Eric D. Bloch
Lawrence Berkeley National Laboratory
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Dalton Transactions | 2012
Wendy L. Queen; Eric D. Bloch; Craig M. Brown; Matthew R. Hudson; Jarad A. Mason; Leslie J. Murray; Anibal J. Ramirez-Cuesta; Vanessa K. Peterson; Jeffrey R. Long
The hydrogen storage properties of Fe(2)(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate) and an oxidized analog, Fe(2)(O(2))(dobdc), have been examined using several complementary techniques, including low-pressure gas adsorption, neutron powder diffraction, and inelastic neutron scattering. These two metal-organic frameworks, which possess one-dimensional hexagonal channels decorated with unsaturated iron coordination sites, exhibit high initial isosteric heats of adsorption of -9.7(1) and -10.0(1) kJ mol(-1), respectively. Neutron powder diffraction has allowed the identification of three D(2) binding sites within the two frameworks, with the closest contacts corresponding to Fe-D(2) separations of 2.47(3) and 2.53(5) Å, respectively. Inelastic neutron scattering spectra, obtained from p-H(2) (para-H(2)) and D(2)-p-H(2) mixtures adsorbed in Fe(2)(dobdc), reveal weak interactions between two neighboring adsorption sites, a finding that is in opposition to a previous report of possible pairing between neighboring H(2) molecules.
Catalysis Today | 2015
Pieterjan Valvekens; Eric D. Bloch; Jeffrey R. Long; Rob Ameloot; Dirk E. De Vos
Archive | 2015
Andreas Schneemann; Eric D. Bloch; Sebastian Henke; Philip Llewellyn; Jeffrey R. Long
Abstracts of Papers, 249th ACS National Meeting & Exposition, Denver, CO, United States, March 22-26, 2015 | 2015
Dianne Xiao; Eric D. Bloch; Jarad A. Mason; Wendy L. Queen; Matthew R. Hudson; Nora Planas; Pragya Verma; Donald G. Truhlar; Laura Gagliardi; Craig M. Brown; Jeffrey R. Long
Abstracts of Papers, 249th ACS National Meeting & Exposition, Denver, CO, United States, March 22-26, 2015 | 2015
Wendy L. Queen; Eric D. Bloch; Jason S. Lee; Joshua D. Howe; Jarad A. Mason; Miguel I. Gonzalez; Matthew R. Hudson; Kyuho Lee; Simon J. Teat; Jeffrey B. Neaton; Berend Smit; Jeff Long; Craig M. Brown
Abstracts of Papers, 249th ACS National Meeting & Exposition, Denver, CO, United States, March 22-26, 2015 | 2015
Thomas M. McDonald; Eric D. Bloch; Zoey R. Herm; Jarad A. Mason; Brian M. Wiers; Matthew T. Kapelewski; Miguel I. Gonzalez; Julia Oktawiec; Gokhan Barin; David Gygi; Wendy L. Queen; Jeffrey R. Long
Abstracts of Papers, 248th ACS National Meeting & Exposition, San Francisco, CA, United States, August 10-14, 2014 | 2014
Eric D. Bloch; Jarad A. Mason; Matthew T. Kapelewski; Kenji Sumida; Miguel I. Gonzalez; Mercedes K. Taylor; David Gygi; Wendy L. Queen; Jinxing Ye; Jeffrey R. Long
Abstracts of Papers, 248th ACS National Meeting & Exposition, San Francisco, CA, United States, August 10-14, 2014 | 2014
David Gygi; Eric D. Bloch; Jarad A. Mason; Wendy L. Queen; Matthew Beckner; Matthew R. Hudson; Anne Dailly; Craig M. Brown; Jeffrey R. Long
Abstracts of Papers, 248th ACS National Meeting & Exposition, San Francisco, CA, United States, August 10-14, 2014 | 2014
Dianne J. Xiao; Eric D. Bloch; Jarad A. Mason; Wendy L. Queen; Matthew R. Hudson; Craig M. Brown; Jeffrey R. Long
Abstracts of Papers, 247th ACS National Meeting & Exposition, Dallas, TX, United States, March 16-20, 2014 | 2014
Eric D. Bloch; Matthew R. Hudson; Wendy L. Queen; Jarad A. Mason; Joseph M. Zadrozny; Sachin Chavan; Silvia Bordiga; Craig M. Brown; Jeffrey R. Long