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Dive into the research topics where Eduardo J. Garcia Suarez is active.

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Featured researches published by Eduardo J. Garcia Suarez.


Dalton Transactions | 2006

Synthesis and characterization of palladium(II) complexes with new diphosphonium-diphosphine and diphosphine ligands. Production of low molecular weight alternating polyketones via catalytic CO/ethene copolymerisation

Claudio Bianchini; Peter Brüggeller; Carmen Claver; Georg Czermak; Alexander Dumfort; Andrea Meli; Werner Oberhauser; Eduardo J. Garcia Suarez

The bis-cationic diphosphonium-diphosphine 6,7-di(di-2-methoxyphenyl)phosphinyl-2,2,4,4-tetra(di-2-methoxyphenyl)-2 lambda 4,4 lambda 4-diphosphoniumbicyclo[3.1.1]heptane-bis(PF6) ((o-MeO-PCP)(PF6)2) and the diphosphine rac-2,4-bis((di-2-methoxyphenyl)phosphino)pentane (rac-o-MeO-bdpp) have been synthesized. Both ligands have been employed to coordinate PdCl2 and Pd(OAc)2 to give [PdCl2(o-MeO-PCP)](PF6)2 (1a), PdCl2(rac-o-MeO-bdpp) (1b), [Pd(OAc)2(o-MeO-PCP)](PF6)2 (2a) and Pd(OAc)2(rac-o-MeO-bdpp) (2b). The ligands and complexes have been fully characterized in solution by multinuclear NMR spectroscopy. In addition, 1a and 1b have been authenticated by single crystal X-ray structure analyses. The Pd(II) complexes 1a and 1b have been employed as catalyst precursors for the CO/ethene copolymerisation in water-acetic acid mixtures, while 2a and 2b have been tested in methanol in the presence of p-toluenesulfonic acid. Irrespective of the reaction media, perfectly alternating polyketones were obtained in excellent yields and with number-average molecular weights ranging from 7.1-13.9 kg mol(-1) with the diphosphonium-diphosphine catalysts and from 37.2-48.2 kg mol(-1) with the diphosphine catalysts.


European Journal of Inorganic Chemistry | 2007

Alternating and Non-Alternating Pd-Catalysed Co- and Terpolymerisation of Carbon Monoxide and Alkenes

Eduardo J. Garcia Suarez; Cyril Godard; Aurora Ruiz; Carmen Claver


Dalton Transactions | 2007

Ligand effects in the non-alternating CO–ethylene copolymerization by palladium(II) catalysis

Lorenzo Bettucci; Claudio Bianchini; Carmen Claver; Eduardo J. Garcia Suarez; Aurora Ruiz; Andrea Meli; Werner Oberhauser


Journal of Molecular Catalysis A-chemical | 2007

CO-ethylene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups

Claudio Bianchini; Andrea Meli; Werner Oberhauser; Anna M. Segarra; Carmen Claver; Eduardo J. Garcia Suarez


European Journal of Inorganic Chemistry | 2007

Unraveling the o-Methoxy Effect in the CO/Ethene Copolymerization Reaction by Diphosphanepalladium(II) Catalysis

Claudio Bianchini; Andrea Meli; Werner Oberhauser; Carmen Claver; Eduardo J. Garcia Suarez


Dalton Transactions | 2007

New alkyl derivatives phosphine sulfonate (P–O) ligands. Catalytic activity in Pd-catalysed Suzuki–Miyaura reactions in water

Eduardo J. Garcia Suarez; Aurora Ruiz; Sergio Castillón; Werner Oberhauser; Claudio Bianchini; Carmen Claver


Archive | 2010

Palladium catalyst system comprising zwitterion and/or acid-functionalized ionic liquid

Anders Riisager; Rasmus Fehrmann; Jianmin Xiong; Eduardo J. Garcia Suarez


Chemcatchem | 2018

Selective Oxidative Carbonylation of Aniline to Diphenylurea with Ionic Liquids

Nanette Zahrtmann; Carmen Claver; Cyril Godard; Anders Riisager; Eduardo J. Garcia Suarez


Sustainability | 2017

Hydroformylation with Integrated Catalytic-Membrane Separation Reaction System

Jakob Maximilian Marinkovic; A. Weiss; Eduardo J. Garcia Suarez; Marco Haumann; Anders Riisager; Rasmus Fehrmann


DTU Chemistry's Annual PhD Symposium 2017 | 2017

ROMEO: a new reactor concept for hydroformylation process intensification

Jakob Maximilian Marinkovic; Alexander Weiß; Eduardo J. Garcia Suarez; Marco Haumann; Anders Riisager; Rasmus Fehrmann

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Anders Riisager

Technical University of Denmark

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Rasmus Fehrmann

Technical University of Denmark

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Aurora Ruiz

University of Barcelona

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Marco Haumann

University of Erlangen-Nuremberg

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Alexander Weiß

University of Erlangen-Nuremberg

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