Frédéric Gruy
Mines ParisTech
Network
Latest external collaboration on country level. Dive into details by clicking on the dots.
Publication
Featured researches published by Frédéric Gruy.
Chemical Engineering Science | 1999
Jean-Michel Herri; Frédéric Gruy; Jean-Stéphane Pic; Michel Cournil; Béatrice Cingotti; Anne Sinquin
In this paper we describe a new experimental set-up which makes possible the in situ determination of the particle size distribution of methane hydrate during its formation in a pressurized reactor. It has been installed on two research sites: one at the Institut Francais du Petrole (IFP) and the other at the Ecole des Mines de Saint-Etienne (EMSE). Thanks to this apparatus, new data can be obtained, in particular concerning the granular aspects of the crystallization processes and the reproducibility of the results. Particularly, we propose a new experimental procedure which allows us two important improvements: • a better reproducibility of the induction time, • the possibility of doing a large number of experiments in a day (around fifteen). Using this protocol, the effect of some kinetic inhibitors of the crystallization processes are shown: increase of the induction time and/or decrease of the quantity of hydrate formed.
Chemical Engineering Science | 1996
George Crawley; Frédéric Gruy; Michel Cournil
This paper presents an example of the use of a turbidity multi-wavelength sensor for an in-line study of fragmentation of crystals in an agitated vessel. Thanks to this in situ sensor, it is possible to continuously record the turbidity spectrum of a suspension. Particle size distributions can be calculated for grain diameters between 0.2 and 10 μm. This sizing technique is applied here to the fragmentation of potassium sulphate in ethanol and in its aqueous solution. A qualitative and quantitative study of the phenomenon of fragmentation can be thus performed. Determination of the influence of mass and stirring rate gives an indication of the prevailing fragmentation mechanisms. The large discrepancies observed between the behaviors in ethanol and in water are due to agglomeration.
Physica Status Solidi (a) | 2002
Michel Cournil; Frédéric Gruy; Pascal Gardin; Hubert Saint-Raymond
Getting clean steel is becoming a major challenge nowadays, both for the production of competitive steel and for making easier the process exploitation. As a consequence, there is a need to study the behavior of solid particles (called inclusions) in liquid steel, responsible for the cleanliness defects observed in steel products. The addition to steel of a deoxidizing element such as aluminum provokes the formation of solid particles (Al 2 O 3 ). These inclusions have a density smaller than steel so they can be eliminated by flotation and captured by the liquid slag layer on the steel surface. The paper proposes some mechanisms for the formation of inclusion cluster in liquid steel and examines the influence of the wetting condition on inclusion growth, using a cold experiment.
Materials Chemistry and Physics | 1995
J.M. Herri; Frédéric Gruy
Abstract The calculation of the refractive index of methane hydrate is carried out using a modified Lorenz-Lorentz model. The occupancy of methane into the structure of the hydrate is taken into account. It is calculated from van der Waals and Platteuuw theory and shows small changes when the experimental pressure varies from 30 to 110 bars and when the experimental temperature varies from − 3 to + 12 °C. We have observed great changes of the relative index of refraction with the methane occupancy (the relative index of refraction is the ratio between the refractive index of the methane hydrate and of liquid water). The relative index of refraction characterizes the ability of the methane hydrate particles to scatter the light. Thus, the occupancy factor of methane must be taken into account when the calculation of size distribution uses the optical properties of particles.
Acta Materialia | 1996
Frédéric Gruy; Michel Cournil
Many models have been developed to describe Ostwald ripening. The most recent of them have dealt with systems of high solid volume fraction (φ > 0.01). To obtain an exploitable solution, all these models require several simplifications: assumption of low solubility, assumption of motionless fluid phase, no consideration of the spatial arrangement of the grains, analytical or numerical approximation methods. In this paper an unidimensional linear model (row of grains) of Ostwald ripening is proposed which can be applied to the most general and difficult situation, i.e. systems with high volume fraction in highly soluble grains. This model does not require any simplifying assumption. Its validity can be proved from already published theoretical results. Within this model, the spatial arrangement of the grains and the associated connectivity effects which have not been studied so far, can be taken into account. These effects become particularly important at high volume fraction.
Aiche Journal | 1999
Jean-Michel Herri; Jean-Stéphane Pic; Frédéric Gruy; Michel Cournil
Chemical Engineering Science | 2006
Annie Fidel-Dufour; Frédéric Gruy; Jean-Michel Herri
Journal of Colloid and Interface Science | 2001
Frédéric Gruy
Journal of Colloid and Interface Science | 2000
Christoph Tontrup; Frédéric Gruy; Michel Cournil
Journal of Crystal Growth | 2008
Ana Cameirão; René David; Fabienne Espitalier; Frédéric Gruy