E. Z. Gareev

Fine-Grained Aluminosiliciclastic Rocks of the Middle Riphean Stratotype Section in the Southern Urals: Formation Conditions, Composition and Provenance Evolution

General trends of the formation of Middle Riphean fine-grained aluminosiliciclastic rocks in the Bashkir Meganticlinorium are considered. It is shown that Yurmatinian shales do not contain any significant pyroclastic admixture. Judging from the relatively constant Th/Cr ratio throughout the Yurmatinian section, the tectonic regime in the study territory during the early Middle Riphean is suggested to be rather stable. The main paleoclimatic indices and indicators of the pelitic material maturity (CIA, CIW, IVC, PIA, and ΣCe/ΣY) suggest that paleodrainage systems in the early Middle Riphean were dominated by humid climate that gave way to the arid or semiarid type in the middle Yurmatinian. The low Mo/Mn ratio and some other indicators of redox conditions in shales from all Yurmatinian lithostratigraphic units show that no explicit reducing conditions existed in the basin during the early Middle Riphean. The shales were characterized by the increase in K2O/Al2O3 ratio, gradual enrichment in REE, and growth of LREE/HREE and LaN/YbN ratios toward the middle Yurmatinian, indicating the gain of an appreciable amount of slightly weathered arkosic aluminosiliciclastic material in the sedimentary basin about 1220–1200 Ma ago. The REE distribution and the UCC- and AUC-normalized shale compositions suggest that the eroded upper crust was compositionally close to the UCC. The occurrence of mafic and ultramafic rocks is also inferred. Data points of Yurmatinian shales plotted in the Cr–Ni, Eu/Eu*–GdN/YbN, and (La/YB)N–YbN diagrams are localized between the fields of Upper Archean and post-Archean rocks or within the latter field. Hence, post-Archean igneous and metamorphic complexes prevailed in paleodrainage systems of the early Middle Riphean. This is also confirmed by the model Nd ages.

Synorogenic psammites: Major lithochemical features

Some lithochemical features of sandstone associations formed at the orogenic stage of the evolution of mobile belts are analyzed on the basis of literature and original data along with the wide application of discrimination diagrams. Psammites of the flysch and molasse formations of foreland basins, as well as sand-stones from intermontane troughs and postcollisonal grabens, are considered synorogenic sediments. Analysis of the chemical composition showed that sandstones were formed by the mixing of clastic material from heterogeneous (proximal included) source areas. In discrimination diagrams, the compositional fields of sandstones are variable, because they were derived from diverse igneous, metamorphic, and sedimentary rocks of different geodynamic settings. Hence, data based on the generally accepted discrimination diagrams cannot be considered as the single (decisive) argument for establishing the geodynamic nature of sandstones without the consideration of textural-structural features of rocks and the analysis of geological structure of sedimentary associations therein.

Upper Riphean and Vendian sandstones of the Bashkirian anticlinorium

The analysis of lithogeochemical data on the Upper Riphean and Vendian sandstones from the Bashkirian anticlinorium showed that sandstone associations formed in a passive sluggish tectonic regime in the middle Late Vendian were replaced by associations accumulated in the more active tectonic settings. This is well seen in the SiO2-K2O/Na2O and (Fe2O3* + MgO)-TiO2 diagrams reflecting the particular and median compositions of psammites. The lithochemical characteristics of sandstones were examined to determine the compositional variation of rock complexes eroded on paleodrainage areas. Quartz-rich sedimentary, metasedimentary, and metamorphic rocks, as well as felsic igneous rocks prevailed in the paleodrainage areas throughout the entire Late Riphean and Early Vendian, while the main sources of clastic material in the Late Vendian were igneous intermediate and basic rocks. With allowance made for the previous comparative-lithological data and some other materials, significant similarity in the position and orientation of compositional fields of psammites from the middle and upper levels of the Asha Group (Bashkirian anticlinorium) with fields of psammites from different syncollisional (flysch and molasse) basins in the SiO2-K2O/Na2O, K2O/Na2O-SiO2/Al2O3, F1–F2 and other diagrams suggests that the middle Late Vendian (beginning from the Basa level) was marked by a variation in tectonic/geodynamic settings of sandstone accumulation and in composition of the eroded paleodrainage systems. The revealed trend agrees well with concept of the existence of the Late Riphean-Vendian Pechora paleocean.

Synorogenic clay rocks: Specifics of bulk composition and paleotectonics

The paper is devoted to the specifics in the chemical composition of synorogenic clay rocks in various environments: the Ural foredeep, Olyutorskii terrane, Dnestr pericratonic trough, Indus-Gang trough, etc. The compositions of the rocks are plotted in conventionally utilized discriminant paleotectonic diagrams. It is demonstrated that the bulk composition of such rocks, which were formed under active tectonic conditions typical of the collisional evolutionary phase of mobile belts, reflects the nature of the rock assemblages produced during both the divergent and the convergent (including collisional) phases. Their mean composition is the closest to PAAS as an integrated parameter of the average composition of the continental crust. The materials presented in the publication suggest that data on the bulk composition of clay rocks shown in conventionally utilized discriminant diagrams, such as SiO2-K2O/Na2O, K2O/Na2O-SiO2/Al2O3, are insufficient to reproduce the tectonic environments in which these rocks were formed.

Provenance Composition and Features of Geological Evolution of the Late Vendian Foreland Basin of the Timan Orogen

The provenance composition and geological evolution of different segments in the distal zone of the Late Vendian foreland basin of the Timan orogen were deciphered on the basis of sequence stratigraphic reconstructions and precision geochemical data on the Upper Vendian fine-grained terrigenous rocks from the Southeast White Sea region, Vychegda, Verkhnekama, and Shkapovo-Shikhan basins, and the Kvarkush-Kamennogorsk and Bashkirian meganticlinoriums. The Upper Vendian of the Southeast White Sea region is subdivided into four sequences: Agma, Solza, Zimnie Gory, and Erga. The tracing of sequence boundaries and lateral facies associations from the Southeast White Sea Region to the South Urals made it possible to identify the main stages of the evolution of sedimentary filling of the foreland basin: (I) shallow water epiplatformal basin, (II) isolated basin, (III) lowstand system tract, and (IV) progradation of delta platforms. Position of data points of the Upper Vendian shales, silty mudstones, and mudstones plotted in the diagrams Th-La, Ni-Cr, GdN/YbN-Eu/Eu*, Sc-Th/Sc, La/Sm-Sc/Th, and Co/Hf-Ce/Cr, together with their REE systematics and data on Nd model ages indicates that the Proterozoic, including Neoproterozoic rocks of the Timan thrust-folded belt served as the main source for fine aluminosiliciclastic material in the distal zones of the Timan foreland basin. Obtained results are consistent with the concept that the Vendian stage of the evolution of the Eastern European platform is related to the intense input of allochthonous material in its peripheral area owing to the activation of orogenic processes in the adjacent mobile belts and allow us to significantly specify the paleogeographical reconstructions.

Lithological, Lithochemical, and Geochemical Indicators of Paleoclimate: Evidence from Riphean of the Southern Urals

Complex lithological, lithochemical, and geochemical data are commonly considered necessary for the reliable reconstruction of Late Precambrian climatic parameters. However, correlation of results deduced from different methods is becoming a more and more topical task. In this paper, we compare paleoclimatic data obtained with various lithological, lithochemical, and geochemical methods for the Riphean stratotype section on the western slope of the southern Urals. The results obtained turned out to be generally convergent, but, paleoclimatic reconstructions based on different methods are directly opposite to each other at some stratigraphic levels. Most likely, the controversy is probably caused by underestimation of recycling effects and incorrect extrapolation of conclusions related to the first-cycle sediments over the rocks that underwent multifold redeposition. Criteria for the recognition of recycled sedimentary units show that more than half of the Riphean stratotype section is composed of recycled materials. Hence, application of standard litho- and geochemical methods (CIA index and others) to these units yields virtual models only remotely resembling the reality rather than actual paleoclimatic indicators. Elaboration of new methods, which make it possible to avoid such errors, is a problem of in the near future.

Tectonic setting discrimination diagrams for terrigenous rocks: a comparison

An attempt is made to compare discrimination diagrams of the first (mid-1980s) and second (early 2010s) generations compiled using data for sedimentary successions of different ages. Our results suggest that the diagrams of different generations allow more or less correct discrimination only between the platform, rift, passive margin, and island arc settings. The data for collision sediments do not form separate fields in these diagrams.

Riphean fine-grained aluminosilicate clastic rocks in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh: Principal litho-geochemical characteristics

Analysis of the litho-geochemistry of fine-grained terrigenous rocks (metapelites, shales, and mudstones) of sedimentary megasequences in the Southern Urals, Uchur-Maya area, and the Yenisei Kryazh indicates that Riphean sequences in these regions are dominated by chlorite-hydromica rocks, with montmorillonite and potassic feldspar possibly occurring only in some of the lithostratigraphic units. According to the values of their hydrolysate modulus, most clay rocks from the three Riphean metamorphosed sedimentary sequences are normal or supersialites, with hydrosialites and hydrolysates playing subordinate roles. The most lithochemicaly mature rocks are Riphean clays in the Yenisei Kryazh (Yenisei Range). The median value of their CIA is 72, whereas this index is 70 for fine-grained aluminosilicate rocks from the Uchur-Maya area and 66 for fine-grained terrigenous rocks of the Riphean stratotype. Hence, at ancient water provenance areas from which aluminosilicate clastic material was transported in sedimentation basins in the southwestern (in modern coordinates) periphery of the Siberian Platform, the climate throughout the whole Riphean was predominantly humid. At the same time, the climate at the eastern part of the East European Platform was semiarid-semihumid. The K2O/Al2O3 ratio, which is employed as an indicator of the presence of petro-and lithogenic aluminosilicate clastic component in Riphean sedimentary megasequences, shows various tendencies. According to their Sc, Cr, Ni, Th, and La concentrations and the Th/Sc ratio, the overwhelming majority of Riphean shales and mudstones notably differ from the average Archean mudstone and approach the average values for post-Archean shales. This suggests that mafic Archean rock in the provenance areas did not play any significant role in the origin of Riphean sedimentary megasequences. The Co/Hf and Ce/Cr ratios of the terrigenous rocks of the three Riphean megaseqeunces and their (Gd/Yb)N and Eu/Eu* ratios place these rocks among those containing little (if any) erosion products of primitive Archean rocks. According to various geochemical data, the source of the great majority of fine-grained aluminosilicate clastic rocks in Riphean sediment megasequences in our study areas should have been mature sialic (felsic), with much lower contents of mafic and intermediate rocks as a source of the clastic material. The REE patterns of the Riphean shales and metapelites in the Bashkir Meganticlinorium, Uchur-Maya area, and Yenisei Kryazh show some features that can be regarded as resulting from the presence of mafic material in the ancient provenance areas. This is most clearly seen in the sedimentary sequences of the Uchur-Maya area, where the decrease in the (La/Yb)N ratio up the sequence of the fine-grained terrigenous rocks from 15–16.5 to 5.8–7.1 suggests that mantle mafic volcanics were brought to the upper crust in the earliest Late Riphean in relation to rifting. Analysis of the Sm-Nd systematics of the Riphean fine-grained rocks reveals the predominance of model age values in the range of 2.5–1.7 Ga, which can be interpreted as evidence that the rocks were formed of predominantly Early Proterozoic source material. At the same time, with regard for the significant role of recycling in the genesis of the upper continental crust, it seems to be quite possible that the ancient provenance areas contained Archean complexes strongly recycled in the Early Proterozoic and sediments formed of their material. An additional likely source of material in the Riphean was mafic rocks, whose variable contribution is reflected in a decrease in the model age values. Higher Th and U concentrations in the Riphean rocks of the Yenisei Kryazh compared to those in PAAS indicate that the sources of their material were notably more mature than the sources of fine-grained aluminosilicate clastic material for the sedimentary megaseqeunces in the Southern Urals and Uchur-Maya area.

Geochemical Features of the Riphean Fine-Grained Terrigenous Rocks of the Southern Urals, Uchur-Maya Region, and Yenisei Range: Estimation of the Maturity of the Pre-Riphean Continental Crust and Its Evolution within 1.65-0.6 Ga

The geochemical features of basal fine-grained terrigenous rocks from the Riphean sedimentary megasequences of the Southern Urals, Uchur-Maya region, and Yenisei Range were compared in order to estimate the maturity of the continental crust that was formed by the beginning of the Riphean. It was shown that initial shales from the base of the Riphean sequence of the Yenisei Range and fine-grained aluminosiliciclastic rocks from the base of the Riphean sections of the Southern Urals were formed by the erosion of a rather mature continental crust. In contrast, fine-grained terrigenous rocks from the base of the Riphean of the Uchur-Maya region were derived from immature Late Archean protoliths or their Early Proterozoic analogs. The fine-grained terrigenous rocks of the three sedimentary megasequences show different variations in the (La/Yb)N ratio. In the Southern Urals, this ratio is high (12–15) in the Burzyan Group and decreases upsection to 6–10. In the shales of the Uchur-Maya region, the (La/Yb)N ratio decreases upsection, and the La/Sc ratio shows a sympathetic behavior. This is due to a decrease in the proportion of “primitive” tonalite-trondhjemite associations of the Archean granite-greenstone terranes in the provenance area with time and the appearance of intra-plate (riftogenic?) granitoids and significant amounts of basic and ultrabasic rocks. The latter marks the onset of large rift-forming events in the Uchur-Maya region at the beginning of the Late Riphean. The (La/Yb)N of the studied rocks from the Yenisei Range are mostly similar to the PAAS ratio, but higher values were found in the Upper Vorogovka and Chingasan groups, which was related to the contribution of strongly LREE-enriched granitoids and rift felsic and alkali basaltic volcanic associations to the formation of the terrigenous material. A comparison of Rb, Sr, Y, Zr, Ba, Hf, Th, U, Cr, and Ni contents and Zr/Y, (La/Yb)N, Ni/Co, Cr/Th, Cr/Sc, and La/Th ratios in the fine-grained terrigenous rocks of the Riphean megasequences of the Southern Urals, Uchur-Maya region, and the Yenisei Range with those in the model geochemical objects (PAAS, UCPR1, UCAR2, and others) showed that, in terms of most of the parameters, the Riphean fine-grained terrigenous rocks from the three regions are similar to each other, PAAS, and Proterozoic cratonic shales. This indicates a fairly high general maturity of the protoliths that were eroded during the Riphean in the eastern East European craton and in the southeastern and southwestern parts of the Siberian craton.

Secular Variations of the Upper Crust Composition: Implication of Geochemical Data on the Upper Precambrian Shales from the Southern Urals Western Flank and Uchur-Maya Region

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.