr were deposited by evaporation in ultrahigh vacuum conditions and their transmittance was measured in situ. Pr films were deposited onto grids coated with a thin, C support film. Transmittance measurements were used to obtain the optical extinction coefficient k of Pr films in the 4–1600 investigated photon energy range. The refractive index n of Pr was calculated using the Kramers–Kronig analysis. Data were extrapolated both on the high and low-energy sides by using experimental and calculated extinction coefficient data available from the literature. Pr, similar to other lanthanides, has a low-absorption band right below the O2,3 edge onset; the lowest absorption was measured at about 17eV. Therefore, Pr is a promising material for filters and multilayer coatings in the energy range below O2,3 edge in which most materials have a strong absor...


Scientific Reports | 2016

Optical vortex beam generator at nanoscale level

Denis Garoli; Pierfrancesco Zilio; Yuri Gorodetski; Francesco Tantussi; Francesco De Angelis

Optical beams carrying orbital angular momentum (OAM) can find tremendous applications in several fields. In order to apply these particular beams in photonic integrated devices innovative optical elements have been proposed. Here we are interested in the generation of OAM-carrying beams at the nanoscale level. We design and experimentally demonstrate a plasmonic optical vortex emitter, based on a metal-insulator-metal holey plasmonic vortex lens. Our plasmonic element is shown to convert impinging circularly polarized light to an orbital angular momentum state capable of propagating to the far-field. Moreover, the emerging OAM can be externally adjusted by switching the handedness of the incident light polarization. The device has a radius of few micrometers and the OAM beam is generated from subwavelength aperture. The fabrication of integrated arrays of PVLs and the possible simultaneous emission of multiple optical vortices provide an easy way to the large-scale integration of optical vortex emitters for wide-ranging applications.


Nano Letters | 2016

Beaming of Helical Light from Plasmonic Vortices via Adiabatically Tapered Nanotip

Denis Garoli; Pierfrancesco Zilio; Yuri Gorodetski; Francesco Tantussi; Francesco De Angelis

We demonstrate the generation of far-field propagating optical beams with a desired orbital angular momentum by using a smooth optical-mode transformation between a plasmonic vortex and free-space Laguerre–Gaussian modes. This is obtained by means of an adiabatically tapered gold tip surrounded by a spiral slit. The proposed physical model, backed up by the numerical study, brings about an optimized structure that is fabricated by using a highly reproducible secondary electron lithography technique. Optical measurements of the structure excellently agree with the theoretically predicted far-field distributions. This architecture provides a unique platform for a localized excitation of plasmonic vortices followed by its beaming.


Journal of Applied Physics | 2008

Transmittance and optical constants of Eu films from 8.3 to 1400 eV

Mónica Fernández-Perea; Manuela Vidal-Dasilva; José A. Aznárez; Juan I. Larruquert; José A. Méndez; Luca Poletto; Denis Garoli; A. Marco Malvezzi; Angelo Giglia; Stefano Nannarone

The optical constants of Eu films were obtained in the 8.3–1400 eV range from transmittance measurements performed at room temperature. Thin films of Eu were deposited by evaporation in ultrahigh vacuum conditions and their transmittance was measured in situ. Eu films were deposited onto grids coated with a thin C support film. The refractive index n of Eu was calculated using the Kramers-Kronig analysis. Data were extrapolated both on the high- and low-energy sides by using experimental and calculated extinction coefficient values available in the literature. Eu, similar to other lanthanides, has a low-absorption band just below the O2,3 edge onset; the lowest absorption was measured at about 16.7 eV. Therefore, Eu is a promising material for filters and multilayer coatings in the energy range below the O2,3 edge in which materials typically have a strong absorption. The consistency of the composite optical constants was tested with the f and inertial sum rules and found to be good.


Journal of Vacuum Science & Technology. B. Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena | 2013

Nanoporous gold—Application to extraordinary optical transmission of light

Denis Garoli; Gianluca Ruffato; Sandro Cattarin; Simona Barison; Mauro Perino; T. Ongarello; Filippo Romanato

The authors present their work in the preparation of nanoporous gold layers and their patterning with an original procedure preserving the porosity, to obtain the phenomenon of extraordinary transmission of light with a porous material. The design, fabrication, and characterization of nanoslit arrays made with bulk gold and nanoporous gold films are presented and their sensing performances are compared after coating with thiolated organic molecules. Thanks to a greatly enhanced surface-to-volume ratio, nanoporous gold reveals benefits for better reaction efficiency and detection sensitivity. Moreover, plasmonic properties in the near-IR range assure employment in plasmonic devices.


Optical Materials Express | 2015

Nanoporous gold leaves: preparation, optical characterization and plasmonic behavior in the visible and mid-infrared spectral regions

Denis Garoli; Gianluca Ruffato; Pierfrancesco Zilio; Eugenio Calandrini; Francesco De Angelis; Filippo Romanato; Sandro Cattarin

A robust and reproducible preparation of self-standing nanoporous gold leaves (NPGL) is presented, with optical characterization and plasmonic behaviour analysis. Nanoporous gold (NPG) layers are tipically prepared as thin films on a bulk substrate. Here we present an alternative approach consisting in the preparation of NPGL in the form of a self-standing film. This solution leads to a perfectly symmetric configuration where the metal is immersed in a homogeneous medium and in addition can support the propagation of symmetric and antisymmetric plasmonic modes. With respect to bulk gold, NPG shows metallic behaviour at higher wavelengths, suggesting possible plasmonic applications in the near / medium infrared range. In this work the plasmonic properties in the wide wavelength range from the ultraviolet up to the mid-infrared range have been investigated. References and links 1. R. Zhang and H. Olin, “Porous Gold Films—A Short Review on Recent Progress,” Materials 7, 3834-3854 (2014). 2. Y. Xue, J. Markmann, H. Duan, J. Weissmuller and P. Huber, “Switchable imbibition in nanoporous gold,” ncomms 5237, 1-8 (2014). 3. R. Zhang, H. A. Andersson, M. Andersson, B. Andres, H. Edlund, P. Edström, S. Edvardsson, S. Forsberg, M. Hummelgård and N. Johansson, “Soap-film coating: High-speed deposition of multilayer nanofilms,” Sci. Rep. 3, 1-7 (2013). 4. Y. Fu, J. Zhang, K. Nowaczyk and J. R. Lakowicz, “Enhanced single molecule fluorescence and reduced observation volumes on nanoporous gold (NPG) films,” Chem. Commun. 49, 10874-10876 (2013). 5. J. Biener, G. W. Nyce, A. M. Hodge, M. M. Biener, A. V. Hamza, and S. A. Maier, “Nanoporous plasmonic metamaterials,” Adv. Mater. 20, 1211–1217 (2008). 6. G. Ruffato, F. Romanato, D. Garoli, and S. Cattarin, “Nanoporous gold plasmonic structures for sensing applications,” Opt. Exp. 19, 13164-13170 (2011). 7. G. Ruffato, D. Garoli, S. Cattarin, S. Barison, M. Natali, P. Canton, A, Benedetti, D. De Salvador, and F. Romanato, “Patterned nanoporous-gold thin layers: Structure control and tailoring of plasmonic properties,” Microporous and Mesoporous Materials 163 153–159 (2012). 8. D. Garoli, G.Ruffato, S. Cattarin, S. Barison, M. Perino, T. Ongarello, and F. Romanato, “Nanoporous gold— Application to extraordinary optical transmission of light,” J. Vac. Sci. Technol. B 31 012601-1-012601-6 (2013). 9. D. Garoli, G.Ruffato, P. Zilio, E. Calandrini, F. De Angelis, F. Romanato and S. Cattarin, “Nanoporous gold leaves: preparation, optical characterization and plasmonic behavior in the visible and mid-infrared spectral regions,” Opt. Mat. Express 5 2246-2256 (2015). 10. D. Garoli, E. Calandrini, A. Bozzola, M. Ortolani, S. Cattarin, S. Barison, A. Tomaa and F. De Angelis, “Boosting infrared energy transfer in 3D nanoporous gold antennas,” Nanoscale 9 915-922 (2017). 11. R. Li, and K. Sieradzki, “Ductile-Brittle Transition in Random Porous Au,” Phys. Rev. Lett. 68 1168-1171 (1992). 12. J. Erlebacher, M. J. Aziz, A. Karma, N. Dimitrov, and K. Sieradzki, “Evolution of nanoporosity in dealloying,” Nature 410 450-453 (2001). 13. M. C. Dixon, T. A. Daniel, M. Hieda, D. M. Smilgies, M. H. W. Chan, and D. L. Allara, “Preparation, Structure and Optical Properties of Nanoporous Gold Thin Films,” Langmuir 23 2414-2422 (2007). 14. J. Wijnhoven, S. J. M. Zevenhuizen, M. A. Hendriks, D. Vanmaekelbergh, J. J. Kelly, and W. L. Vos, “Electrochemical Assembly of Ordered Macropores in Gold,” Adv. Mat. 12, 888-890 (2000). 15. P. N. Bartlett, J. J. Baumberg, P. R. Birkin, M. A. Ghanem, and M. C. Netti, “Highly ordered Macroporous Gold and Platinum Films Formed by Electrochemical Deposition through templates assembled from Submicron Diameter Monodisperse Polystyrene Spheres,” Chem. Mater. 14, 2199-2208 (2002). 16. M. Heim, S. Reculusa, S. Ravaine, and A. Kuhn, “Engineering of complex macroporous materials through controlled electrodeposition in colloidal superstructures,” Adv. Funct. Mater. 22, 538-545 (2012). 17. C. Shin, W. Shin, and H. G. Hong, “Electrochemical fabrication and electrocatalytic characteristics studies of gold nanopillar array electrode (AuNPE) for development of a novel electrochemical sensor,” Electrochim. Acta 53 720-728 (2007). 18. S. Cherevko, and C-H. Chung, “Direct electrodeposition of nanoporous gold with controlled multimodal pore size distribution,” Electrochem. Commun. 13, 16-19 (2011). 19. H. Li, Y-J. Li, L-L. Sun, and X-L. Zhao, “One-step, template-free electrochemical preparation of threedimensional porous Au nanowire network and its enhanced activity toward methanol electrooxidation,” Electrochim. Acta 108, 74-78 (2013). 20. K. Murata, K. Kajiya, M. Nukaga, Y. Suga, T. Watanabe, N. Nakamura, and H. Ohno, “A simple fabrication method for three-dimensional gold nanoparticle electrodes and their application to the study of the direct electrochemistry of cytochrome C,” Electroanalysis 22,185-190 (2010). 21. F. Bisio, M. Palombo, M. Prato, O. Cavalleri, E. Barborini, S. Vinati, M. Franchi, L. Mattera, and M. Canepa, “Optical properties of cluster-assembled nanoporous gold films,” Phys. Rev. B 80, 205428 (2009). 22. M. C. Dixon, T. A. Daniel, M. Hieda, D. M. Smilgies, M. H. W. Chan, and D. L. Allara, “Preparation, Structure, and Optical Properties of Nanoporous Gold Thn Films,” Langmuir 23, 2414-2422 (2007). 23. Y. Ding, Y-J. Kim, and J. Erlebacher, “Nanoporous gold leaf: “An ancient technology” ,” Adv. Mat. 16, 18971900 (2004). 24. P. N. Ciesielski, A. M. Scott, C. J. Faulkner, B. J. Berron, D. E. Cliffel, and G. K. Jennings, “Functionalized Nanoporous Gold Leaf Electrode Films for the Immobilization of Photosystem I,” ACS Nano 2, 2465–2472 (2008). 25. H. Rosner, S. Parida, D. Kramer, C. A. Volkert, and J. Weissmuller, “Reconstructing a Nanoporous Metal in Three Dimensions: An Electron Tomography Study of Dealloyed Gold Leaf,” Adv. Engin. Mater. 9, 535-541 (2007). 26. E. Detsi, M. Salverda, P. R. Onck, and J. T. M. De Hosson, “On localized surface plasmon resonance modes in nanoporous gold films,” Journal of Applied Physics 115, 044308 (2014). 27. S. R. Ahmed, M. A. Hossain, J. Y. Park, S-H. Kim, D. Lee, T. Suzuki, J. Lee, E. Y. Park, “Metal enhanced fluorescence on nanoporous gold leaf-based assay platform for virus detection,” Biosensors and Bioelectronics. 58, 33-39 (2014). 28. X. Ge, L. Wang, Z. Liu, and Y. Ding, “Nanoporous Gold Leaf for Amperometric Determination of Nitrite,” Electroanalysis 23, 381 – 386 (2011). 29. S. Parida, D. Kramer, C. A. Volkert, H. Rösner, J. Erlebacher, and J. Weissmüller, “Volume change during the formation of nanoporous gold by dealloying,” Phys. Rev. Lett. 97, 035504-1-35504-4 (2006). 30. H. Fujiwara, “Spectroscopic Ellipsometry: Principles and Applications” (Wiley, 2007). 31. X. F. Ang, F. Y. Li, W. L. Tan, Z. Chen, and C. C. Wong, “Self-assembled monolayer for reduced temperature direct metal thermocompression bonding,” Appl. Phys. Lett. 91, 061913-1-3 (2007). 32. S. Cattarin, D, Kramer, A. Lui, and M. Musiani, “Preparation and Characterization of Gold Nanostructures of Controlled Dimension by Electrochemical Techniques,” J. Phys. Chem. C 111, 12643-12649 (2007). 33. S. Cattarin, D, Kramer, A. Lui, and M. Musiani, “Formation of nanostructured gold sponges by anodic dealloying. EIS investigation of product and process,” Fuel Cells 9, 209-214 (2009). 34. E. Rouya, S. Cattarin, M.L. Reed, R.G. Kelly, G. Zangari, “Electrochemical characterization of the surface area of nanoporous gold films,” J. Electrochemical Society 159, K97-K102 (2012). 35. Y. Sun, and T. J. Balk, “Evolution of structure, composition and stress in nanoporous gold thin films with grainboundary cracks” Metall. Mater. Trans. A 39, 2656-2665 (2008). 36. A. I. Maaroof, A. Gentle, G. B. Smith, and M. B. Cortie, “Bulk and Surface Plasmons in highly nanoporous gold films,” J. Phys. D: Appl. Phys. 40, 5675-5682 (2007). 37. G. B. Smith, and A. A. Earp, “Metal-in-metal localized surface plasmon resonance,” Nanotechnology 21, 015203 (2010). 38. N. W. Ashcroft and N. D. Mermin, “Solid State Physics” (Thomson Brookes – Cole, 1976). 39. D. A. G. Bruggeman, “Berechnung verschiedener physikalischer Konstanten von heterogenen substanzen,” Ann. Phys. 24, 636-679 (1935). 40. J. Homola, “Surface Plasmon Resonance Based Sensors” (Springer, 2006). 41. A. D. Rakić, A. B. Djurišic, J. M. Elazar, and M. L. Majewski, “Optical properties of metallic films for verticalcavity optoelectronic devices,” Appl. Opt. 37, 5271-5283 (1998). 42. P. Berini, “Long-range surface plasmon polaritons,” Adv. Opt. Phot. 1 (3), 484-588 (2009). 43. J. A. Dionne, L. A. Sweatlock, A. Atwater, and A. Polman, “Planar metal plasmon waveguides: frequencydependent dispersion, propagation, localization and loss beyond the free electron model,” Phys. Rev. B 72, 075405-1-10 (2005).A robust and reproducible preparation of self-standing nanoporous gold leaves (NPGL) is presented, with optical characterization and plasmonic behaviour analysis. Nanoporous gold (NPG) layers are tipically prepared as thin films on a bulk substrate. Here we present an alternative approach consisting in the preparation of NPGL in the form of a self-standing film. This solution leads to a perfectly symmetric configuration where the metal is immersed in a homogeneous medium and in addition can support the propagation of symmetric and antisymmetric plasmonic modes. With respect to bulk gold, NPG shows metallic behaviour at higher wavelengths, suggesting possible plasmonic applications in the near / medium infrared range. In this work the plasmonic properties in the wide wavelength range from the ultraviolet up to the mid-infrared range have been investigated.

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Francesco De Angelis

Istituto Italiano di Tecnologia

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Pierfrancesco Zilio

Istituto Italiano di Tecnologia

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Eugenio Calandrini

Istituto Italiano di Tecnologia

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Sandro Cattarin

National Research Council

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Nicolò Maccaferri

Istituto Italiano di Tecnologia

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Luca Poletto

National Research Council

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Juan I. Larruquert

Spanish National Research Council

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