Ernst A. Stadlbauer

Verwendung von Biomassekarbonisaten

Die Verwendungsmoglichkeiten von Biomassekarbonisaten sind sehr vielfaltig. Dabei ist darauf hinzuweisen, dass sich die Anwendung von Biomassekarbonisaten bisher fast ausschlieslich auf pyrolytisch erzeugte Produkte beschrankt. Fur Karbonisate aus der HTC existieren noch kein Produktionsanlagen im Dauerbetrieb und dementsprechend auch kein Markt. Auserdem sind die HTC-Karbonisate fur manche Einsatzgebiete, wie z. B. als Medizinalkohle oder in der Landwirtschaft, nicht zugelassen.

Thermochemical Processing of Animal Fat and Meat and Bone Meal to Hydrocarbon Based Fuels

The results of the study at hand may have implications for treatment of grease, lipid fractions, free fatty acids (FFA) and salts of FFA extracted from wastes of food industry, bio-refineries or sewage sludge as well as contaminated lipid containing forage. The goal of the study is, to prevent such contaminated wastes from entering the food chain. The following ways of treatment are proposed. Thermal conversion of waste fats from rendering plants or lipids in the presence of aluminosilicates of the zeolite family produce hydrocarbons with net calorific values in the range of 40–42 MJ/kg. NMR studies show aliphatic hydrocarbons as main product at T = 400°C. The spectrum of products is shifted to alkyl benzenes at T = 550°C. In case of sodium carbonate conversion is achieved in the presence of 5% water at T = 430 ± 20°C yielding mainly a liquid bio-crude with a low acid index, a mixture of non-condensable gases and minor amounts of coke. Rectification of bio-crude from animal fat produces 65.8% of hydrocarbon based bio-diesel and 13.3% of gasoline type hydrocarbons. Distillation curve for bio-diesel is in accordance with DIN EN 490. However, the gasoline fraction lacks low boiling hydrocarbons indicating the necessity for technical improvements of condensers. Sodium carbonate is found to be effective as well as being relatively inexpensive compared to zeolite catalysts. Finally, successful conversion of meat and bone meal to biochar is proved by solid-state 13C-NMR.Copyright