Eduardo J. Garcia Suarez
Technical University of Denmark
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Dalton Transactions | 2006
Claudio Bianchini; Peter Brüggeller; Carmen Claver; Georg Czermak; Alexander Dumfort; Andrea Meli; Werner Oberhauser; Eduardo J. Garcia Suarez
The bis-cationic diphosphonium-diphosphine 6,7-di(di-2-methoxyphenyl)phosphinyl-2,2,4,4-tetra(di-2-methoxyphenyl)-2 lambda 4,4 lambda 4-diphosphoniumbicyclo[3.1.1]heptane-bis(PF6) ((o-MeO-PCP)(PF6)2) and the diphosphine rac-2,4-bis((di-2-methoxyphenyl)phosphino)pentane (rac-o-MeO-bdpp) have been synthesized. Both ligands have been employed to coordinate PdCl2 and Pd(OAc)2 to give [PdCl2(o-MeO-PCP)](PF6)2 (1a), PdCl2(rac-o-MeO-bdpp) (1b), [Pd(OAc)2(o-MeO-PCP)](PF6)2 (2a) and Pd(OAc)2(rac-o-MeO-bdpp) (2b). The ligands and complexes have been fully characterized in solution by multinuclear NMR spectroscopy. In addition, 1a and 1b have been authenticated by single crystal X-ray structure analyses. The Pd(II) complexes 1a and 1b have been employed as catalyst precursors for the CO/ethene copolymerisation in water-acetic acid mixtures, while 2a and 2b have been tested in methanol in the presence of p-toluenesulfonic acid. Irrespective of the reaction media, perfectly alternating polyketones were obtained in excellent yields and with number-average molecular weights ranging from 7.1-13.9 kg mol(-1) with the diphosphonium-diphosphine catalysts and from 37.2-48.2 kg mol(-1) with the diphosphine catalysts.
European Journal of Inorganic Chemistry | 2007
Eduardo J. Garcia Suarez; Cyril Godard; Aurora Ruiz; Carmen Claver
Dalton Transactions | 2007
Lorenzo Bettucci; Claudio Bianchini; Carmen Claver; Eduardo J. Garcia Suarez; Aurora Ruiz; Andrea Meli; Werner Oberhauser
Journal of Molecular Catalysis A-chemical | 2007
Claudio Bianchini; Andrea Meli; Werner Oberhauser; Anna M. Segarra; Carmen Claver; Eduardo J. Garcia Suarez
European Journal of Inorganic Chemistry | 2007
Claudio Bianchini; Andrea Meli; Werner Oberhauser; Carmen Claver; Eduardo J. Garcia Suarez
Dalton Transactions | 2007
Eduardo J. Garcia Suarez; Aurora Ruiz; Sergio Castillón; Werner Oberhauser; Claudio Bianchini; Carmen Claver
Archive | 2010
Anders Riisager; Rasmus Fehrmann; Jianmin Xiong; Eduardo J. Garcia Suarez
Chemcatchem | 2018
Nanette Zahrtmann; Carmen Claver; Cyril Godard; Anders Riisager; Eduardo J. Garcia Suarez
Sustainability | 2017
Jakob Maximilian Marinkovic; A. Weiss; Eduardo J. Garcia Suarez; Marco Haumann; Anders Riisager; Rasmus Fehrmann
DTU Chemistry's Annual PhD Symposium 2017 | 2017
Jakob Maximilian Marinkovic; Alexander Weiß; Eduardo J. Garcia Suarez; Marco Haumann; Anders Riisager; Rasmus Fehrmann