Donald E. Voigt

Onset of deglacial warming in West Antarctica driven by local orbital forcing

The cause of warming in the Southern Hemisphere during the most recent deglaciation remains a matter of debate. Hypotheses for a Northern Hemisphere trigger, through oceanic redistributions of heat, are based in part on the abrupt onset of warming seen in East Antarctic ice cores and dated to 18,000 years ago, which is several thousand years after high-latitude Northern Hemisphere summer insolation intensity began increasing from its minimum, approximately 24,000 years ago. An alternative explanation is that local solar insolation changes cause the Southern Hemisphere to warm independently. Here we present results from a new, annually resolved ice-core record from West Antarctica that reconciles these two views. The records show that 18,000 years ago snow accumulation in West Antarctica began increasing, coincident with increasing carbon dioxide concentrations, warming in East Antarctica and cooling in the Northern Hemisphere associated with an abrupt decrease in Atlantic meridional overturning circulation. However, significant warming in West Antarctica began at least 2,000 years earlier. Circum-Antarctic sea-ice decline, driven by increasing local insolation, is the likely cause of this warming. The marine-influenced West Antarctic records suggest a more active role for the Southern Ocean in the onset of deglaciation than is inferred from ice cores in the East Antarctic interior, which are largely isolated from sea-ice changes.

Chemical fixation of arsenic in contaminated soils

Arsenic-contaminated soils have been successfully treated using fixation methods whereby chemicals are added to prevent As mobilization. However, the chemistry of the fixation process used in the field is poorly understood. We have examined one process which succeeded in immobilizing 0. I to 0.2 weight % As in soil at a 69 a old dump site through the addition of ferrous sulfate and water followed by Ca(OH)2, Portland cement and water. The intent of the first step is to form insoluble Fe arsenate, the second to bind the soil. The particle-size distribution of the untreated soil grains containing As is bimodal, with 70% of the As occurring in 2 size fractions: 38% in the 0.25–0.5 mm fraction mostly as the mineral hoernesite (Mg3(ASO4)2 · 8H2O), and 32% in the size fraction less than 5 pm. From sequential extractions, As in the finest fraction is inferred to be present in an oxyanionic form adsorbed on mineral surfaces. Arsenic may also be associated with Fe or Mn oxide coatings, and may be present as fine grains of hoernesite. Hoernesite, which we infer formed because of the brackish nature of the ground water at this site, represents an example of natural fixation of As. Arsenic is more evenly distributed among grain size fractions in the field-fixed soils. Using X-ray diffraction, electron microscopy, and chemical analysis, we find no direct evidence for the formation of Fe arsenate phases in the fixed soils. Sequential extractions demonstrate that the fixation method reduces exchangeable As in the < 5 μm fraction even when only Fe sulfate is added. While fixation occurs by reaction with FeSO4, it is unlikely that ferric arsenate forms as an insoluble phase under these conditions, as is generally assumed. Arsenic fixation occurs through precipitation of an unknown AsFe phase or by incorporation during Fe oxide precipitation aided by immobilization by a cement coating.

Ice stream D flow speed is strongly modulated by the tide beneath the Ross Ice Shelf

The flow velocity of ice stream D, West Antarctica has been measured to vary by a factor of three over the course of a day. These fluctuations are measured at the grounding line as well as upstream of the grounding line in the ice plain of ice stream D. The diurnal velocity fluctations appear to be driven by the tide beneath the Ross Ice Shelf. These results suggest that there is significant, and heretofore poorly understood, influence of the ocean tide and of the ice shelf on the dynamics of ice stream flow.

Precise interpolar phasing of abrupt climate change during the last ice age

The last glacial period exhibited abrupt Dansgaard–Oeschger climatic oscillations, evidence of which is preserved in a variety of Northern Hemisphere palaeoclimate archives. Ice cores show that Antarctica cooled during the warm phases of the Greenland Dansgaard–Oeschger cycle and vice versa, suggesting an interhemispheric redistribution of heat through a mechanism called the bipolar seesaw. Variations in the Atlantic meridional overturning circulation (AMOC) strength are thought to have been important, but much uncertainty remains regarding the dynamics and trigger of these abrupt events. Key information is contained in the relative phasing of hemispheric climate variations, yet the large, poorly constrained difference between gas age and ice age and the relatively low resolution of methane records from Antarctic ice cores have so far precluded methane-based synchronization at the required sub-centennial precision. Here we use a recently drilled high-accumulation Antarctic ice core to show that, on average, abrupt Greenland warming leads the corresponding Antarctic cooling onset by 218 ± 92 years (2σ) for Dansgaard–Oeschger events, including the Bølling event; Greenland cooling leads the corresponding onset of Antarctic warming by 208 ± 96 years. Our results demonstrate a north-to-south directionality of the abrupt climatic signal, which is propagated to the Southern Hemisphere high latitudes by oceanic rather than atmospheric processes. The similar interpolar phasing of warming and cooling transitions suggests that the transfer time of the climatic signal is independent of the AMOC background state. Our findings confirm a central role for ocean circulation in the bipolar seesaw and provide clear criteria for assessing hypotheses and model simulations of Dansgaard–Oeschger dynamics.

Crust and upper mantle structure of the Transantarctic Mountains and surrounding regions from receiver functions, surface waves, and gravity: Implications for uplift models

[1] This study uses seismic receiver functions, surface wave phase velocities, and airborne gravity measurements to investigate the structure of the Transantarctic Mountains (TAM) and adjacent regions of the Ross Sea (RS) and East Antarctica (EA). Forty-one broadband seismometers deployed during the Transantarctic Mountain Seismic Experiment provide new insight into the differences between the TAM, RS, and EA crust and mantle. Combined receiver function and phase velocity inversion with niching genetic algorithms produces accurate crustal and upper mantle seismic velocity models. The crustal thickness increases from 20 ± 2 km in the RS to a maximum of 40 ± 2 km beneath the crest of the TAM at 110 ± 10 km inland. Farther inland, the crust of EA is uniformly 35 ± 3 km thick over a lateral distance greater than 1300 km. Upper mantle shear wave velocities vary from 4.5 km s � 1 beneath EA to 4.2 km s � 1 beneath RS, with a transition between the two at 100 ± 50 km inland near the crest of the TAM. The � 5k m thick crustal root beneath the TAM has an insufficient buoyant load to explain the entire TAM uplift, suggesting some portion of the uplift may result from flexure associated with a buoyant thermal load in the mantle beneath the edge of the TAM lithosphere.

Subglacial Sediments as a Control on the Onset and Location of two Siple Coast Ice Streams, West Antarctica

Laterally continuous subglacial sediments are a necessary component for ice streaming in the modern onset regions of the ice streams draining the Siple Coast of West Antarctica on the basis of new seismic data combined with previous results. We present geophysical results from seismic reflection and refraction experiments in the upper reaches of ice streams C and D that highlight continuous sedimentary basins within and upstream of the current onset regions of both ice streams, with streaming ice overlying these sedimentary packages. The subglacial environment changes from no-sediment to discontinuous-sediment to continuous-sediment cover along a longitudinal profile from the ice sheet to tributary C1B. Along this same profile, we observe a speedup of ice flow and then full development of the ice stream tributary. Ice stream D flows above a thick sedimentary package with an uppermost low-seismic-velocity zone indicative of soft till, and the upglacier and lateral extensions of ice stream D are tightly constrained by the extent of continuous sediments. The inland termination of these sediments suggests that future migration of high-velocity, low-shear-stress ice flow in these regions appears unlikely.

Complex fabric development revealed by englacial seismic reflectivity: Jakobshavn Isbræ, Greenland

This is the published version. Copyright 2008 American Geophysical Union. All Rights Reserved.

P and S velocity structure of the upper mantle beneath the Transantarctic Mountains, East Antarctic craton, and Ross Sea from travel time tomography

P and S wave travel times from teleseismic earthquakes recorded by the Transantarctic Mountains Seismic Experiment (TAMSEIS) have been used to tomographically image upper mantle structure beneath portions of the Transantarctic Mountains (TAM), the East Antarctic (EA) craton, and the West Antarctic rift system (WARS) in the vicinity of Ross Island, Antarctica. The TAM form a major tectonic boundary that divides the stable EA craton and the tectonically active WARS. Relative arrival times were determined using a multichannel cross-correlation technique on teleseismic P and S phases from earthquakes with mb ≥ 5.5. 3934 P waves were used from 322 events, and 2244 S waves were used from 168 events. Relative travel time residuals were inverted for upper mantle structure using VanDecars method. The P wave tomography model reveals a low-velocity anomaly in the upper mantle of approximately δVp = −1 to −1.5% in the vicinity of Ross Island extending laterally 50 to 100 km beneath the TAM from the coast, placing the contact between regions of fast and slow velocities well inland from the coast beneath the TAM. The magnitude of the low-velocity anomaly in the P wave model appears to diminish beneath the TAM to the north and south of Ross Island. The depth extent of the low-velocity anomaly is not well constrained, but it probably is confined to depths above ∼200 km. The S wave model, within resolution limits, is consistent with the P wave model. The low-velocity anomaly within the upper mantle can be attributed to a 200–300 K thermal anomaly, consistent with estimates obtained from seismic attenuation measurements. The presence of a thermal anomaly of this magnitude supports models invoking a thermal buoyancy contribution to flexurally driven TAM uplift, at least in the Ross Island region of the TAM. Because the magnitude of the anomaly to the north and south of Ross Island may diminish, the thermal contribution to the uplift of the TAM could be variable along strike, with the largest contribution in the Ross Island region. The tomography results reveal faster than average velocities beneath East Antarctica, as expected for cratonic upper mantle.

Monitoring volcanic hazard using eddy covariance at Solfatara volcano, Naples, Italy

An eddy covariance (EC) station was deployed at Solfatara crater, Italy, June 8–25, 2001 to assess if EC could reliably monitor CO2 fluxes continuously at this site. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes calculated in 30-min averages varied between 950 and 4460 g CO2 m−2 d−1; the highest measurements were made downwind of degassing pools. Comparing turbulent fluxes with chamber measurements of surface fluxes using footprint models in diffuse degassing regions yielded an average difference of 0% (±4%), indicating that EC measurements are representative of surface fluxes at this volcanic site. Similar comparisons made downwind of degassing pools yielded emission rates from 12 to 27 t CO2 d−1 for these features. Reliable EC measurements (i.e. measurements with sufficient and stationary turbulence) were obtained primarily during daytime hours (08:00 and 20:00 local time) when the wind speed exceeded 2 m s−1. Daily average EC fluxes varied by ±50% and variations were likely correlated to changes in atmospheric pressure. Variations in CO2 emissions due to volcanic processes at depth would have to be on the same order of magnitude as the measured diurnal variability in order to be useful in predicting volcanic hazard. First-order models of magma emplacement suggest that emissions could exceed this rate for reasonable assumptions of magma movement. EC therefore provides a useful method of monitoring volcanic hazard at Solfatara. Further, EC can monitor significantly larger areas than can be monitored by previous methods.

Core handling and processing for the WAIS Divide ice-core project

Abstract On 1 December 2011 the West Antarctic Ice Sheet (WAIS) Divide ice-core project reached its final depth of 3405 m. The WAIS Divide ice core is not only the longest US ice core to date, but is also the highest-quality deep ice core, including ice from the brittle ice zone, that the US has ever recovered. The methods used at WAIS Divide to handle and log the drilled ice, the procedures used to safely retrograde the ice back to the US National Ice Core Laboratory (NICL) and the methods used to process and sample the ice at the NICL are described and discussed.