Fu-Yuan Wu

A-type granites in northeastern China: age and geochemical constraints on their petrogenesis

Abstract A-type granites are widely distributed in northeastern China (NE China). They were emplaced during three major episodes (the Permian, late Triassic to early Jurassic, and early Cretaceous) and evolved in different tectonic regimes. According to their mineralogical and geochemical characteristics, two subgroups of A-type granites (aluminous and peralkaline) can be recognized. The peralkaline subgroup contains alkali mafic minerals, such as riebeckite, arfvedsonite and sodic pyroxene, while the aluminous subgroup contains annite and Fe-rich calcic- or sodic-calcic amphibole. With respect to the aluminous subgroup, the peralkaline granites contain higher Rb, Ga and total rare earth elements (REE), but lower MgO, CaO, Al 2 O 3 , Ba and Sr. Based on the discrimination criteria of Eby [Geology 20 (1992) 641], the Permian and late Triassic to early Jurassic A-type granites belong to the A 2 (post-orogenic) type, whereas the early Cretaceous granites are of the A 1 (anorogenic) type. Nd isotopic compositions of these A-type granites indicate their derivation from a dominantly juvenile crustal source. Their origin is thought to have involved partial melting of an underplated lower crustal source. Because the generation of A-type granites requires high melting temperature, we propose models involving slab break-off, lithospheric delamination and extension. The Permian A-type granites have the same age range as those in eastern Junggar, southern Mongolia and central Inner Mongolia. They occur along a major suture and form a narrow belt between the north China and Siberian Cratons. We suggest that their formation was associated with post-collisional slab break-off. The late Triassic to early Jurassic A-type granites are likely to be the product of lithospheric delamination after the final collision of the major crustal blocks in the late Paleozoic to early Triassic. The early Cretaceous A-type granites have an anorogenic affinity and were possibly associated with rifting in eastern China at this time, associated with the onset of paleo-Pacific subduction. Consequently, we conclude that the A-type granites in NE China were generated at three different times, involving multiple processes operative in different tectonic environments.

Granitoids of the Central Asian Orogenic Belt and continental growth in the Phanerozoic

The Central Asian Orogenic Belt (CAOB), also known as the Altaid Tectonic Collage, is characterised by a vast distribution of Paleozoic and Mesozoic granitic intrusions. The granitoids have a wide range of compositions and roughly show a temporal evolution from calcalkaline to alkaline to peralkaline series. The emplacement times for most granitic plutons fall between 500 Ma and 100 Ma, but only a small proportion of plutons have been precisely dated. The Nd-Sr isotopic compositions of these granitoids suggest their juvenile characteristics, hence implying a massive addition of new continental crust in the Phanerozoic. In this paper we document the available isotopic data to support this conclusion. Most Phanerozoic granitoids of Central Asia are characterised by low initial Sr isotopic ratios, positive e Nd (T) values and young Sm—Nd model ages (T DM ) of 300-1200 Ma. This is in strong contrast with the coeval granitoids emplaced in the European Caledonides and Hercynides. The isotope data indicate their ‘juvenile’ character and suggest their derivation from source rocks or magmas separated shortly before from the upper mantle. Granitoids with negative e Nd (T) values also exist, but they occur in the environs of Precambrian microcontinental blocks and their isotope compositions may reflect contamination by the older crust in the magma generation processes. The evolution of the CAOB is probably related to accretion of young arc complexes and old terranes (microcontinents). However, the emplacement of large volumes of post-tectonic granites requires another mechanism, probably through a series of processes including underplating of massive basaltic magma, intercalation of basaltic magma with lower crustal granulites, partial melting of the mixed lithologic assemblages leading to generation of granitic liquids, followed by extensive fractional crystallisation. The proportions of the juvenile or mantle component for most granitoids of Central Asia are estimated to vary from 70% to 100%.

A review of the geodynamic setting of large-scale Late Mesozoic gold mineralization in the North China Craton: an association with lithospheric thinning

Abstract Abundant gold deposits are distributed along the margins of the North China Craton (NCC). Occurring throughout the Precambrian basement and located in or proximal to Mesozoic granitoids, these deposits show a consistent spatial–temporal association with Late Jurassic–Early Cretaceous magmatism and are characterized by quartz lode or disseminated styles of mineralization with extensive alteration of wall rock. Their ages are mainly Early Cretaceous (130–110 Ma) and constrain a very short period of metallogenesis. Sr–Nd–Pb isotopic tracers of ores, minerals and associated rocks indicate that gold and associated metals mainly were derived from multi-sources, i.e., the wall rocks (Precambrian basement and Mesozoic granites) and associated mafic rocks. Previous studies, including high surface heat flow, uplift and later basin development, slow seismic wave speeds in the upper mantle, and a change in the character of mantle xenoliths sampled by Paleozoic to Cenozoic magmas, have been used to suggest that ancient, cratonic mantle lithosphere was removed from the base of the NCC some time after the Ordovician, and replaced by younger, less refractory lithospheric mantle. The geochemistry and isotopic compositions of the mafic rocks associated with gold mineralization (130–110 Ma) indicate that they were derived from an ancient enriched lithospheric mantle source; whereas, the mafic dikes and volcanic rocks younger than 110 Ma were derived from a relatively depleted mantle source, i.e., asthenospheric mantle. According to their age and sources, relation to magmatism and geodynamic framework, the gold deposits were formed during lithospheric thinning. The removal of lithospheric mantle and the upwelling of new asthenospheric mantle induced partial melting and dehydration of the lithospheric mantle and lower crust due to an increase of temperature. The fluids derived from the lower crust were mixed with magmatic and meteoric waters, and resulted in the deposition of gold and associated metals.

Highly fractionated I-type granites in NE China (II): isotopic geochemistry and implications for crustal growth in the Phanerozoic

NE China is the easternmost part of the Central Asian Orogenic Belt (CAOB). The area is distinguished by widespread occurrence of Phanerozoic granitic rocks. In the companion paper (Part I), we established the Jurassic ages (184–137 Ma) for three granitic plutons: Xinhuatun, Lamashan and Yiershi. We also used geochemical data to argue that these rocks are highly fractionated I-type granites. In this paper, we present Sr–Nd–O isotope data of the three plutons and 32 additional samples to delineate the nature of their source, to determine the proportion of mantle to crustal components in the generation of the voluminous granitoids and to discuss crustal growth in the Phanerozoic. Despite their difference in emplacement age, Sr–Nd isotopic analyses reveal that these Jurassic granites have common isotopic characteristics. They all have low initial 87 Sr/ 86 Sr ratios (0.7045F0.0015), positive eNd(T) values (+1.3 to +2.8), and young Sm–Nd model ages (720–840 Ma). These characteristics are indicative of juvenile nature for these granites. Other Late Paleozoic to Mesozoic granites in this region also show the same features. Sr–Nd and oxygen isotopic data suggest that the magmatic evolution of the granites can be explained in terms of two-stage processes: (1) formation of parental magmas by melting of a relatively juvenile crust, which is probably a mixed lithology formed by pre-existing lower crust intruded or underplated by mantle-derived basaltic magma, and (2) extensive magmatic differentiation of the parental magmas in a slow cooling environment. The widespread distribution of juvenile granitoids in NE China indicates a massive transfer of mantle material to the crust in a post-orogenic tectonic setting. Several recent studies have documented that juvenile granitoids of Paleozoic to Mesozoic ages are ubiquitous in the Central Asian Orogenic Belt, hence suggesting a significant growth of the continental crust in the Phanerozoic. D 2003 Elsevier Science B.V. All rights reserved.

Mesozoic decratonization of the North China block

Cratons are old, stable parts of the continental crust that have survived at least since Proterozoic time and have not undergone strong magmatism or tectonism since their stabilization. Traditionally, the growth of continental crust in the North China craton is considered to have been complete by Paleoproterozoic time, Phanerozoic events being largely restricted to surrounding orogenic belts. However, the eastern part of the North China craton contains large volumes of Mesozoic igneous rocks, with widespread metamorphic core complexes and pull-apart basins. Hf isotope compositions of magmatic zircon grains from igneous rocks in the Liaodong Peninsula indicate that widespread late Mesozoic granitoids formed by partial melting of ancient crust, but with significant input of a mantle component via magma mixing and crustal assimilation. This magmatism has resulted from removal and modification of lithospheric mantle, accompanied by asthenospheric upwelling. The Hf isotopic signatures thus record the addition of juvenile crust beneath the eastern part of the North China craton, which appears related to major extension and possibly slab rollback of the Pacific plate. Whatever the mechanism, it is apparent that since ca. 200 Ma, ancient lithosphere beneath the eastern North China craton has been progressively reactivated and replaced, resulting in “decratonization.” Tertiary to Holocene volcanism in the area and major subsidence around the Gulf of Bohai suggest that the effects of the process are continuing. Similar processes probably operated in the geological past, leading to significant modification of continental crust and requiring reconsideration of mechanisms for continental breakup and dispersal and of continental growth rates.

Hf isotopic compositions of the standard zircons for U-Pb dating

Using the newly published Yb isotopic abundances and the mass bias relationship between Yb and Hf, we carried out an analysis of Hf isotopes in the standard zircon 91500 by means of 193 nm laser attached to Neptune multi-collector ICP-MS (LA-MC-ICPMS). The obtained Hf isotopic data, in eitherin situ or line scan modes, are not only identical for different spot sizes, but also are consistent with previously published results obtained on TIMS or other MC-ICPMS machines within errors. This indicates that it is possible to obtain reliable176Hf/177Hf isotopic ratios for zircon in eitherin situ or line scan conditions on LA-MC-ICPMS machine, and the applied procedures in our study for elemental interfering correction are appropriate for the purpose of acquiring satisfactory accuracy for Hf isotope analyses. The Hf isotopic compositions of four zircon standards in high spatial resolution U-Pb dating, 91500, CZ3, CN92-1 and TEMORA, are measured, respectively. The obtained176Hf/177Hf ratios are 0.282316±4 (n = 34, 2σ) for 91500, 0.281704±6 (n = 16, 2σ) for CZ3, 0.282200±6 (n = 20, 2σ) for CN92-1 and 0.282684±14 (n = 24, 2σ) for TEMORA, respectively, with176Lu/177Hf ratios of ~0.00031, 0.000036, 0.00083 and 0.00127. Zircons 91500 and CZ3 show narrower variations in176Hf/177Hf and176Lu/177Hf ratios than those of zircons CN92-1 and TEMORA, and thus are appropriate standards for the Hf isotope analysis.

PALEOPROTEROZOIC CRUSTAL GROWTH IN THE WESTERN BLOCK OF THE NORTH CHINA CRATON: EVIDENCE FROM DETRITAL ZIRCON Hf AND WHOLE ROCK Sr-Nd ISOTOPIC COMPOSITIONS OF THE KHONDALITES FROM THE JINING COMPLEX

Detrital zircons from the khondalites in the Western Block of the North China Craton were mainly derived from a 1.9 to 2.1 Ga Paleoproterozoic provenance. Most of the more than 200 detrital zircons analyzed in this study have positive initial εHf values and a wide range of Hf depleted mantle model ages (TDMC) that range from 2.08 Ga to 2.74 Ga, with a peak at 2.24 to 2.40 Ga. The whole rock Nd isotopic analyses for the khondalite samples give quite uniform 143Nd/144Nd ratios from 0.511188 to 0.511858, corresponding to initial εNd (2.10Ga) values ranging from -1.6 to +0.6. In contrast, Sr isotopic compositions of these samples are more varied, with initial 87Sr/86Sr ratios at 2.10 Ga ranging from 0.7017 to 0.7076. In the εNd versus 87Sr/86Sr correlation diagram, most samples plot near the mixing hyperbola of the depeleted mantle and crust, with the contribution of depleted mantle about 65 to 75 percent. These results suggest that a large amount of juvenile materials from the depleted mantle was accreted to the Western Block at 2.1 Ga, a period of magmatic quiescence in many cratons of the world.

Magmatic record of India-Asia collision

New geochronological and geochemical data on magmatic activity from the India-Asia collision zone enables recognition of a distinct magmatic flare-up event that we ascribe to slab breakoff. This tie-point in the collisional record can be used to back-date to the time of initial impingement of the Indian continent with the Asian margin. Continental arc magmatism in southern Tibet during 80–40 Ma migrated from south to north and then back to south with significant mantle input at 70–43 Ma. A pronounced flare up in magmatic intensity (including ignimbrite and mafic rock) at ca. 52–51 Ma corresponds to a sudden decrease in the India-Asia convergence rate. Geological and geochemical data are consistent with mantle input controlled by slab rollback from ca. 70 Ma and slab breakoff at ca. 53 Ma. We propose that the slowdown of the Indian plate at ca. 51 Ma is largely the consequence of slab breakoff of the subducting Neo-Tethyan oceanic lithosphere, rather than the onset of the India-Asia collision as traditionally interpreted, implying that the initial India-Asia collision commenced earlier, likely at ca. 55 Ma.

U–Pb and Hf isotopic study of detrital zircons from the Lüliang khondalite, North China Craton, and their tectonic implications

Two types of metasedimentary rocks occur in the Trans-North China Orogen of the North China Craton. One type consists of highly metamorphosed supracrustal rocks with protoliths of mature cratonic shale, called khondalites, as found in the Luliang Complex; rocks of the other type are also highly metamorphosed but less mature, as represented by the Wanzi supracrustal assemblage in the Fuping Complex. U–Pb isotopic data for detrital zircons from khondalites show a provenance dominated by 1.9–2.1 Ga Palaeoproterozoic rocks. These detrital zircons display a wide range of e Hf values from −16.0 to +9.2 and give Hf isotopic model ages mostly around 2.3 Ga. The high positive e Hf values approach those for the depleted mantle at 2.1 Ga, highlighting a juvenile crustal growth event in Palaeoproterozoic times. Hf isotopic data also imply that c. 2.6 Ga old crustal material was involved in the Palaeoproterozoic magmatic event. These data are similar to those for the khondalitic rocks from the interior of the Western Block of the North China Craton, suggesting a common provenance. In contrast, other metasedimentary rocks in the Trans-North China Orogen, such as the Wanzi supracrustal assemblage in the Fuping Complex, have a source region with both Palaeoproterozoic and Archaean rocks. Their detrital zircon Hf isotopic data indicate reworking of old crustal material and a lack of significant juvenile Palaeoproterozoic magmatic input. These rocks are similar to the coevally deposited meta-sedimentary rocks in the interior of the Eastern Block. We propose that the Luliang khondalites were deposited on the eastern margin of the Western Block in a passive continental margin environment and were thrust eastward later during collision with the Eastern Block. Other metasedimentary rocks in the Trans-North China Orogen were deposited on the western margin of the Eastern Block in a continental arc environment. Our data support the eastward subduction model for the Palaeoproterozoic tectonic evolution of the North China Craton.

A Jurassic garnet-bearing granitic pluton from NE China showing tetrad REE patterns

Abstract NE China is characterized by the massive distribution of Phanerozoic granitoids. Most of them are of I- and A-type granites, whereas S-type granites are rarely documented. The present work deals with the Dongqing pluton, a small granitic body emplaced in the southern Zhangguangcai Range. The pluton comprises a two-mica (±garnet) granite and a garnet-bearing muscovite granite; the latter occurs as veins in the former. The pluton shows a gradational contact with the surrounding host granites. Rb–Sr and Sm–Nd isotope analyses on whole-rocks and minerals reveal that the two types of granites were emplaced synchronously at about 160 Ma. The pluton was emplaced coeval with the surrounding I-type granitic pluton, and had a rapid cooling history. It is characterized by an initial Sr isotopic ratio of ∼0.706, slightly negative eNd(T) values (−0.5 to −1.9) and young depleted-mantle model ages (970–1090 Ma). This suggests that the parent magma originated from partial melting of relatively juvenile crust, which is largely compatible with the general scenario for much of the Phanerozoic granitoids emplaced in the Central Asian Orogenic Belt. Geochemically, the granites of the Dongqing pluton are peraluminous, with a Shand Index (molar ratio A/CNK) of 1.0–1.1 for the two-mica granites and 1.2–1.3 for the garnet-bearing granites. All the garnet-bearing granites and some of the two-mica granites show tetrad REE patterns (=tetrad group), whereas most two-mica granites show normal granitic REE patterns (=normal group). The normal group granites exhibit depletion in Nb, Ta, P and Ti in spidergrams, and generally weak positive Eu anomalies in REE patterns. By contrast, the tetrad group granites manifest depletion in Ba, Nb, Ta, Sr, P, and Ti and significant negative Eu anomalies. The trace element data constrain the parental magmas to having undergone extensive magmatic differentiation. During their late stage magmatic evolution, intense interaction of residual melts with aqueous hydrothermal fluids resulted in the non-CHARAC (charge and radius controlled) trace element behavior and the tetrad effect in REE distribution patterns. This, in turn, leads to the invalidation of the commonly used tectonic discrimination criteria derived from trace element abundances of normal granites. In view of this and previous studies, we conclude that there were probably no S-type granites produced in NE China during the Phanerozoic. Consequently, weathered sedimentary material did not play an important role in the genesis of the strongly peraluminous granites in the Zhangguangcai Range.