E. Cuoco

Impact of volcanic plume emissions on rain water chemistry during the January 2010 Nyamuragira eruptive event: implications for essential potable water resources.

On January 2, 2010 the Nyamuragira volcano erupted lava fountains extending up to 300 m vertically along an ~1.5 km segment of its southern flank cascading ash and gas on nearby villages and cities along the western side of the rift valley. Because rain water is the only available potable water resource within this region, volcanic impacts on drinking water constitutes a major potential hazard to public health within the region. During the 2010 eruption, concerns were expressed by local inhabitants about water quality and feelings of physical discomfort (e.g. nausea, bloating, indigestion, etc.) after consuming rain water collected after the eruption began. We present the elemental and ionic chemistry of drinking water samples collected within the region on the third day of the eruption (January 5, 2010). We identify a significant impact on water quality associated with the eruption including lower pH (i.e. acidification) and increases in acidic halogens (e.g. F(-) and Cl(-)), major ions (e.g. SO(4)(2-), NH(4)(+), Na(+), Ca(2+)), potentially toxic metals (e.g. Al(3+), Mn(2+), Cd(2+), Pb(2+), Hf(4+)), and particulate load. In many cases, the waters composition significantly exceeds World Health Organization (WHO) drinking water standards. The degree of pollution depends upon: (1) ash plume direction and (2) ash plume density. The potential negative health impacts are a function of the waters pH, which regulates the elements and their chemical form that are released into drinking water.

Radon hazard in shallow groundwaters: Amplification and long term variability induced by rainfall

(222)Rn concentrations have been determined with a RAD7 radon detector in shallow groundwaters of the Pietramelara Plain, north-western Campania, southern Italy, where pyroclastic deposits, along with recent stream alluvial sediments, come in contact with Mesozoic carbonate reservoirs. The aim of this study has been to study the annual variation of (222)Rn concentration in the shallow groundwaters, scarcely considered in the literature and of obvious relevance for radon hazard evaluation. Our results definitely show that (222)Rn levels are characterized by a clear annual periodicity, strictly related to rainfall and water table levels, with a pronounced difference between the dry and the wet season. In this last case with concentrations increasing up to two orders of magnitude (up to two times the lower threshold given in the Recommendation 2001/928/EURATOM for public waters). In relation to this, experimental field data will be presented to demonstrate that this variability is due to purely hydrological mechanisms, mainly rinse out and discharge that control leaching efficiency. The detected cycle (Radon Hydrological Amplification Cycle, RHAC) has been generalized for the Mediterranean Tyrrhenian climate. The marked and seasonally persistent amplification in (222)Rn levels poses the problem of evaluating the epidemiological risk brought up by this previously not yet reported mechanism. This mechanism, occurring in shallow groundwaters, very likely should strongly influence indoor radon levels via groundwater-soil-building exchange.

Radon hazard in shallow groundwaters II: Dry season fracture drainage and alluvial fan upwelling

²²²Rn concentrations have been measured in a well located on the edge of a large Pleistocene-Holocene fan and belonging to the shallow pyroclastic aquifer of the Pietramelara Plain, southern Italy. The aim of this study has been both to characterise the hydrological inputs that determine the influx of ²²²Rn to the shallow aquifer and to understand the correlations between ²²²Rn, major ions, physical-chemical parameters and rainfall. Results obtained from the time series indicate that the studied well shows a ²²²Rn variability that is inconsistent with a mechanism of pure hydrological amplification, such as described in Radon hazard in shallow groundwaters: Amplification and long term variability induced by rainfall (De Francesco et al., 2010a). On the contrary, in this well hydrological amplification appears to be mainly tied to the upwelling of alluvial fan waters, rich in radon, in response to pistoning from recharge in the carbonate substrate. This upwelling of alluvial fan waters occurs during almost the whole period of the annual recharge and is also responsible of the constant increase in ²²²Rn levels during the autumn-spring period, when both the water table level and weekly rainfall totals drop. Furthermore, a rapid delivery mechanism for ²²²Rn likely operates through fracture drainage in concomitance with the very first late summer-early autumn rains, when rainfall totals appear largely insufficient to saturate the soil storage capacity. Results obtained from this study appear to be particularly significant in both radon hazard zoning in relation to the shallow aquifer and possibly also for indoor radon, owing to possible shallow aquifer-soil-building exchanges. Moreover, both the spike-like events and the long wave monthly scale background fluctuations detected can also have potential significance in interpreting ²²²Rn time series data as seismic and/or volcanic precursors. Finally, ²²²Rn has proved to be an excellent tracer for hydrological inputs to the shallow aquifer when combined with major ions, physical-chemical data and geological and geomorphological controls.

Measurement of the transfer function of the steering filter of the Virgo super attenuator suspension

The optical elements of the Virgo antenna are supported and isolated from seismic noise disturbances by super attenuator (SA) suspensions. The steering filter (SF) is a component of the SA, designed for the mirror control. The dynamical properties of the SF are described by transfer functions, which have been measured in order to define the control strategy; the results have made it possible to set and tune the parameters of a simulation of the SA. The measuring devices were linear voltage differential transducers: they were found to be quite effective and flexible in usage. An auto-regressive model was used to fit the experimental data, implementing the linear relation between the input forces and the resulting motion. The ability of the model to reproduce the experimental behavior was a clear indication of the good data quality, showing that the contaminating noise was under control. The simulation was able to reproduce the qualitative behavior, and the simulation parameters were estimated, with 10% and...

The VIRGO interferometer for gravitational wave detection.

The Virgo gravitational wave detector is an interferometer with 3 km long arms in construction near Pisa in Italy. The accessible sources at the design sensitivity and main noises are reviewed. Virgo has devoted a significant effort to extend sensitivity to low frequency reaching the strain level h = 10−21 Hz−1/2 at 10 Hz while at 200 Hz h = 3 · 10−23 Hz−1/2. Design choices and status of construction are presented.

Inorganic contaminants from diffuse pollution in shallow groundwater of the Campanian Plain (Southern Italy). Implications for geochemical survey.

The Campanian Plain (CP) shallow aquifer (Southern Italy) represents a natural laboratory to validate geochemical methods for differentiating diffuse anthropogenic pollution from natural water-rock interaction processes. The CP is an appropriate study area because of numerous potential anthropogenic pollution vectors including agriculture, animal husbandry, septic/drainage sewage systems, and industry. In order to evaluate the potential for geochemical methods to differentiate various contamination vectors, 538 groundwater wells from the shallow aquifer in Campanian Plain (CP) were sampled. The dataset includes both major and trace elements. Natural water-rock interactions, which primarily depend on local lithology, control the majority of geochemical parameters, including most of the major and trace elements. Using prospective statistical methods in combination with the traditional geochemical techniques, we determined the chemical variables that are enriched by anthropogenic contamination (i.e. NO3, SO4 and U) by using NO3 as the diagnostic variable for detecting polluted groundwater. Synthetic agricultural fertilizers are responsible for the majority of SO4 and U pollution throughout the CP area. Both SO4 and U are present in the groundmass of synthetic fertilizers; the uranium concentration is specifically applicable as a tracer for non-point source agricultural fertilizer contamination. The recognition of non-geological (anthropogenic) inputs of these elements has to be considered in the geochemical investigations of contaminated aquifers.

First joint gravitational wave search by the AURIGA-EXPLORER-NAUTILUS-Virgo Collaboration

We present a methodology of network data analysis applied to the search for coincident burst excitations over a 24 h long data set collected by AURIGA, EXPLORER, NAUTILUS and Virgo detectors during September 2005. The search of candidate triggers was performed independently on each of the data sets from single detectors. We looked for two-fold time coincidences between these candidates using an algorithm optimized for a given population of sources and we calculated the efficiency of detection through injections of templated signal waveforms into the streams of data. To this end we have considered the case of signals shaped as damped sinusoids coming from the galactic center direction. Our method targets an optimal balance between high efficiency and low false alarm rate, aiming at setting confidence intervals as stringent as possible in terms of the rate of the selected source models.

Geolithological and anthropogenic controls on the hydrochemistry of the Volturno River (Southern Italy)

The present work aims to study the main chemical and physical water parameters in the upper and middle Volturno River catchment (southern Italy), between the Capo Volturno Springs and the confluence with the Calore River. This study makes use of morphology, geolithology, tectonic, land-use and physico-chemical (pH, EC, Eh, Temperature, major ions and 222Rn) data for the identification of the main sources of surface and ground waters in the Volturno catchment and of their evolution and mixing both in base flow and peak flow conditions. The study was also performed to assess whether the alteration due to potential anthropogenic contamination may hamper the identification of natural “primitive” sources of surface waters, especially in the populated and farmed plains far from the river headwaters. Our data suggests that water chemistry of this stretch of the Volturno River is dominated mainly by lithology and, only marginally, by the intense exogenous activities and that this trend is appreciable in both base flow and peak flow conditions. The proposed simple geochemical approach based on easy-to-sample matrices and on cost-effective standard methods, is a valuable tool to address catchment functionality especially in upland areas, where complex geologic and structural settings, heterogeneous groundwater flow and logistical issues are the rule rather than the exception. Since the upper and middle Volturno catchment is comparable to numerous valleys of the Mediterranean area, this study could be a reference for analogous applications. This article is protected by copyright. All rights reserved.

Differentiating natural and anthropogenic impacts on water quality in a hydrothermal coastal aquifer (Mondragone Plain, Southern Italy)

Groundwater from the Mondragone Plain (Southern Italy) has been investigated by a monthly sampling regimen over the course of a hydrologic year in order to analyze geochemical signatures and has been experienced methods for detecting natural and anthropogenic contamination dynamics that affect resources for human water supply. The Mondragone Plain aquifer is characterized by (1) anthropogenic land uses, (2) varying degrees of hydrothermal interactions, and (3) the potential for seawater intrusion. Anomalies induced by anthropogenic pollution produce non-normally distributed time series and an alteration of the natural SO42− background of groundwater. Variables depending on natural processes are related to water–rock interactions along groundwater flow path, i.e., the hosting aquifer lithology of hydrothermal systems, the recharging massifs of Mt. Petrino and Mt. Massico, and more recent volcanic and alluvial formations. Solute transport in groundwater affects the urban aquifer, both by mixing of thermal waters and by ions deriving from agricultural activity (NO3−, SO42−, NH4+), compromising the quality of a resource largely used by locals. The two thermal systems in the studied area [Levagnole and Padule–San Rocco] are two different aquifers with an independent circulation and chemical composition. Seawater intrusion, both into thermal systems and into shallow aquifers, seems to be unlikely despite the detected increase of salinity in the LEV system close to the shoreline.

Multivariate statistical analysis to characterize/discriminate between anthropogenic and geogenic trace elements occurrence in the Campania Plain, Southern Italy

Shallow aquifers are the most accessible reservoirs of potable groundwater; nevertheless, they are also prone to various sources of pollution and it is usually difficult to distinguish between human and natural sources at the watershed scale. The area chosen for this study (the Campania Plain) is characterized by high spatial heterogeneities both in geochemical features and in hydraulic properties. Groundwater mineralization is driven by many processes such as, geothermal activity, weathering of volcanic products and intense human activities. In such a landscape, multivariate statistical analysis has been used to differentiate among the main hydrochemical processes occurring in the area, using three different approaches of factor analysis: (i) major elements, (ii) trace elements, (iii) both major and trace elements. The elaboration of the factor analysis approaches has revealed seven distinct hydrogeochemical processes: i) Salinization (Cl-, Na+); ii) Carbonate rocks dissolution; iii) Anthropogenic inputs (NO3-, SO42-, U, V); iv) Reducing conditions (Fe2+, Mn2+); v) Heavy metals contamination (Cr and Ni); vi) Geothermal fluids influence (Li+); and vii) Volcanic products contribution (As, Rb). Results from this study highlight the need to separately apply factor analysis when a large data set of trace elements is available. In fact, the impact of geothermal fluids in the shallow aquifer was identified from the application of the factor analysis using only trace elements. This study also reveals that the factor analysis of major and trace elements can differentiate between anthropogenic and geogenic sources of pollution in intensively exploited aquifers.