Euan Hendry

Coherent nonlinear optical response of graphene

We present the first experimental investigation of nonlinear optical properties of graphene flakes. We find that at near infrared frequencies a graphene monolayer exhibits a remarkably high thirdorder optical nonlinearity which is practically independent of the wavelengths of incident light. The nonlinear optical response can be utilized for imaging purposes, with image contrasts of graphene which are orders of magnitude higher than those obtained using linear microscopy.

Ultrasensitive detection and characterization of biomolecules using superchiral fields.

The spectroscopic analysis of large biomolecules is important in applications such as biomedical diagnostics and pathogen detection, and spectroscopic techniques can detect such molecules at the nanogram level or lower. However, spectroscopic techniques have not been able to probe the structure of large biomolecules with similar levels of sensitivity. Here, we show that superchiral electromagnetic fields, generated by the optical excitation of plasmonic planar chiral metamaterials, are highly sensitive probes of chiral supramolecular structure. The differences in the effective refractive indices of chiral samples exposed to left- and right-handed superchiral fields are found to be up to 10(6) times greater than those observed in optical polarimetry measurements, thus allowing picogram quantities of adsorbed molecules to be characterized. The largest differences are observed for biomolecules that have chiral planar sheets, such as proteins with high β-sheet content, which suggests that this approach could form the basis for assaying technologies capable of detecting amyloid diseases and certain types of viruses.

Induced chirality through electromagnetic coupling between chiral molecular layers and plasmonic nanostructures.

We report a new approach for creating chiral plasmonic nanomaterials. A previously unconsidered, far-field mechanism is utilized which enables chirality to be conveyed from a surrounding chiral molecular material to a plasmonic resonance of an achiral metallic nanostructure. Our observations break a currently held preconception that optical properties of plasmonic particles can most effectively be manipulated by molecular materials through near-field effects. We show that far-field electromagnetic coupling between a localized plasmon of a nonchiral nanostructure and a surrounding chiral molecular layer can induce plasmonic chirality much more effectively (by a factor of 10(3)) than previously reported near-field phenomena. We gain insight into the mechanism by comparing our experimental results to a simple electromagnetic model which incorporates a plasmonic object coupled with a chiral molecular medium. Our work offers a new direction for the creation of hybrid molecular plasmonic nanomaterials that display significant chiroptical properties in the visible spectral region.

Determining the terahertz optical properties of subwavelength films using semiconductor surface plasmons

By employing a combination of time-domain measurements and numerical calculations, we demonstrate that the semiconductor InSb supports a strongly confined surface plasmon (SP) in the terahertz frequency range. We show that these SPs can be used to enhance the light-matter interaction with dielectric layers above the semiconductor surface, thereby allowing us to detect the presence of polystyrene layers around 1000 times thinner than the free space wavelength of the terahertz light. Finally we discuss the viability of using semiconductor SPs for the purposes of terahertz sensing and spectroscopy.

Chiral electromagnetic fields generated by arrays of nanoslits

Using a modal matching theory, we demonstrate the generation of short-range, chiral electromagnetic fields via the excitation of arrays of staggered nanoslits that are chiral in two dimensions. The electromagnetic near fields, which exhibit a chiral density greater than that of circularly polarized light, can enhance the chiroptical interactions in the vicinity of the nanoslits. We discuss the features of nanostructure symmetry required to obtain the chiral fields and explicitly show how these structures can give rise to detection and characterization of materials with chiral symmetry.

THz generation from plasmonic nanoparticle arrays.

We investigate the generation of THz pulses when arrays of silver nanoparticles are irradiated by femtosecond laser pulses, providing the first reproducible experimental evidence in support of recent theoretical predictions of such an effect. We assess our results in the context of a model where photoelectrons are produced by plasmon-mediated multiphoton excitation, and THz radiation is generated via the acceleration of the ejected electrons by ponderomotive forces arising from the inhomogeneous plasmon field. By exploring the dependence of the THz emission on the femtosecond pulse intensity and as a function of metal nanoparticle morphology, and by comparing measurements to numerical modeling, we are able to verify the role of the particle plasmon mode in this process.

All-optical generation of surface plasmons in graphene

The strong confinement of plasmons in graphene makes them interesting for practical applications, but also difficult to excite. An all-optical technique can excite plasmons in graphene over a range of frequencies.

Noninvasive, near-field terahertz imaging of hidden objects using a single-pixel detector

Terahertz imaging for noninvasive measurements. Terahertz (THz) imaging can see through otherwise opaque materials. However, because of the long wavelengths of THz radiation (λ = 400 μm at 0.75 THz), far-field THz imaging techniques suffer from low resolution compared to visible wavelengths. We demonstrate noninvasive, near-field THz imaging with subwavelength resolution. We project a time-varying, intense (>100 μJ/cm2) optical pattern onto a silicon wafer, which spatially modulates the transmission of synchronous pulse of THz radiation. An unknown object is placed on the hidden side of the silicon, and the far-field THz transmission corresponding to each mask is recorded by a single-element detector. Knowledge of the patterns and of the corresponding detector signal are combined to give an image of the object. Using this technique, we image a printed circuit board on the underside of a 115-μm-thick silicon wafer with ~100-μm (λ/4) resolution. With subwavelength resolution and the inherent sensitivity to local conductivity, it is possible to detect fissures in the circuitry wiring of a few micrometers in size. THz imaging systems of this type will have other uses too, where noninvasive measurement or imaging of concealed structures is necessary, such as in semiconductor manufacturing or in ex vivo bioimaging.

Tuneable Fabry–Perot etalon for terahertz radiation

An indium tin oxide-clad liquid crystal filled Fabry-Perot etalon structure has been shown to act as an effective narrow-band filter at terahertz frequencies. An applied voltage, which controls the alignment of the nematic liquid crystal allows the refractive index of the core to be tuned. Transmission spectra show well-defined resonant peaks which shift in position when the alignment is changed from planar to homeotropic. The measured transmission spectra agree well with the results of a multilayer optics model and the birefringence of the liquid crystals over this frequency range are determined as 1n = 0.15(±0.01) and 1n = 0.08(±0.01) for E7 and ZLI 2293, respectively.

Hot phonon decay in supported and suspended exfoliated graphene

Near infrared pump-probe spectroscopy has been used to measure the ultrafast dynamics of photoexcited charge carriers in monolayer and multilayer graphene. We observe two decay processes occurring on 100-fs and 2-ps time scales. The first is attributed to the rapid electron-phonon thermalization in the system. The second time scale is found to be due to the slow decay of hot phonons. Using a simple theoretical model we calculate the hot phonon decay rate and show that it is significantly faster in monolayer flakes than in multilayer ones. We observe this enhanced decay rate in both supported and suspended flakes and thereby demonstrate that it has an intrinsic origin. Possible decay mechanisms, such as flexural phonons, that could cause such an enhancement are discussed.