Domenico Paparo

Optical spin-to-orbital angular momentum conversion in inhomogeneous anisotropic media

We demonstrate experimentally an optical process in which the spin angular momentum carried by a circularly polarized light beam is converted into orbital angular momentum, leading to the generation of helical modes with a wave-front helicity controlled by the input polarization. This phenomenon requires the interaction of light with matter that is both optically inhomogeneous and anisotropic. The underlying physics is also associated with the so-called Pancharatnam-Berry geometrical phases involved in any inhomogeneous transformation of the optical polarization.

Pancharatnam-Berry phase optical elements for wave front shaping in the visible domain: Switchable helical mode generation

We report the realization of a Pancharatnam-Berry phase optical element [Z. Bomzon, G. Biener, V. Kleiner, and E. Hasman, Opt. Lett. 27, 1141 (2002)], for wave front shaping working in the visible spectral domain, based on patterned liquid crystal technology. This device generates helical modes of visible light with the possibility of electro-optically switching between opposite helicities by controlling the handedness of the input circular polarization. By cascading this approach, fast switching among multiple wave front helicities can be achieved, with potential applications to multistate optical information encoding. The approach demonstrated here can be generalized to other polarization-controlled devices for wave front shaping, such as switchable lenses, beam splitters, and holographic elements.

Dielectric Relaxation Dynamics of Water in Model Membranes Probed by Terahertz Spectroscopy

We study hydrated model membranes, consisting of stacked bilayers of 1,2-dioleoyl-sn-glycero-3-phosphocholine lipids, using terahertz time-domain spectroscopy and infrared spectroscopy. Terahertz spectroscopy enables the investigation of water dynamics, owing to its sensitivity to dielectric relaxation processes associated with water reorientation. By controlling the number of water molecules per lipid molecule in the system, we elucidate how the interplay between the model membrane and water molecules results in different water dynamics. For decreasing hydration levels, we observe the appearance of new types of water dynamics: the collective bulklike dynamics become less pronounced, whereas an increased amount of both very slowly reorienting (i.e., irrotational) and very rapidly reorienting (i.e., fast) water molecules appear. Temperature-dependent measurements reveal the interconversion between the three distinct types of water present in the system.

Polar catastrophe and electronic reconstructions at the LaAlO3/SrTiO3 interface: evidence from optical second harmonic generation

The so-called “polar catastrophe,” a sudden electronic reconstruction taking place to compensate for the interfacial ionic polar discontinuity, is currently considered as a likely factor to explain the surprising conductivity of the interface between the insulators LaAlO3 and SrTiO3. We applied optical second harmonic generation, a technique that a priori can detect both mobile and localized interfacial electrons, to investigating the electronic polar reconstructions taking place at the interface. As the LaAlO3 film thickness is increased, we identify two abrupt electronic rearrangements: the first takes place at a thickness of unit cells, in the insulating state; the second occurs at a thickness of 4–6 unit cells, i.e., just above the threshold for which the samples become conducting. Two possible physical scenarios behind these observations are proposed. The first is based on an electronic transfer into localized electronic states at the interface that acts as a precursor of the conductivity onset. In the second scenario, the signal variations are attributed to the strong ionic relaxations taking place in the LaAlO3 layer.

Quantum walks and wavepacket dynamics on a lattice with twisted photons

A discrete quantum walk occurs in the orbital angular momentum space of light, both for a single photon and for two simultaneous photons. The “quantum walk” has emerged recently as a paradigmatic process for the dynamic simulation of complex quantum systems, entanglement production and quantum computation. Hitherto, photonic implementations of quantum walks have mainly been based on multipath interferometric schemes in real space. We report the experimental realization of a discrete quantum walk taking place in the orbital angular momentum space of light, both for a single photon and for two simultaneous photons. In contrast to previous implementations, the whole process develops in a single light beam, with no need of interferometers; it requires optical resources scaling linearly with the number of steps; and it allows flexible control of input and output superposition states. Exploiting the latter property, we explored the system band structure in momentum space and the associated spin-orbit topological features by simulating the quantum dynamics of Gaussian wavepackets. Our demonstration introduces a novel versatile photonic platform for quantum simulations.

Direct Femtosecond Laser Surface Structuring with Optical Vortex Beams Generated by a q-plate

Creation of patterns and structures on surfaces at the micro- and nano-scale is a field of growing interest. Direct femtosecond laser surface structuring with a Gaussian-like beam intensity profile has already distinguished itself as a versatile method to fabricate surface structures on metals and semiconductors. Here we present an approach for direct femtosecond laser surface structuring based on optical vortex beams with different spatial distributions of the state of polarization, which are easily generated by means of a q-plate. The different states of an optical vortex beam carrying an orbital angular momentum ℓ = ±1 are used to demonstrate the fabrication of various regular surface patterns on silicon. The spatial features of the regular rippled and grooved surface structures are correlated with the state of polarization of the optical vortex beam. Moreover, scattered surface wave theory approach is used to rationalize the dependence of the surface structures on the local state of the laser beam characteristics (polarization and fluence). The present approach can be further extended to fabricate even more complex and unconventional surface structures by exploiting the possibilities offered by femtosecond optical vector fields.

Blue luminescence of SrTiO3 under intense optical excitation

The blue-green photoluminescence emitted by pure and electron-doped strontium titanate under intense pulsed near-ultraviolet excitation is studied experimentally, as a function of excitation intensity and temperature. Both emission spectra and time-resolved decays of the emission are measured and analyzed in the framework of simple phenomenological models. We find an interesting blue-to-green transition occurring for increasing temperatures in pure samples, which is instead absent in doped materials. The luminescence yield and decay rate measured as a function of temperature can be modeled well as standard activated behaviors. The leading electron-hole recombination process taking place in the initial decay is established to be second-order, or bimolecular, in contrast to recent reports favoring a third-order interpretation as an Auger process. The temporal decay of the luminescence can be described well by a model based on two interacting populations of excitations, respectively identified with interacting defect-trapped (possibly forming excitons) and mobile charges. Finally, from the measured doping and sample dependence of the luminescence yield, we conclude that the radiative centers responsible for the luminescence are probably intrinsic structural defects other than bulk oxygen vacancies.

Wavelength dependence of optical reorientation in dye-doped nematics

Abstract The wavelength dependence of the optical reorientation of nematic liquid crystals is investigated in the presence of two dyes, using the z-scan technique. A strong correlation is found between the magnitude of the dyeinduced amplification of the optical torque and the dichroism of the system.

Femtosecond laser surface structuring of silicon using optical vortex beams generated by a q-plate

We report on laser surface structuring of silicon using Ti:Sa femtosecond laser ablation with optical vortex beams. A q-plate is used to generate an optical vortex beam with femtosecond pulse duration through spin-to-orbital conversion of the angular momentum of light. The variation of the produced surface structures is investigated as a function of the number of pulses, N, at laser fluence slightly above the ablation threshold value. At low N (≈10), only surface corrugation of the irradiated, ring-shaped area is observed. This is followed by a progressive formation of regular ripples at larger N (≈100–500), which eventually transform in smaller columnar structures for N ≈ 1000. Moreover, the central, non-ablated part is gradually decorated by nanoparticles produced during laser ablation, a process which eventually leads to the formation of a central turret of assembled nanoparticles. Our experimental findings suggest the importance of a feedback mechanism and a cumulative effect on the formation of ripples with interesting patterns not achievable by the more standard beams with a Gaussian intensity profile.

Recombination kinetics of a dense electron-hole plasma in strontium titanate

We investigated the nanosecond-scale time decay of the blue-green light emitted by nominally pure