Elizabeth H. Steenbergen

Measurement of InAsSb bandgap energy and InAs/InAsSb band edge positions using spectroscopic ellipsometry and photoluminescence spectroscopy

The structural and optical properties of lattice-matched InAs0.911Sb0.089 bulk layers and strain-balanced InAs/InAs1−xSbx (xu2009∼u20090.1–0.4) superlattices grown on (100)-oriented GaSb substrates by molecular beam epitaxy are examined using X-ray diffraction, spectroscopic ellipsometry, and temperature dependent photoluminescence spectroscopy. The photoluminescence and ellipsometry measurements determine the ground state bandgap energy and the X-ray diffraction measurements determine the layer thickness and mole fraction of the structures studied. Detailed modeling of the X-ray diffraction data is employed to quantify unintentional incorporation of approximately 1% Sb into the InAs layers of the superlattices. A Kronig-Penney model of the superlattice miniband structure is used to analyze the valence band offset between InAs and InAsSb, and hence the InAsSb band edge positions at each mole fraction. The resulting composition dependence of the bandgap energy and band edge positions of InAsSb are described using the bandgap bowing model; the respective low and room temperature bowing parameters for bulk InAsSb are 938 and 750u2009meV for the bandgap, 558 and 383u2009meV for the conduction band, and −380 and −367u2009meV for the valence band.

Unipolar infrared detectors based on InGaAs/InAsSb ternary superlattices

Growth and characteristics of mid-wave infrared (MWIR) InGaAs/InAsSb strained layer superlattice (SLS) detectors are reported. InGaAs/InAsSb SLSs, identified as ternary SLSs, not only provide an extra degree of freedom for superlattice strain compensation but also show enhanced absorption properties compared to InAs/InAsSb SLSs. Utilizing In1-yGayAs/InAs0.65Sb0.35 ternary SLSs (yu2009=u20090, 5, 10, and 20%) designed to have the same bandgap, a set of four unipolar detectors are investigated. These demonstrate an enhancement in the detector quantum efficiency due to the increased absorption coefficient. The detectors exhibit dark current performance within a factor of 10 of Rule 07 at temperatures above 120u2009K, and external quantum efficiencies in the 15%–25% range. This work demonstrates ternary SLSs are a potential absorber material for future high performance MWIR detectors.

Absorption properties of type-II InAs/InAsSb superlattices measured by spectroscopic ellipsometry

Strain-balanced InAs/InAsSb superlattices offer access to the mid- to long-wavelength infrared region with what is essentially a ternary material system at the GaSb lattice constant. The absorption coefficients of InAs/InAsSb superlattices grown by molecular beam epitaxy on (100)-oriented GaSb substrates are measured at room temperature over the 30 to 800u2009meV photon energy range using spectroscopic ellipsometry, and the miniband structure of each superlattice is calculated using a Kronig-Penney model. The InAs/InAsSb conduction band offset is used as a fitting parameter to align the calculated superlattice ground state transition energy to the measured absorption onset at room temperature and to the photoluminescence peak energy at low temperature. It is observed that the ground state absorption coefficient and transition strength are proportional to the square of the wavefunction overlap and the ground state absorption coefficient approaches a maximum value of around 5780u2009cm−1 as the wavefunction overlap...

A recent review of mid-wavelength infrared type-II superlattices: carrier localization, device performance, and radiation tolerance

The last two decades have seen tremendous progress in the design and performance of mid-wavelength infrared (MWIR) type-II superlattices (T2SL) for detectors. The materials of focus have evolved from the InAs/(In)GaSb T2SL to include InAs/InAsSb T2SLs and most recently InGaAs/InAsSb SLs, with each materials system offering particular advantages and challenges. InAs/InAsSb SLs have the longest minority carrier lifetimes, and their best nBn dark current densities are <5X Rule ’07 at high temperatures, while those of InAs/GaSb SLs and InGaAs/InAsSb SLs are <10X Rule ’07. The quantum efficiency of all three SL detectors can still be improved, especially by increasing the diffusion length beyond the absorber length at low temperatures. Evidence of low temperature carrier localization is greatest for the two SLs containing ternary layers; however, the interface intermixing causing the localization is present in all three SLs. Localization likely does not affect the high temperature detector performance (>120 K) where these SL unipolar barrier detectors are diffusion-limited and Auger-limited. The SL barrier detectors remain diffusion-limited post proton irradiation, but the dark current density increases due to the minority carrier lifetime decreasing with increased displacement damage causing an increase in the trap density. For these SL detectors to operate in space, the continued understanding and mitigation of point defects is necessary.

Absorption characteristics of mid-wave infrared type-II superlattices

Recently, a new strategy used to achieve high operation temperature (HOT) infrared photodetectors including III-V compound materials (bulk materials and type-II superlattices) and cascade devices has been observed. Another method to reduce detector’s dark current is reducing volume of detector material via a concept of photon trapping detector. The barrier detectors are designed to reduce dark current associated with Shockley-Read (SR) processes and to decrease influence of surface leakage current without impeding photocurrent (signal). In consequence, absence of a depletion region in barrier detectors offers a way to overcome the disadvantage of large depletion dark currents. So, they are typically implemented in materials with relatively poor SR lifetimes, such as all III-V compounds. From considerations presented in the paper results that despite numerous advantages of III-V barrier detectors over present-day detection technologies, including reduced tunneling and surface leakage currents, normal-incidence absorption, and suppressed Auger recombination, the promise of a superior performance of these detectors in comparison to HgCdTe photodiodes, has not been yet realized. The dark current density is higher than that of bulk HgCdTe photodiodes, especially in MWIR range. To attain their full potential, the following essential technological limitations such as short carrier lifetime, passivation, and heterostructure engineering, need to be overcome.

Carrier transfer from InAs quantum dots to ErAs metal nanoparticles

Erbium arsenide (ErAs) is a semi-metallic material that self-assembles into nanoparticles when grown in GaAs via molecular beam epitaxy. We use steady-state and time-resolved photoluminescence to examine the mechanism of carrier transfer between indium arsenide (InAs) quantum dots and ErAs nanoparticles in a GaAs host. We probe the electronic structure of the ErAs metal nanoparticles (MNPs) and the optoelectronic properties of the nanocomposite and show that the carrier transfer rates are independent of pump intensity. This result suggests that the ErAs MNPs have a continuous density of states and effectively act as traps. The absence of a temperature dependence tells us that carrier transfer from the InAs quantum dots to ErAs MNPs is not phonon assisted. We show that the measured photoluminescence decay rates are consistent with a carrier tunneling model.

Stability studies of lead sulfide colloidal quantum dot films on glass and GaAs substrates

The stability of colloidal PbS quantum dot (QD) films deposited on various substrates including glass and GaAs was studied. Over a period of months, the QD film sample was re-tested after being left unprotected in air under ambient conditions. Despite exposure to 532 nm laser excitation and cooling to cryogenic temperatures, the initial photoluminescence (PL) remained stable between tests. We also retested a set of samples that had remained under ambient conditions for over 2 years. To track potential changes to the QDs over time, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), powder X-ray diffraction (XRD), optical microscopy, UV-Vis-NIR spectrophotometry and atomic force microscopy (AFM) were employed. Evidence points towards oxidation enforced shrinking of the active QD volume causing a blue shift of the absorption and photoluminescence. The presented studies are important for reliability expectations of light emitters based on PbS QDs.

Proton radiation effects on the photoluminescence of infrared InAs/InAsSb superlattices

Infrared detector arrays operating in space must be able to withstand defect-inducing proton radiation without performance degradation. Therefore, it is imperative that the proton-radiation hardness of infrared detector materials be investigated. Photoluminescence (PL) is sensitive to defects in materials, and thus can be used to quantify the effects of proton-radiation-induced defects. The excitation intensity-dependent PL was used to examine of a set of InAs/InAsSb superlattices before and after 63-MeV-proton irradiation. A proton dose of 100 kRad(Si) was applied to a different piece of each superlattice sample. The low-temperature excitation intensity dependent PL results reveal minimal increases in the carrier concentration, non-radiative recombination, and the PL full-width half-maximum. These results suggest that InAs/InAsSb superlattices are quite tolerant of proton irradiation and may be suitable for space infrared detector arrays.

High quantum efficiency mid-wavelength infrared superlattice photodetector

We report high quantum efficiency (QE) MWIR barrier photodetectors based on the InAs/GaSb/AlSb type II superlattice (T2SL) material system. The nBp design consists of a single unipolar barrier (InAs/AlSb SL) placed between a 4 μm thick p-doped absorber (InAs/GaSb SL) and an n-type contact layer (InAs/GaSb SL). At 80K, the device exhibited a 50% cut-off wavelength of 5 μm, was fully turned-ON at zero bias and the measured QE was 62% (front side illumination with no AR coating) at 4.5 μm with a dark current density of 8.5×10-9 A/cm2 . At 150 K and Vb=50 mV, the 50% cut-off wavelength increased to 5.3 μm and the quantum efficiency (QE) was measured to be 64% at 4.5 μm with a dark current of 1.07×10-4 A/cm2 . The measurements were verified at multiple AFRL laboratories. The results from this device along with the analysis will be presented in this paper.

Growth and characterization of In1-xGaxAs/InAs0.65Sb0.35 strained layer superlattice infrared detectors

Type-II strained layer superlattices (SLS) are an active research topic in the infrared detector community and applications for SLS detectors continue to grow. SLS detector technology has already reached the commercial market due to improvements in material quality, device design, and device fabrication. Despite this progress, the optimal superlattice design has not been established, and at various times has been believed to be InAs/GaSb, InAs/InGaSb, or InAs/InAsSb. Building on these, we investigate the properties of a new mid-wave infrared SLS material: InGaAs/InAsSb SLS. The ternary InGaAs/InAsSb SLS has three main advantages over other SLS designs: greater support for strain compensation, enhanced absorption due to increased electron-hole wavefunction overlap, and improved vertical hole mobility due to reduced hole effective mass. Here, we compare three ternary SLSs, with approximately the same bandgap (0.240 eV at 150 K), comprised of Ga fractions of 5%, 10%, and 20% to a reference sample with 0% Ga. Enhanced absorption is both theoretically predicted and experimentally realized. Furthermore, the characteristics of ternary SLS infrared detectors based on an nBn architecture are reported and exhibit nearly state-of-the-art dark current performance with minimal growth optimization. We report standard material and device characterization information, including dark current and external quantum efficiency, and provide further analysis that indicates improved quantum efficiency and vertical hole mobility. Finally, a 320×256 focal plane array built based on the In0.8Ga0.2As/InAs0.65Sb0.35 SLS design is demonstrated with promising performance.