Yue-Heng Yang

Hf isotopic compositions of the standard zircons for U-Pb dating

Using the newly published Yb isotopic abundances and the mass bias relationship between Yb and Hf, we carried out an analysis of Hf isotopes in the standard zircon 91500 by means of 193 nm laser attached to Neptune multi-collector ICP-MS (LA-MC-ICPMS). The obtained Hf isotopic data, in eitherin situ or line scan modes, are not only identical for different spot sizes, but also are consistent with previously published results obtained on TIMS or other MC-ICPMS machines within errors. This indicates that it is possible to obtain reliable176Hf/177Hf isotopic ratios for zircon in eitherin situ or line scan conditions on LA-MC-ICPMS machine, and the applied procedures in our study for elemental interfering correction are appropriate for the purpose of acquiring satisfactory accuracy for Hf isotope analyses. The Hf isotopic compositions of four zircon standards in high spatial resolution U-Pb dating, 91500, CZ3, CN92-1 and TEMORA, are measured, respectively. The obtained176Hf/177Hf ratios are 0.282316±4 (n = 34, 2σ) for 91500, 0.281704±6 (n = 16, 2σ) for CZ3, 0.282200±6 (n = 20, 2σ) for CN92-1 and 0.282684±14 (n = 24, 2σ) for TEMORA, respectively, with176Lu/177Hf ratios of ~0.00031, 0.000036, 0.00083 and 0.00127. Zircons 91500 and CZ3 show narrower variations in176Hf/177Hf and176Lu/177Hf ratios than those of zircons CN92-1 and TEMORA, and thus are appropriate standards for the Hf isotope analysis.

Petrogenesis of the Neoproterozoic bimodal volcanic rocks along the western margin of the Yangtze Block: New constraints from Hf isotopes and Fe/Mn ratios

High-precision major element and Hf isotope data are reported for the Neoproterozoic Suxiong volcanic rocks along the western margin of the Yangtze Block. These volcanic rocks have variable εHf(T) values and Fe/Mn ratios. The relatively primitive basalts have high Fe/Mn ratios and high Hf-Nd isotopic compositions, indicating that they were generated by partial melting of garnet clinopyroxene in mantle plume at high pressure. Thus, the Suxiong basalts are genetically related to the proposed Neoproterozoic superplume. On the contrary, a few differentiated basalts have low Fe/Mn ratios and low Hf-Nd isotopic compositions. They are likely to experience assimilation-fractional crystallization process. The Suxiong rhyolites have consistent Hf and Nd model ages of 1.3–1.4 Ga. They are likely generated by shallow dehydration melting of pre-existing young arc igneous rocks associated with the basaltic underplating/intrusion in a continental rift.

The Bikou basalts in the northwestern Yangtze block, South China: Remnants of 820-810 Ma continental flood basalts?

National Natural Science foundation of China[40721063]; Chinese Academy of Sciences[KZCX3-SW-141]; Australian Research Council[DP0770228]

Rapid and precise determination of Sr and Nd isotopic ratios in geological samples from the same filament loading by thermal ionization mass spectrometry employing a single-step separation scheme

Thermal ionization mass spectrometry (TIMS) offers the excellent precision and accuracy of the Sr and Nd isotopic ratio analysis for geological samples, but this method is labour intensive, expensive and time-consuming. In this study, a new analytical protocol by TIMS is presented that aims at improving analytical efficiency and cutting down experimental cost. Using the single-step cation exchange resin technique, mixed Sr and rare earth elements (REEs) fractions were separated from matrix and evaporated to dryness. Afterwards, mixed Sr+REEs fractions were dissolved and loaded onto the same Re filament using 1 μL of 2 M HCl. Then, Sr and Nd were sequentially measured without venting using TIMS. In contrast to conventional TIMS methods, the merits of this analytical protocol are its cost- and time-saving adaptations. The applicability of our method is evaluated by replicated measurements of (87)Sr/(86)Sr and (143)Nd/(144)Nd for nine international silicate rock reference materials, spanning a wide range of bulk compositions. The typical internal precision in this study is ca. 0.001% (RSE) for (87)Sr/(86)Sr and (143)Nd/(144)Nd; the analytical results obtained for these standard rocks show a good agreement with reported values, indicating the effectiveness of the proposed method.

The Precambrian Khondalite Belt in the Daqingshan area, North China Craton: evidence for multiple metamorphic events in the Palaeoproterozoic era

Abstract High-grade pelitic metasedimentary rocks (khondalites) are widely distributed in the northwestern part of the North China Craton and were named the ‘Khondalite Belt’. Prior to the application of zircon geochronology, a stratigraphic division of the supracrustal rocks into several groups was established using interpretative field geology. We report here SHRIMP U–Pb zircon ages and Hf-isotope data on metamorphosed sedimentary and magmatic rocks at Daqingshan, a typical area of the Khondalite Belt. The main conclusions are as follows: (1) The early Precambrian supracrustal rocks belong to three sequences: a 2.56–2.51 Ga supracrustal unit (the previous Sanggan ‘group’), a 2.51–2.45 Ga supracrustal unit (a portion of the previous upper Wulashan ‘group’) and a 2.0–1.95 Ga supracrustal unit (including the previous lower Wulashan ‘group’, a portion of original upper Wulashan ‘group’ and the original Meidaizhao ‘group’) the units thus do not represent a true stratigraphy; (2) Strong tectono-thermal events occurred during the late Neoarchaean to late Palaeoproterozoic, with four episodes recognized: 2.6–2.5, 2.45–2.37, 2.3–2.0 and 1.95–1.85 Ga, with the latest event being consistent with the assembly of the Palaeoproterozoic supercontinent Columbia; (3) During the late Neoarchaean to late Palaeoproterozoic (2.55–2.5, 2.37 and 2.06 Ga) juvenile, mantle-derived material was added to the crust.

Hf isotopes of the 3.8 Ga zircons in eastern Hebei Province, China： Implications for early crustal evolution of the North China Craton

Zircon U-Pb dating indicates that the fuchsite quartzite in eastern Hebei Province was derived from weathering and erosion of the 3.6–3.8 Ga granitic rocks.In-situ zircon Hf analyses show that the Lu-Hf isotopic system remained closed during later thermal disturbances. Zircons with concordant ages have Hf isotopic model ages of about 3.8 Ga, suggesting a recycling of this ancient crust. The ∼3.8 Ga zircons have similar Hf isotopic compositions to those of chondrite, indicating that their source rocks (granitic rocks) were derived from partial melting of the juvenile crust which originated from a mantle without significant crust-mantle differentiation. Therefore, it is proposed that there was no large-scale crustal growth before ∼3.8 Ga in eastern Hebei Province. Considering zircon Hf isotopic data from other areas, it is concluded that the most ancient crust in the North China Craton probably formed at about 4.0 Ga, and the possibility to find crust older than 4.0 Ga is very limited.

Precise determination of Sm, Nd concentrations and Nd isotopic compositions at the nanogram level in geological samples by thermal ionization mass spectrometry

In this paper, a high sensitivity method for measurements of Nd isotopes as NdO+, on a TIMS using a single W filament with TaF5 as an ion emitter is presented. Although analyzing Nd isotopes as oxides (NdO+) is a well known technique, this is the first report to analyze Nd isotopic compositions as oxides using W filaments and the TaF5 emitter. When 0.5–1 ng loads of a Neodymium isotopic reference reagent, JNdi-1, were measured using this method, the ion yields were found to be mostly in excess of 15% and could be as high as 32%. Internal precision on 143Nd/144Nd could be better than 10 ppm (2SE) for 1 ng JNdi-1 loads and better than 15 ppm (2SE) for 0.5 ng JNdi-1 loads; thirteen replicates of 0.5–1 ng JNdi-1 loads yielded a 143Nd/144Nd value of 0.512112 ± 0.000028 (2SD). Compared with the previously reported NdO+ measurement method using the Re (or W) filaments + Silica-gel + H3PO4 loading techniques, this method has advantages including higher sensitivity, a more stable ion beam, and no need for oxygen gas to be bled into the ion source chamber. Sm isotopes were analyzed as Sm+ using the W filaments and the TaF5 emitter, and high sensitivity and good ion beam stability were also obtained. Several international rock reference materials, including an ultramafic rock reference material USGS PCC-1 that contains very low amounts of Sm and Nd, were analyzed with full column chemistry and the TaF5 method, and the results of Sm, Nd concentrations and Nd isotopic data are in good agreement with the reported values. Combined with a highly efficient and low-blank column chemistry to separate Nd from Sm, Ce, and Pr, this method holds potential to analyze Sm, Nd concentrations and Nd isotopic compositions of highly depleted peridotites; very small aliquots of minerals such as garnets; extra-terrestrial materials of limited sample size; and environmental samples that contain very low quantities of Sm and Nd.

Precise and accurate determination of Sm, Nd concentrations and Nd isotopic compositions in geological samples by MC-ICP-MS

In this work, we established a highly reproducible analysis of Sm, Nd concentrations and Nd isotopic compositions in geological samples by isotope dilution analysis with MC-ICP-MS. This technique is superior in terms of the analytical reproducibility or rapidity of analysis compared with quadrupole ICP-MS or with thermal ionization mass spectrometry (TIMS) isotope dilution techniques. Samples were spiked with 149Sm–150Nd enriched tracer and then digested by a commonly used HF, HNO3 and HClO4 acid protocol. The bulk rare earth elements (REEs) were separated from the sample on a standard cation exchange resin, and further purified on Eichrom Technologies Ln Resin, to obtain Sm and Nd fractions prior to mass spectrometric measurements. Replicate analyses of international certified reference materials (CRMs) demonstrate that our obtained 147Sm/144Nd and 143Nd/144Nd isotopic ratios are in good agreement with previously published values from isotope dilution methods. In addition to determining the concentrations of Sm and Nd, the Nd isotopic composition can be measured simultaneously during Nd isotope dilution run. Additionally, a mineral Sm-Nd isochronal age that is identical to, within error, a U-Th-Pb zircon age for the same rock is further measured and validates the robustness of the present protocol. Therefore, the high actual sample throughput inherent to the MC-ICP-MS can be fully exploited for the determination of Sm and Nd concentrations and Nd isotopic compositions.

A rapid single column separation scheme for high-precision Sr–Nd–Pb isotopic analysis in geological samples using thermal ionization mass spectrometry

Thermal ionization mass spectrometry (TIMS) is considered the most accurate technique for determining Sr–Nd–Pb isotopic ratios in geological samples. However, time-consuming and complex sample separation procedures greatly hinder the instrumental measurement efficiency. In this study, a single-column separation chemistry procedure for Sr–Nd–Pb from single rock dissolution was developed. The chemistry procedure was designed to minimize the number of evaporation steps and considerably shorten the separation time, enabling high throughput for TIMS. In contrast to conventional three-column separation procedures (∼3 days), this technique was characterized by high efficiency superiority in terms of separation time (∼8 hours), a 3-fold enhancement in the separation efficiency. The stability of our procedure was demonstrated by replicated TIMS measurements of 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios for six international silicate rock reference materials, spanning a wide range of bulk compositions. The analytical results obtained for these standards agreed well with published data. The external reproducibility (2 RSD, n = 10) of a BCR-2 standard sample was ±0.0020% for 87Sr/86Sr, ±0.0023% for 143Nd/144Nd, and ±0.021–0.033% for 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios.

Crustal growth and intracrustal recycling in the middle segment of the Trans-North China Orogen, North China Craton: a case study of the Fuping Complex

The most important crustal growth on Earth occurred at ~2.7 Ga, but the North China Craton (NCC) is characterized by prevalent development of ~2.5 Ga juvenile crust, with relatively rare records of ~2.7 Ga crustal growth. The Fuping Complex in the middle segment of the Trans-North China Orogen (TNCO) between the Eastern and Western blocks of the NCC is composed mainly of ~2.5 Ga Fuping tonalitic–trondhjemitic–granodioritic (TTG) gneisses and Longquanguan augen gneisses, ~2.1 Ga Nanying granitic gneisses and the Wanzi supracrustal rocks. Previous studies have suggested one major phase of crustal growth at ~2.5 Ga, possible intracrustal recycling at ~2.1 Ga and the presence of older rocks in the Fuping Complex, but there has been no record of ~2.7 Ga crustal growth. The Fuping TTG gneisses are dominated by stromatic migmatite, and new U–Pb dating of magmatic zircons from two stromatic migmatite samples yielded three different ages: (1) 2.75 Ga, which is the oldest age obtained from the Fuping TTG gneisses, (2) 2.54 Ga, which just falls in the published zircon U–Pb age range of 2.53 to 2.47 Ga for the Fuping TTG gneisses, and (3) 2.11 Ga, which is almost the same as the age of the Nanying granitic gneisses. Therefore, there are two generations of TTG gneisses in the Fuping Complex. Importantly, both of the 2.75 and 2.54 Ga zircons have the highest e Hf ( t ) values, almost equal to the contemporaneous depleted mantle. This indicates high contributions of juvenile material to the two generations of TTG gneisses. In contrast, the 2.11 Ga zircons have apparently low e Hf ( t ) values of −0.47 to +2.04, just falling in between 2.55 and 2.75 Ga continental crust values. This strongly suggests the reworking of the two generations of TTG gneisses at 2.1 Ga. Zircon U–Pb and Hf isotopes convincingly reveal two major phases of crustal growth in the Fuping Complex at ~2.7 and ~2.5 Ga, the same as in the northern and southern segments of the TNCO, and also confirm one major phase of intracrustal recycling at ~2.1 Ga, which may be responsible for the Nanying granitic gneisses.