Eric Hébrard

A KINETIC DATABASE FOR ASTROCHEMISTRY (KIDA)

We present a novel chemical database for gas-phase astrochemistry. Named the KInetic Database for Astrochemistry (KIDA), this database consists of gas-phase reactions with rate coefficients and uncertainties that will be vetted to the greatest extent possible. Submissions of measured and calculated rate coefficients are welcome, and will be studied by experts before inclusion into the database. Besides providing kinetic information for the interstellar medium, KIDA is planned to contain such data for planetary atmospheres and for circumstellar envelopes. Each year, a subset of the reactions in the database (kida.uva) will be provided as a network for the simulation of the chemistry of dense interstellar clouds with temperatures between 10 K and 300 K. We also provide a code, named Nahoon, to study the time-dependent gas-phase chemistry of zero-dimensional and one-dimensional interstellar sources.

A chemical model for the atmosphere of hot Jupiters

Our purpose is to release a chemical network, and the associated rate coefficients, developed for the temperature and pressure range relevant to hot Jupiters atmospheres. Using this network, we study the vertical atmospheric composition of the two hot Jupiters (HD209458b, HD189733b) with a model that includes photolyses and vertical mixing and we produce synthetic spectra. The chemical scheme is derived from applied combustion models that have been methodically validated over a range of temperatures and pressures typical of the atmospheric layers influencing the observations of hot Jupiters. We compare the predictions obtained from this scheme with equilibrium calculations, with different schemes available in the literature that contain N-bearing species and with previously published photochemical models. Compared to other chemical schemes that were not subjected to the same systematic validation, we find significant differences whenever non-equilibrium processes take place. The deviations from the equilibrium, and thus the sensitivity to the network, are more important for HD189733b, as we assume a cooler atmosphere than for HD209458b. We found that the abundances of NH3 and HCN can vary by two orders of magnitude depending on the network, demonstrating the importance of comprehensive experimental validation. A spectral feature of NH3 at 10.5

How Measurements of Rate Coefficients at Low Temperature Increase the Predictivity of Photochemical Models of Titan’s Atmosphere†

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WASP-52b, WASP-58b, WASP-59b, and WASP-60b: Four new transiting close-in giant planets

m is sensitive to these abundance variations and thus to the chemical scheme. Due to the influence of the kinetics, we recommend the use of a validated scheme to model the chemistry of exoplanet atmospheres. Our network is robust for temperatures within 300-2500K and pressures from 10mbar up to a few hundreds of bars, for species made of C,H,O,N. It is validated for species up to 2 carbon atoms and for the main nitrogen species.

High-temperature measurements of VUV-absorption cross sections of CO2 and their application to exoplanets

The predictivity of photochemical models of Titans atmosphere depends strongly on the precision and accuracy of reaction rates. For many reactions, large uncertainty results from the extrapolation of rate laws to low temperatures. A few reactions have been measured directly at temperatures relevant to Titans atmosphere. In the present study, we observed the consequences of the reduced uncertainty attributed to these reactions. The global predictivity of the model was improved, i.e., most species are predicted with lower uncertainty factors. Nevertheless, high uncertainty factors are still observed, and a new list of key reactions has been established.

The impact of atmospheric circulation on the chemistry of the hot Jupiter HD 209458b

We present the discovery of four new transiting hot Jupiters, detected mainly from SuperWASP-North and SOPHIE observations. These new planets, WASP-52b, WASP-58b, WASP-59b, and WASP-60b, have orbital periods ranging from 1.7 to 7.9 days, masses between 0.46 and 0.94 MJup, and radii between 0.73 and 1.49RJup. Their G1 to K5 dwarf host stars have V magnitudes in the range 11.7−13.0. The depths of the transits are between 0.6 and 2.7%, depending on the target. With their large radii, WASP-52b and WASP-58b are new cases of low-density, inflated planets, whereas WASP-59b is likely to have a large, dense core. WASP-60 shows shallow transits. In the case of WASP-52 we also detected the Rossiter-McLaughlin anomaly via time-resolved spectroscopy of a transit. We measured the sky-projected obliquity λ = 24 ◦ +17 −9 , indicating that WASP-52b orbits in the same direction as its host star is rotating and that this prograde orbit is slightly misaligned with the stellar equator. These four new planetary systems increase our statistics on hot Jupiters and provide new targets for follow-up studies.

Neutral production of hydrogen isocyanide (HNC) and hydrogen cyanide (HCN) in Titan’s upper atmosphere

Context. Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Aims. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We also investigate the influence of these new data on the photochemistry of some exoplanets. Methods. We performed these measurements with synchrotron radiation as a tunable VUV light source for the 115–200 nm range at 300, 410, 480, and 550 K. In the 195–230 nm range, we used a deuterium lamp and a 1.5 m Jobin-Yvon spectrometer and we worked at seven temperatures between 465 and 800 K. We implemented the measured cross section into a 1D photochemical model. Results. For λ> 170 nm, the wavelength dependence of ln(σCO2 (λ,T ) × 1 Qv(T ) ) can be parametrized with a linear law. Thus, we can interpolate σCO 2 (λ,T ) at any temperature between 300 and 800 K. Within the studied range of temperature, the CO2 cross section can vary by more than two orders of magnitude. This, in particular, makes the absorption of CO2 significant up to wavelengths as high as 230 nm, while it is negligible above 200 nm at 300 K. Conclusions. The absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm. The model predicts that accounting for this temperature dependency of CO 2 cross section can affect the computed abundances of NH 3 ,C O 2 , and CO by one order of magnitude in the atmospheres of hot Jupiter and hot Neptune. This effect will be more important in hot CO 2 -dominated atmospheres.

New chemical scheme for studying carbon-rich exoplanet atmospheres

We investigate the effects of atmospheric circulation on the chemistry of the hot Jupiter HD 209458b. We use a simplified dynamical model and a robust chemical network, as opposed to previous studies which have used a three dimensional circulation model coupled to a simple chemical kinetics scheme. The temperature structure and distribution of the main atmospheric constituents are calculated in the limit of an atmosphere that rotates as a solid body with an equatorial rotation rate of 1 km/s. Such motion mimics a uniform zonal wind which resembles the equatorial superrotation structure found by three dimensional circulation models. The uneven heating of this tidally locked planet causes, even in the presence of such a strong zonal wind, large temperature contrasts between the dayside and nightside, of up to 800 K. This would result in important longitudinal variations of some molecular abundances if the atmosphere were at chemical equilibrium. The zonal wind, however, acts as a powerful disequilibrium process. We identify the existence of a pressure level of transition between two regimes, which may be located between 100 and 0.1 mbar depending on the molecule. Below this transition layer, chemical equilibrium holds, while above it, the zonal wind tends to homogenize the chemical composition of the atmosphere, bringing molecular abundances in the limb and nightside regions close to chemical equilibrium values characteristic of the dayside, i.e. producing an horizontal quenching effect in the abundances. Reasoning based on timescales arguments indicates that horizontal and vertical mixing are likely to compete in HD 209458bs atmosphere, producing a complex distribution where molecular abundances are quenched horizontally to dayside values and vertically to chemical equilibrium values characteristic of deep layers.

An aerodynamic roughness length map derived from extended Martian rock abundance data

Following the first detection of hydrogen isocyanide (HNC) in Titans atmosphere, we have devised a new neutral chemical scheme for hydrogen cyanide (HCN) and hydrogen isocyanide (HNC) in the upper atmosphere of Titan. To improve the chemistry of HNC and HCN, a careful review of the literature has been performed to retrieve critical reaction rates and to evaluate their uncertainty factors. We have also estimated the reaction rates of 48 new reactions using simple capture theory. Our photochemical model gives abundances of HNC and HCN in reasonable agreement with observations. An uncertainty propagation study shows large uncertainties for HNC. A global sensitivity analysis pinpoints some key reactions to study as a priority to improve the predictivity of the model. In particular, our knowledge of the isomerization of HNC via the reaction H + HNC ! HCN + H and the chemistry of H2CN needs to be improved [9].

A solar escalator on Mars: Self‐lifting of dust layers by radiative heating

Atmospheres with a high C/O ratio are expected to contain an important quantity of hydrocarbons, including heavy molecules (with more than 2 carbon atoms). To study correctly these C-rich atmospheres, a chemical scheme adapted to this composition is necessary. We have implemented a chemical scheme that can describe the kinetics of species with up to 6 carbon atoms. This chemical scheme has been developed with specialists of combustion and validated through experiments on a wide range of T and P. This chemical network is available on the online database KIDA. We have created a grid of 12 models to explore different thermal profiles and C/O ratios. For each of them, we have compared the chemical composition determined with a C0-C2 chemical scheme (species with up to 2 carbon atoms) and with the C0-C6 scheme. We found no difference in the results obtained with the two schemes when photolyses are not included in the model, whatever the temperature of the atmosphere. In contrast, when there is photochemistry, differences can appear in the upper atmosphere. These differences are found for all the tested PT profiles in the case that the C/O ratio is above 1. When the C/O ratio of the atmosphere is solar, differences are only found at temperatures lower than 1000K. The differences linked to the use of different chemical schemes do not have important influence on the synthetic spectra. However, we have confirmed that C2H2 and HCN as possible tracers of warm C-rich atmospheres. The use of this new chemical scheme is mandatory to model atmospheres with a high C/O ratio and, in particular, if one is interested in studying in details the photochemistry. If one is just interested in the synthetic spectra, the use of a smaller scheme may be sufficient.