Thomas Raab

Using Geophysical Methods to Study the Shallow Subsurface of a Sensitive Alpine Environment, Niwot Ridge, Colorado Front Range, U.S.A

ABSTRACT Shallow seismic refraction (SSR) and ground penetrating radar (GPR) are non-invasive geophysical techniques that enhance studies of the shallow subsurface deposits which control many geomorphic and biogeochemical processes. These techniques permit measuring the thickness and material properties of these deposits in sensitive alpine areas without using extensive pits and trenches that can impact current biogeospheric processes or distort them for future research. Application of GPR and SSR along 1.5 km of geophysical lines shows that layers of fine to coarse, blocky deposits of periglacial origin underlie alpine slopes in the vicinity of Niwot Ridge, Colorado Front Range. Interpretation of geophysical and drilling data shows that depth to bedrock ranges from 4 to >10 m and is not simply related to local slope. Our measurements suggest that ice lenses form seasonally beneath solifluction lobes; ice was not present in adjacent areas. Ice lenses are associated with local ponded water and saturated sediments that result from topographic focusing and low-permeability layers beneath active periglacial features. Geophysical interpretations are mainly consistent with data derived from nearby drill cores and corroborate the utility of GPR in combination with SSR for collecting subsurface data required by different landscape models in sensitive alpine environments.

Character, Age, and Ecological Significance of Pleistocene Periglacial Slope Deposits in Germany

Periglacial slope deposits (PSD) of Pleistocene age are one of the most widely distributed sediment types in nonglaciated mid-latitude regions. As diamictons of different genesis (geli-solifluction, cryoturbation, eolian transportation) they have a wide range of physical, chemical and mineralogical characteristics which are mainly controlled by bedrock geology, including saprolite. This paper reviews concepts used in Germany to study PSD stratigraphy and describes the different PSD units encountered (Upper Head, Middle Head, Lower Head). The paper is relevant to the understanding of PSDs in other mid-latitude regions. Classical and new results concerning the age of PSDs show differences in the interpretation of Upper Head genesis. In terms of their ecological significance, case studies from eastern Bavaria illustrate the influence of PSDs on the character and intensity of slope hydrological processes as well as on the formation and distribution of soils. Presently important research questions include (1) the establishment of a genetically based classification of PSDs, (2) the intensification of dating studies on PSDs, and (3) the clarification of hydrological processes in PSDs.

Initial Ecosystem Processes as Key Factors of Landscape Development—A Review

The Earths surface is the dynamic interface of climatic, biotic, and geologic systems and is often described as the Earths critical zone. Structures and processes within this zone are highly complex and heterogeneous and therefore not yet completely understood, particularly with regard to their interactions. In contrast, parts of the critical zone still in their initial development stages are expected to be less complex and heterogeneous compared to mature systems. Therefore, research approaches concentrating on this crucial initial development period of ecosystems have been recently initiated. A central hypothesis is that the initial ecosystem development phase forms the later state of ecosystems. Similarly, the behavior of mature ecosystems can only be understood if knowledge about their evolution exists. The initial development stages of geo-ecosystems are characterized by highly dynamic abiotic and biotic processes. This results in the rapid formation and alteration of structures, which in turn constitute a new framework for new processes. To disentangle the structure-process interactions, interdisciplinary and integrative research approaches in the fields of geomorphology, ecology, biology, soil science, hydrology, and environmental modeling are required. We discuss ideas that emerged from the fourth Meeting of Young Researchers in Earth Sciences (MYRES IV) held at the Brandenburg University of Technology (BTU) Cottbus in 2010 (www.myres.org), which focused on the overarching question: what are the evolutionary constraints and pathways that govern development of spatiotemporal patterns in ecosystem process and structure? This paper presents a review of the most important aspects of initial ecosystem processes as key factors of landscape development.

Subdued Mountains of Central Europe

Abstract Slope deposits, which veil entire slopes or large parts of them in a rather uniform manner (cover beds), are ubiquitous in the subdued mountains of Central Europe. Here we provide an overview of the current state of knowledge on these deposits. The Central European cover beds are divided into (1) the upper layer that is ubiquitously distributed and displays a relatively constant thickness; (2) the intermediate layer the distribution of which is mainly restricted to flat relief, to slope depressions, and to lee-ward facing slopes; and (3) the basal layer, which is rather widespread again. Both the upper and intermediate layer contain intermixed loess, whereas the basal layer is free of loess and typically has a high bulk density. Aside from the loess content, the composition of the layers differs, reflecting varying portions of crushed and chemically weathered rock allocated from up-slope. This causes notable diversity depending on bedrock and, thus, induces remarkable regional differences. Cover beds were mainly formed by periglacial gelifluction. The upper layer formed in the Late Glacial possibly during several short episodes of activity. In contrast, the underlying layers may be diachronous; nevertheless, they display recurring vertical sequences. This is probably due to the fact that loess-free layers usually could not deposit as long as there was loess in the environs, which may have been inherited from older deposits. Thus, the last phase of surface wash, during which older loess was removed, determines the age of the lower layers.

Stratigraphy and Chronology of Late Quaternary Floodplain Sediments in a Historic Mining Area, Vils River Valley, East Bavaria, Germany

Analysis of 288 percussion drillings from depths of up to seven meters and a 120 m long excavated section provide new and detailed information on the Late Quaternary to Late Holocene floodplain evolution from the most important Central European iron-mining region of the 15th century. The generalized sequence of the Vils River floodplain is built of five units representing facies of different genesis (rock/saprolite, gravel, sand, loam, peat) that are identified by physical, chemical, and mineralogical parameters (grain size, clast shape, and content, TOC, bulk mineralogy). Along the 87 km length of the valley, different units/facies are found at the Upper Vils River (UVR 1-5) and at the Lower Vils River (LVR 1-4b). In both river sections, fine-grained material (flood loam) forms the major part (up to 4 m) of the alluvial sequence. 29 age determinations (24 14C, 4 IRSL, 1 tree-ring analysis) show increasing accumulation of flood loam in the last millennium. The data correlate with the beginning of mining at the Vils River and hence suggest a causal connection with mining activities in the catchment—both on the slopes and in the floodplain—with intense deposition of flood loams.

Opencast mines in South Brandenburg (Germany)—archives of Late Quaternary landscape development and human-induced land use changes

This study outlines the opportunities for geoarchaeological research in active opencast lignite mines in southern Brandenburg (Germany). Studies on extensive outcrops that address both archaeology and soil geomorphology, combined with a geographical information system (GIS) approach, provide unique insights into human-induced environmental changes in Lower Lusatia and generally improve our understanding of landscape dynamics. We present the most recent results from three case studies and review important findings from the last several years. Studies conducted in opencast mines of Cottbus-Nord and Jänschwalde focus on (i) Late Quaternary geomorphodynamics and soil development and (ii) past land use and the legacy of agriculture and woodland use. Our results are similar to those in other regions in Central Europe, but we also observe regional differences caused by the local setting, e.g. intensification of soil erosion coinciding with the expansion of farming of cultivated lands in the Slavic Middle Ages. Our research reveals the largest archaeologically investigated area of historical charcoal production in the Northern European Lowland (NEL). We are clearly only beginning to understand the massive dimensions of charcoal production in the region.

Nutrient and heavy metal accumulation in municipal organic waste from separate collection during anaerobic digestion in a two-stage laboratory biogas plant

Municipal organic waste (MOW) is a promising feedstock for biogas plants and separate collection will increase available quantities. To close nutrient circles digestates shall be redistributed to arable land. However, less is known about digestate properties and how they are influenced during digestion. Therefore, changes in nutrient and heavy metal concentration in the solid digestate were investigated during anaerobic treatment of MOW in a two-stage laboratory biogas plant. Results show that the solid digestate is exposed to element accumulation, except for N, P and Mg. The loss of initial N, P and Mg load accounts up to 45%, which must be redistributed elsewhere in the digester system. K load of feedstock was completely rediscovered in the solid digestate. Heavy metal concentration in the digestate increases by factor 1.6 at average. The results emphasize that element retention in the digester system has a decisive impact on nutrient content of digestates.

Stability of Prussian Blue in Soils of a Former Manufactured Gas Plant Site

Soil contamination with iron-cyanide complexes is a common problem at former manufactured gas plant (MGP) sites. Dissolution of the cyanide, from Prussian Blue (ferric ferrocyanide), creates an environmental hazard, whereas the risk of groundwater contamination depends on the stability of dissolved iron–cyanide complexes. Lack of a standard leaching method to determine the water-soluble (plant-available) cyanide fraction generates potential limitations for implementing remediation strategies like phytoremediation. Applicability of neutral solution extraction to determine the water-soluble cyanide fraction and the stability of Prussian Blue in surface and near-surface soils of an MGP site in Cottbus, undersaturated and unsaturated water conditions, was studied in column leaching and batch extraction experiments. MGP soils used in the long-term tests varied according to the pH (5.0–7.7) and the total cyanide content (40–1718 mg kg−1). Column leaching, after four months of percolation, still yielded effluent concentrations exceeding the German drinking water limit (> 50 μg L−1) and the solubility of Prussian Blue reported in the literature (< 1 mg L−1) from both alkaline and acidic soils. Long-term (1344 h) extraction of MGP soils with distilled water was sufficient to dissolve 97% of the total cyanide from the slightly alkaline soils and up to 78% from the acidic soils. Both experiments revealed that dissolution of ferric ferrocyanide under circum-neutral pH and oxic water conditions is a function of time, where the released amount is dependent on the soil pH and total cyanide content. Unexpectedly high and continuous solubility of Prussian Blue, both in acidic and slightly alkaline MGP soils, implies the need to introduce an additional cyanide fraction (“readily soluble fraction”) to improve and specify cyanide leaching methods. Long-term extraction of cyanide-contaminated soil in neutral solution seems to be a promising approach to evaluate the potential hazard of groundwater pollution at the MGP sites.

Impacts of soil additives on crop yield and C-sequestration in post mine substrates of Lusatia, Germany.

Abstract Opencast lignite mining in the Lusatia region of Germany has resulted in large scale landscape disturbances, which require suitable recultivation techniques in order to promote plant growth and establishment in the remaining nutrient-poor substrates with low water-holding capacity. Thus, the effects of two commercial soil additives (CSA), a hydrophilic polymer mixed with volcanic rock flour and bentonite (a-CSA), and digester solids from biogas plants enriched with humic acids and bentonite (b-CSA), on soil organic carbon (SOC) storage, plant yields and root biomass were assessed after cultivating perennial crops (Dactylis glomerata L.) in monoculture and Helianthus annuus L.-Brassica napus L. in crop rotation systems. The CSA were incorporated into the top 20 cm soil depth using a rotary spader. The results indicated that a-CSA led to a significant increase in plant yield during the first year, and improved root biomass in the following year. As a result, SOC stocks increased, especially in the 0–10 cm soil layer. No significant sequestration of additional SOC was observed on b-CSA-amended plots at the end of both years. Bulk density values decreased in all treatments under the monoculture system. It can be concluded that application of a-CSA enhanced soil water availability for plant uptake and consequently promoted plant growth and organic carbon sequestration. The relative enrichment of organic matter without effects on water-holding capacities of b-CSA treatments suggested that it was not suitable for rapid land reclamation.

Impact of Commercial Soil Additives on Microbial Activity and Carbon Isotopic Characteristics of Recultivated Post Lignite Mine Soils

The impact of commercial soil additives (CSA) on post lignite mine soils was assessed after 14 months of field application by evaluating the changes in microbial respiration, the respiratory quotient and the isotopic signature of microbial respired CO2-C. Soil samples were randomly collected from 0 to 5 cm depths from: (1) tilled plots amended with polyacrylate hydrophilic polymer, mixed with zeolithes and bentonite (a-CSA) at 5,000 kg ha−1 dry mass; (2) tilled plots amended with a near-natural digester compost enriched with mineral additives, bentonite and synthesized humic acids (b-CSA) at 10,000 kg ha−1 dry mass; (3) plots tilled and without amendment (control), and (4) plots without tillage and amendment. All plots were seeded with orchard grass (Dactilus glomerata, L.). Soil microbial basal respiration was low and not significantly affected by the treatments presumably, due to low availability of CSA for microbial metabolism. Soil microbial respiration, respiratory quotients and 13C isotopic characteristics of the respired CO2 followed a similar trend for all treatments throughout the incubation period and was not significantly different between a-CSA and b-CSA amended plots compared to the control and untilled plots. The results indicate that the current soil microbial communities have similar eco-physiology and substrate utilisation patterns, and may have met their metabolic requirements mainly from the inherent and recent organic matter input from the vegetation cover. This may be due to the recalcitrant nature of the CSAs or the recommended application rates being too low to affect any significant short-term biochemical impact on these recultivated soils in early stages of development.