E.L. Silva

All-Diamond Microelectrodes as Solid State Probes for Localized Electrochemical Sensing

The fabrication of an all-diamond microprobe is demonstrated for the first time. This ME (microelectrode) assembly consists of an inner boron doped diamond (BDD) layer and an outer undoped diamond layer. Both layers were grown on a sharp tungsten tip by chemical vapor deposition (CVD) in a stepwise manner within a single deposition run. BDD is a material with proven potential as an electrochemical sensor. Undoped CVD diamond is an insulating material with superior chemical stability in comparison to conventional insulators. Focused ion beam (FIB) cutting of the apex of the ME was used to expose an electroactive BDD disk. By cyclic voltammetry, the redox reaction of ferrocenemethanol was shown to take place at the BDD microdisk surface. In order to ensure that the outer layer was nonelectrically conductive, a diffusion barrier for boron atoms was established seeking the formation of boron-hydrogen complexes at the interface between the doped and the undoped diamond layers. The applicability of the microelectrodes in localized corrosion was demonstrated by scanning amperometric measurements of oxygen distribution above an Al-Cu-CFRP (Carbon Fiber Reinforced Polymer) galvanic corrosion cell.

Novel electrochemical method of fast and reproducible fabrication of metallic nanoelectrodes

A novel electrochemical wire etching method of fabrication of ultrasharp nanoelectrodes is reported. Tungsten wires can be sharpened to less than 10 nm tip radius in a reproducible manner in less than 1 min by using controllable hydrodynamic electrolyte flow combined with optimized electrochemical etching parameters. The method relies on the variations of the electric field at the surface of a metal wire, while the electrolyte solution is in motion, rather than on the ionic gradient generated in a static solution.

Interfacing metallic ohmic contacts in biocompatible ceramic substrates with diamond surfaces for biosensing applications

The development of biosensors for in vivo applications requires the deposition of metallic contacts on biofunctionalized, biocompatible surfaces. For improved performance the metallic contacts should not interfere with the biosensing zone of the sensors. Owing to their biological compatibility with human tissues and fluids, diamond, titanium and silicon nitride ceramics (Si3N4) are potential candidates to be incorporated in implantable biosensors. The easy formation of titanium carbide under carbon saturated atmospheres, make titanium the right choice for diamond nucleation and growth. The same applies to the well studied Si3N4 ceramics used as substrates for diamond growth. The fabrication of biocompatible ceramic substrates with incorporated titanium contacts and chemically vapour deposited low resistivity boron doped diamond surfaces is the aim of the present work.

The Reduction of Dissolved Oxygen During Magnesium Corrosion

Abstract The consumption of dissolved oxygen (DO) during the corrosion of commercially pure magnesium specimens was investigated by localized corrosion techniques. The concentration of oxygen and the local current density on the near‐surface of magnesium were measured simultaneously by a micro‐optode DO sensor and the scanning vibrating electrode technique (SVET), respectively. Diamond microelectrodes were also used for DO mapping. Significant DO depletion was found since the initial immersion time of Mg in NaCl 0.5 m, and a correlation could be established between DO consumption and areas of anodic and cathodic activity. These findings assume particular relevance for the corrosion of Mg alloys or magnesium components with impurity levels higher than the tolerance limit. Moreover, this study points out the significance of the partial oxygen pressure as an influential parameter during magnesium corrosion.