Florian Hirsch

Opencast mines in South Brandenburg (Germany)—archives of Late Quaternary landscape development and human-induced land use changes

This study outlines the opportunities for geoarchaeological research in active opencast lignite mines in southern Brandenburg (Germany). Studies on extensive outcrops that address both archaeology and soil geomorphology, combined with a geographical information system (GIS) approach, provide unique insights into human-induced environmental changes in Lower Lusatia and generally improve our understanding of landscape dynamics. We present the most recent results from three case studies and review important findings from the last several years. Studies conducted in opencast mines of Cottbus-Nord and Jänschwalde focus on (i) Late Quaternary geomorphodynamics and soil development and (ii) past land use and the legacy of agriculture and woodland use. Our results are similar to those in other regions in Central Europe, but we also observe regional differences caused by the local setting, e.g. intensification of soil erosion coinciding with the expansion of farming of cultivated lands in the Slavic Middle Ages. Our research reveals the largest archaeologically investigated area of historical charcoal production in the Northern European Lowland (NEL). We are clearly only beginning to understand the massive dimensions of charcoal production in the region.

Impact of crystalline and amorphous iron- and aluminum hydroxides on mechanisms of phosphate adsorption and desorption

Fourier-transform infrared (FT-IR) spectroscopic experiments were carried out during phosphate adsorption on highly crystalline gibbsite, poorly crystalline 2-line-ferrihydrite and amorphous iron-aluminum-hydroxide mixtures in the molar ratio 1:0, 10:1, 5:1, 1:1, 1:5, 1:10 and 0:1. The OH stretching vibrational bands were utilized to analyze changes in structural and surface OH groups during adsorption, because the position of characteristic PO vibrational bands can shift depending on reaction conditions, pH or adsorbed phosphate content. Adsorption and desorption kinetics were studied at pH6 and different initial phosphate concentrations to achieve varying phosphate coverage on the mineral surfaces. For gibbsite the formation of AlHPO4 and Al2HPO4 can be assumed, while for ferrihydrite, a FeHPO4 or Fe2PO4 complex and the precipitation of FePO4 with longer equilibration time were proposed. Fe2HPO4 or a Fe2PO4 surface complex was deduced for Fe-hydroxides, an AlH2PO4 surface complex was identified for Al-hydroxide, and both displayed either hydrogen bonds to neighboring hydroxyl groups or hydrogen bonds to outer-sphere complexes. Fe:Al-hydroxide mixtures with high Al ratios showed a low phosphate desorption rate, while ferrihydrite and the Fe:Al-hydroxide mixtures with high Fe ratios had almost negligible desorption rates. It was concluded that within the weakly associated amorphous FeO(OH) materials, FePO4 precipitated, which was bound by outer-sphere hydrogen bonds. With high Al ratios, desorption increased, which indicated weaker phosphate binding of both inner-sphere and outer-sphere complexes and hence, either no or minor quantities of precipitate. Ferrihydrite showed a more rigid structure and a lower extent of precipitation compared to amorphous Fe-hydroxide.

Formation, classification and properties of soils at two relict charcoal hearth sites in Brandenburg, Germany

Historical charcoal production can have significant effects on soil properties. We studied soils at former charcoal production sites (relict charcoal hearths, RCHs) and compared these soils with undisturbed soil next to the charcoal hearths and four typical soils on similar parent material located at distances between 10 and 70 km from the RCHs. In a landscape typical of the northern German lowland, we found Podsolige Braunerde (WRB: Brunic Arenosols (Protospodic)) outside of the RCHs and soils with a clearly different stratigraphy within the RCHs. The main feature of the soils at both of the studied RCHs is a heterogeneous, charcoal-bearing deposit that is approximately 30 cm thick. No indications of translocation or mineral transformation processes, which form distinct soil horizons after the deposition of anthropogenic material on the RCHs, are present. Except for the differences in color and total carbon content, the soil chemistry of the RCHs hardly differs from that of the soil outside of the charcoal hearth sites. The soil colors and magnetic susceptibility values strongly suggest that the RCH substrates and the underlying topsoil were affected by thermally induced transformation of iron (hydr-)oxides. Although the charring procedure normally requires approximately two weeks, the heating effect only reaches to a maximum depth of 8 cm into the buried soil below the charcoal hearths. The presence of reddish soil and an abrupt increase in magnetic susceptibility in the upper 2 cm of the soil below the charcoal hearths indicate the heat-induced transformation of iron (hydr-)oxides into maghemite. Brighter soil color and an increase in soil organic matter in the lower parts of the buried topsoil demonstrate the combustion of soil organic matter up to 5 cm depth below the RCH. According to the German Guidelines for Soil Mapping, the soils in the RCHs are classified as Regosols above Braunerde (WRB: Spolic Technosols (Arenic)). However, because the anthropogenic features of these soil sediments are disregarded in the German Guidelines for Soil Mapping, we suggest adapting the ‘M’ horizon to permit a jM horizon. Thus, the soils in the RCHs could be classified as Kolluviale Braunerde.