Fanghui Ren

Enhancing surface plasmon resonances of metallic nanoparticles by diatom biosilica

Diatoms are single-celled algaes that make photonic-crystal-like silica shells or frustules with hierarchical micro- & nano-scale features consisting of two-dimensional periodic pores. This article reports the use of diatom frustules as an integration platform to enhance localized surface plasmon resonances of self-assembled silver nanoparticles (NPs) on the surface of diatom frustules. Theoretical and experimental results show enhanced localized surface plasmons due to the coupling with the guided-mode resonances of the frustules. We observed 2 × stronger optical extinction and over 4 × higher sensitivity of surface-enhanced Raman scattering of Rhodmine 6G from the NPs-on-diatom than the NPs-on-glass structure.

Ultra-sensitive immunoassay biosensors using hybrid plasmonic-biosilica nanostructured materials

We experimentally demonstrate an ultra-sensitive immunoassay biosensor using diatom biosilica with self-assembled plasmonic nanoparticles. As the nature-created photonic crystal structures, diatoms have been adopted to enhance surface plasmon resonances of metal nanoparticles on the surfaces of diatom frustules and to increase the sensitivity of surface-enhanced Raman scattering (SERS). In this study, a sandwich SERS immunoassay is developed based on the hybrid plasmonic-biosilica nanostructured materials that are functionalized with goat anti-mouse IgG. Our experimental results show that diatom frustules improve the detection limit of mouse IgG to 10 pg/mL, which is ˜100× better than conventional colloidal SERS sensors on flat glass. Ultra-sensitive immunoassay biosensor using diatom biosilica with self-assembled plasmonic nanoparticles.

Surface-Enhanced Raman Spectroscopy Sensors From Nanobiosilica With Self-Assembled Plasmonic Nanoparticles

We present an innovative surface-enhanced Raman spectroscopy (SERS) sensor based on a biological-plasmonic hybrid nanostructure by self-assembling silver (Ag) nanoparticles into diatom frustules. The photonic-crystal-like diatom frustules provide a spatially confined electric field with enhanced intensity that can form hybrid photonic-plasmonic modes through the optical coupling with Ag nanoparticles. The experimental results demonstrate 4-6× and 9-12× improvement of sensitivities to detect the Raman dye for resonance and nonresonance SERS sensing, respectively. Such low-cost and high-sensitivity SERS sensors have significant potentials for label-free biosensing.

Detecting explosive molecules from nanoliter solution: A new paradigm of SERS sensing on hydrophilic photonic crystal biosilica.

We demonstrate a photonic crystal biosilica surface-enhanced Raman scattering (SERS) substrate based on a diatom frustule with in-situ synthesized silver nanoparticles (Ag NPs) to detect explosive molecules from nanoliter (nL) solution. By integrating high density Ag NPs inside the nanopores of diatom biosilica, which is not achievable by traditional self-assembly techniques, we obtained ultra-high SERS sensitivity due to dual enhancement mechanisms. First, the hybrid plasmonic-photonic crystal biosilica with three dimensional morphologies was obtained by electroless-deposited Ag seeds at nanometer sized diatom frustule surface, which provides high density hot spots as well as strongly coupled optical resonances with the photonic crystal structure of diatom frustules. Second, we discovered that the evaporation-driven microscopic flow combined with the strong hydrophilic surface of diatom frustules is capable of concentrating the analyte molecules, which offers a simple yet effective mechanism to accelerate the mass transport into the SERS substrate. Using the inkjet printing technology, we are able to deliver multiple 100pico-liter (pL) volume droplets with pinpoint accuracy into a single diatom frustule with dimension around 30µm×7µm×5µm, which allows for label-free detection of explosive molecules such as trinitrotoluene (TNT) down to 10-10M in concentration and 2.7×10-15g in mass from 120nL solution. Our research illustrates a new paradigm of SERS sensing to detect trace level of chemical compounds from minimum volume of analyte using nature created photonic crystal biosilica materials.

Thermo-optic modulation of plasmonic bandgap on metallic photonic crystal slab

We demonstrate active control of plasmonic bandgap on a metallic photonic crystal slab using thermo-optic effects. The Au grating, which is milled by focused-ion beam on a glass substrate, is designed to exhibit an extraordinary optical transmission and a sharp transitional edge for high modulation efficiency. Only a moderate refractive index modulation of Δn = 0.0043 is required to obtain more than 60% modulation depth with surface-normal optical coupling.

Effect of finite metallic grating size on Rayleigh anomaly-surface plasmon polariton resonances.

Rayleigh anomalies (RAs) and surface plasmon polaritons (SPPs) on subwavelength metallic gratings play pivotal roles in many interesting phenomena such as extraordinary optical transmission. In this work, we present a theoretical analysis of the effect of finite metallic grating size on RA-SPP resonances based on the combination of rigorous coupled wave analysis and finite aperture diffraction. One-dimensional arrays of gold subwavelength gratings with different device sizes were fabricated and the optical transmission spectra were measured. As the grating size shrinks, the broadening of the RA-SPP resonances is predicted by the theoretical model. For the first order RA-SPP resonances, the results from this model are in good agreement with the spectra measured from the fabricated plasmonic gratings.

Broadband on-chip near-infrared spectroscopy based on a plasmonic grating filter array

We demonstrate an ultra-compact, broadband on-chip near-infrared (NIR) spectroscopy system based on a narrow-band plasmonic filter array. The entire filter array, consisting of 28 individual subwavelength metallic gratings, was monolithically integrated in a thin gold film on a quartz substrate, covering a 270 nm spectra from 1510 nm to 1780 nm. In order to achieve a high spectral resolution, extremely narrow slits are created for the gratings with a polymer waveguide layer on top, generating narrow-band guided-mode resonances through coupling with the surface-plasmon resonances of the metallic gratings. Experimental results show that the transmission bands of the filter array have full width at half-maximum of only 7 nm-13 nm, which is sufficient for NIR spectroscopy. The NIR absorption spectroscopy of xylene using the on-chip plasmonic filter array matches very well with the results from conventional Fourier transform infrared spectroscopy, which proves the great potential for NIR sensing applications.

Guided-Mode Resonance Grating with Self-Assembled Silver Nanoparticles for Surface-Enhanced Raman Scattering Spectroscopy

We designed and fabricated guided-mode resonance (GMR) gratings on indium-tin-oxide (ITO) thin film to generate a significantly enhanced local electric field for surface-enhanced Raman scattering (SERS) spectroscopy. Ag nanoparticles (NPs) were self-assembled onto the surface of the grating, which can provide a large amount of “hot-spots” for SERS sensing. The ITO gratings also exhibit excellent tolerance to fabrication deviations due to the large refractive index contrast of the ITO grating. Quantitative experimental results of 5,5’-dithiobis(2-nitrobenzoic acid) (DTNB) demonstrate the best enhancement factor of ~14× on ITO gratings when compared with Ag NPs on a flat ITO film, and the limit of detection (LOD) of DTNB is as low as 10 pM.

Direct and Efficient Optical Coupling Into Plasmonic Integrated Circuits From Optical Fibers

We demonstrate direct and efficient optical coupling from an optical fiber into plasmonic integrated circuits (PICs) at 1.55-μm wavelength using ultra-compact plasmonic dipole nanoantennas. The PICs consist of slot waveguides with single-chip integrated Yagi-Uda antennas. To improve the optical coupling efficiency from optical fibers, we add 500-nm-thick Su-8 film with a high refractive index as the top cladding. We experimentally achieve 8.6% couple-in efficiency from a high numerical aperture fiber to the plasmonic slot waveguide and 46% total couple-out efficiency from the plasmonic slot waveguide. We also quantitatively characterize the dependence of the couple-in efficiency to the spot size of the incident light.

Slow-light effect via Rayleigh anomaly and the effect of finite gratings

In this Letter, we investigate the slow-light effect of subwavelength diffraction gratings via the Rayleigh anomaly using a fully analytical approach without needing to consider specific grating structures. Our results show that the local group velocity of the transmitted light can be significantly reduced due to the optical vortex, which can inspire a new mechanism to enhance light-matter interactions for optical sensing and photodetection. However, the slow-light effect will diminish as the transmitted light propagates farther from the grating surface, and the slowdown factor decreases as the grating size shrinks.