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XXIVth International Congress of Pure and Applied Chemistry#R##N#Plenary and Main Section Lectures Presented at Hamburg, Federal Republic of Germany, 2–8 September 1973 | 1974

THE HYDROLYSIS OF PHOSPHATE ESTERS AND RELATED COMPOUNDS: MONOMERIC METAPHOSPHATES AND PHOSPHORIMIDATES

F. H. Westheimer; Charles Clapp; Jeffrey Wiseman

Monomeric metaphosphates have long been postulated as intermediates in the solvolysis of phosphate esters, but none had previously been isolated. We now present evidence that monomeric methyl metaphosphate has been prepared in the gas phase, and trapped with N- methylaniline.


Journal of the American Chemical Society | 1974

Monomeric methyl metaphosphate

Charles H. Clapp; F. H. Westheimer


Journal of the American Chemical Society | 1978

Monomeric methyl metaphosphate. 3. Electrophilic aromatic substitution in solution

Arnold C. Satterthwait; F. H. Westheimer


Journal of the American Chemical Society | 1981

Monomeric metaphosphate anion: reaction with carbonyl groups

Arnold C. Satterthwait; F. H. Westheimer


Journal of the American Chemical Society | 1975

Monomeric methyl metaphosphate. II. Electrophilic aromatic substitution

Charles H. Clapp; Arnold C. Satterthwait; F. H. Westheimer


ChemInform | 1980

Monomeric methyl metaphosphate: reactions with carbonyl groups

Arnold C. Satterthwait; F. H. Westheimer


ChemInform | 1974

MONOMERIC METHYL METAPHOSPHATE

Charles H. Clapp; F. H. Westheimer


ChemInform | 1976

MONOMERIC METHYL METAPHOSPHATE. II. ELECTROPHILIC AROMATIC SUBSTITUTION

Charles H. Clapp; Arnold C. Satterthwait; F. H. Westheimer


ChemInform | 1974

Photolysis of 1-azido-2,2,3,4,4-pentamethylphosphetane 1-oxide. Monomeric metaphosphonimidate

Jeffrey Wiseman; F. H. Westheimer


Journal of the American Chemical Society | 1980

Additions and Corrections - Monomeric Methyl Metaphosphate: Reactions with Carbonyl Groups.

Arnold C. Satterthwait; F. H. Westheimer

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