Franco Barberi

Evolution of a section of the Africa-Europe plate boundary: Paleomagnetic and volcanological evidence from Sicily

Abstract New paleomagnetic data relative to Upper Cretaceous, Neogene and Quaternary volcanic rocks from eastern Sicily definitively indicate that Sicily is a part of the African plate, which collided with the European continental plate in Middle Miocene times. These data and the tectonic evolution of Sicily as inferred from the nature, age and distribution of volcanic products, are broadly consistent with the motions of Africa relative to Europe since the Upper Trias. During the Mesozoic, eastern Sicily was affected by extensional tectonics with associated alkali basaltic volcanism, and oceanic crust was produced in the meantime between the diverging African and European plates. Near the end of Mesozoic times the two plates started to converge with consequent consumption of oceanic crust. Different times of oceanic plate consumption along the Sicily-Calabria section of the plate boundary are suggested by the occurence of andesitic volcanism of different ages. The tectonic significance of late Tertiary to present basaltic activity in eastern Sicily is also discussed.

Atmospheric dispersion of natural carbon dioxide emissions on Vulcano Island, Italy

La Fossa quiescent volcano and its surrounding area on the Island of Vulcano (Italy) are characterized by intensive, persistent degassing through both fumaroles and diffuse soil emissions. Periodic degassing crises occur, with marked increase in temperature and steam and gas output (mostly CO2) from crater fumaroles and in CO2 soil diffuse emission from the crater area as well as from the volcano flanks and base. The gas hazard of the most inhabited part of the island, Vulcano Porto, was investigated by simulating the CO2 dispersion in the atmosphere under different wind conditions. The DISGAS (DISpersion of GAS) code, an Eulerian model based on advection-diffusion equations, was used together with the mass-consistent Diagnostic Wind Model. Numerical simulations were validated by measurements of air CO2 concentration inside the village and along the craters rim by means of a Soil CO2 Automatic Station and a Tunable Diode Laser device. The results show that in the village of Vulcano Porto, the CO2 air concentration is mostly due to local soil degassing, while the contribution from the crater gas emission is negligible at the breathing height for humans and always remains well below the lowest indoor CO2 concentration threshold recommended by the health authorities (1000u2009ppm). Outdoor excess CO2 maxima up to 200u2009ppm above local background CO2 air concentration are estimated in the center of the village and up to 100u2009ppm in other zones. However, in some ground excavations or in basements the health code threshold can be exceeded. In the crater area, because of the combined effect of fumaroles and diffuse soil emissions, CO2 air concentrations can reach 5000–7000u2009ppm in low-wind conditions and pose a health hazard for visitors.