G. Brent Dalrymple

Hawaiian-Emperor Chain and Its Relation to Cenozoic Circumpacific Tectonics

The Hawaiian Ridge and Emperor Seamounts appear to form a single chain of tholeiitic shield volcanoes that erupted sequentially on the sea floor of the central Pacific Ocean during Tertiary and Quaternary time. The chain cuts obliquely across the older Cretaceous structural patterns of that sea floor. While the pattern of the chain as a whole is linear, the individual volcanoes lie on short, sigmoidal, en echelon loci that are subparallel with respect to each other and that may represent extensional features in the crust and upper mantle. In general, the order of eurption progressed from northwest to southeaśt along the chain, but the rate of progression of volcanism along individual loci is nonlinear where best studied in the southeastern part of the chain. Furthermore, simultaneous eruptions appear to have occurred within a distance along the chain of about 200 to 400 km. The available data are consistent with a genesis related to the motion of the Pacific crust over a melting spot in the mantle. This melting spot, which may be due to either excess heat or pressure release, appears to have a diameter of about 300 km and is presently centered slightly north of the island of Hawaii. We concur with the idea that the bend in the Hawaiian-Emperor chain probably reflects a significant change in the motion of the Pacific plate. Our best estimate of the age of the Hawaiian-Emperor bend, based on the existing radiometric data, is 24.6 ± 2.5 m.y., which correlates with a time of increased tectonic activity in the western Pacific island arcs and along the northern and eastern boundaries of the Pacific plate. The vector change in the motion of the Pacific plate (with respect to the melting spot) that is required to produce the bend is about 12 cm/yr in a west-southwest-ward direction.

Identification of excess 40Ar by the 40Ar/39Ar age spectrum technique

Abstract 40 Ar/ 39 Ar incremental heating experiments on igneous plagioclase, biotite, and pyroxene that contain known amounts of excess 40 Ar indicate that saddle-shaped age spectra are diagnostic of excess 40 Ar in igneous minerals as well as in igneous rocks. The minima in the age spectra approach but do not reach the crystallization age. Neither the age spectrum diagram nor the 40 Ar/ 36 Ar versus 39 Ar/ 36 Ar isochron diagram reliably reveal the crystallization age in such samples.

40Ar/39Ar technique of KAr dating: a comparison with the conventional technique

Abstract K-Ar ages have been determined by the 40 Ar/ 39 Ar total fusion technique on 19 terrestrial samples whose conventional K-Ar ages range from 3.4 my to nearly 1700 my. Sample materials included biotite, muscovite, sanidine, adularia, plagioclase, hornblende, actinolite, alunite, dacite, and basalt. For 18 samples there are no significant differences at the 95% confidence level between the K Ar ages obtained by these two techniques; for one sample the difference is 4.3% and is statistically significant. For the neutron doses used in these experiments (≈4 × 10 18 nvt) it appears that corrections for interfering Ca- and K-derived Ar isotopes can be made without significant loss of precision for samples with K/Ca > 1 as young as about 5 × 10 5 yr, and for samples with K/Ca 7 yr. For younger samples the combination of large atmospheric Ar corrections and large corrections for Ca- and K-derived Ar may make the precision of the 40 Ar/ 39 Ar technique less than that of the conventional technique unless the irradiation parameters are adjusted to minimize these corrections.

40Ar/39Ar age spectra of some undisturbed terrestrial samples

Abstract 40 Ar/ 39 Ar age spectra and 40 Ar/ 36 Ar vs 39 Ar/ 36 Ar isochrons were determined by incremental heating for 11 terrestrial rocks and minerals whose geology indicates that they represent essentially undisturbed systems. The samples include muscovite, biotite, hornblende, sanidine, plagioclase, dacite, diabase and basalt and range in age from 40 to 1700 m.y. For each sample, the 40 Ar/ 39 Ar ratios, corrected for atmospheric and neutron-generated argon isotopes, are the same for most of the gas fractions released and the age spectra, which show pronounced plateaus, thus are consistent with models previously proposed for undisturbed samples. Plateau ages and isochron ages calculated using plateau age fractions are concordant and appear to be meaningful estimates of the crystallization and cooling ages of these samples. Seemingly anomalous age spectrum points can be attributed entirely to small amounts of previously unrecognized argon loss and to gas fractions that contain too small (less than 2 per cent) a proportion of the 39 Ar released to be geologically significant. The use of a quantitative abscissa for age spectrum diagrams is recommended so that the size of each gas fraction is readily apparent. Increments containing less than about 4–5 per cent of the total 39 Ar released should be interpreted cautiously. Both the age spectrum and isochron methods of data reduction for incremental heating experiments are worthwhile, as each gives slightly different but complementary information about the sample from the same basic data. Use of a least-squares fit that allows for correlated errors is recommended for 40 Ar/ 36 Ar vs 39 Ar/ 36 Ar isochrons. The results indicate that the 40 Ar/ 39 Ar incremental heating technique can be used to distinguish disturbed from undisturbed rock and mineral systems and will be a valuable geochronological tool in geologically complex terranes.

Potassium-Argon Ages and Paleomagnetism of the Waianae and Koolau Volcanic Series, Oahu, Hawaii

Paleomagnetic and potassium-argon measurements on 786 oriented cores from 99 volcanic units at 18 sites in the Waianae and Koolau Ranges, Oahu, when combined with data from previous studies, show that the sub-aerial Waianae Volcano was active only from about 3.6 to 2.4 m.y. ago and the subaerial Koolau Volcano from about 2.6 to 1.8 m.y. ago. There is some evidence that Waianae Volcano was still active when Koolau Volcano emerged from the sea. The predominantly tholeiitic lower and middle members of the Waianae Volcanic Series are approximately contemporaneous and were extruded during the late Gilbert and early Gauss geomagnetic polarity epochs. They were followed within less than 0.2 m.y. by the alkalic lavas of the upper member, which were probably extruded largely during the later part of the Gauss normal polarity epoch. The Koolau Volcanic Series was extruded entirely during the early Matuyama reversed polarity epoch. Data from three thick stratigraphic sections in the Waianae and Koolau Volcanic Series indicate that stacks of lava flows as much as 470 m thick can be formed in less than 0.25 m.y. and that the maximum average period between superimposed lava flows is on the order of 103 yrs. Additional data on the hawaiite flow that led to the discovery of the Kaena reversed event indicate that this reversed flow is 2.85 ± 0.05 m.y. old. Angular dispersion of virtual geomagnetic poles (VGP) in the Hawaiian Islands appears to have decreased during the past 5 m.y. This may be caused by a decrease in dipole wobble, a decrease in the nondipole component of the Earth9 magnetic field, or the accumulated effects of weathering, tectonism, and geomorphic processes in older rocks. The mean Waianae and Koolau VGPs are slightly on the side of the Earth9s rotation axis away from Oahu. This supports, but does not prove, the hypothesis that the axial dipole is displaced slightly northward from the Earth9s center. Three VGP “excursions” were recorded in sections of lava in the Waianae and Koolau ranges. During these excursions, the VGPs appear to have traveled away from or toward the geographic axis along great circle paths, suggesting they may be related to the dipole rather than the nondipole field and may record aborted reversals in polarity or rapid and infrequent dipole tilts.

The Taylor Creek Rhyolite of New Mexico: a rapidly emplaced field of lava domes and flows

The Tertiary Taylor Creek Rhyolite of southwest New Mexico comprises at least 20 lava domes and flows. Each of the lavas was erupted from its own vent, and the vents are distributed throughout a 20 km by 50 km area. The volume of the rhyolite and genetically associated pyroclastic deposits is at least 100 km3 (denserock equivalent). The rhyolite contains 15%–35% quartz, sanidine, plagioclase, ±biotite, ±hornblende phenocrysts. Quartz and sanidine account for about 98% of the phenocrysts and are present in roughly equal amounts. With rare exceptions, the groundmass consists of intergrowths of fine-grained silica and alkali feldspar. Whole-rock major-element composition varies little, and the rhyolite is metaluminous to weakly peraluminous; mean SiO2 content is about 77.5±0.3%. Similarly, major-element compositions of the two feldsparphenocryst species also are nearly constant. However, whole-rock concentrations of some trace-elements vary as much as several hundred percent. Initial radiometric age determinations, all K−Ar and fission track, suggest that the rhyolite lava field grew during a period of at least 2 m.y. Subsequent 40Ar/39Ar ages indicate that the period of growth was no more than 100 000 years. The time-space-composition relations thus suggest that the Taylor Creek Rhyolite was erupted from a single magma reservoir whose average width was at least 30 km, comparable in size to several penecontemporaneous nearby calderas. However, this rhyolite apparently is not related to a caldera structure. Possibly, the Taylor Creek Phyolite magma body never became sufficiently volatile rich to produce a large-volume pyroclastic eruption and associated caldera collapse, but instead leaked repeatedly to feed many relatively small domes and flows.The new 40Ar/39Ar ages do not resolve preexisting unknown relative-age relations among the domes and flows of the lava field. Nonetheless, the indicated geologically brief period during which Taylor Creek Rhyolite magma was erupted imposes useful constraints for future evaluation of possible models for petrogenesis and the origin of trace-element characteristics of the system.

Age and petrology of alkalic postshield and rejuvenated-stage lava from Kauai, Hawaii

At the top of the Waimea Canyon Basalt on the island of Kauai, rare flows of alkalic postshield-stage hawaiite and mugearite overlie tholeiitic flows of the shield stage. These postshield-stage flows are 3.92 Ma and provide a younger limit for the age of the tholeiitic shield stage. The younger Koloa Volcanics consist of widespread alkalic rejuvenated-stage flows and vents of alkalic basalt, basanite, nephelinite, and nepheline melilitite that erupted between 3.65 and 0.52 Ma. All the flows older than 1.7 Ma occur in the west-northwestern half of the island and all the flows younger than 1.5 Ma occur in the east-southeastern half. The lithologies have no spatial or chronological pattern. The flows of the Koloa Volcanics are near-primary magmas generated by variable small degrees of partial melting of a compositionally heterogeneous garnet-bearing source that has about two-thirds the concentration of P2O5, rare-earth elements, and Sr of the source of the Honolulu Volcanics on the island of Oahu. The same lithology in the Koloa and Honolulu Volcanics is generated by similar degrees of partial melting of distinct source compositions. The lavas of the Koloa Volcanics can be generated by as little as 3 percent to as much as 17 percent partial melting for nepheline melilitite through alkalic basalt, respectively. Phases that remain in the residue of the Honolulu Volcanics, such as rutile and phlogopite, are exhausted during formation of the Koloa Volcanics at all but the smallest degrees of partial melting. The mantle source for Kauai lava becomes systematically more depleted in 87Sr/86Sr as the volcano evolves from the tholeiitic shield stage to the alkalic postshield stage to the alkalic rejuvenated stage: at the same time, the lavas become systematically more enriched in incompatible trace elements. On a shorter timescale, the lavas of the Koloa Volcanics display the same compositional trends, but at a lower rate of change. The source characteristics of the Koloa Volcanics, considered along with those of the Honolulu Volcanics, support a mixing model in which the source of rejuvenated-stage lava represents large-percent melts of a plume source mixed with small amounts of small-percent melts of a heterogeneous mid-ocean-ridge source.

Potassium-Argon Age and Paleomagnetism of Diabase Dikes in Liberia: Initiation of Central Atlantic Rifting

Tholeiitic diabase dikes that trend northwest-southeast, parallel to the coastline, are common in northwestern Liberia. K-Ar whole-rock and mineral ages determined from dikes that intrude Precambrian crystalline rocks are discordant and range from 186 to 1,213 m.y. Incremental heating experiments on three neutron-irradiated samples of these rocks give “saddle-shaped” 40 Ar/ 39 Ar release diagrams that reach minima of less than 300 m.y. at intermediate temperatures and that do not fit a 40 Ar/ 36 Ar versus 39 Ar/ 36 Ar isochron. K-Ar ages determined from diabase dikes and sills that intrude Paleozoic sedimentary rocks near the coast are all within the range 173 to 192 m.y. 40 Ar/ 39 Ar incremental heating data for one of these samples gives a plateau age and a 40 Ar/ 36 Ar versus 39 Ar/ 36 Ar isochron age that are concordant with the conventional K-Ar age. The conventional and 40 Ar/ 39 Ar K-Ar data show that the dikes intruding Precambrian basement rocks contain large and variable amounts of excess 40 Ar, whereas the diabase intruding Paleozoic sandstone does not. All of the intrusions are probably earliest Jurassic in age. Mean paleomagnetic directions in six dikes and sills that intrude sedimentary rocks are nearly parallel to mean paleomagnetic directions in 19 dikes that intrude Precambrian rock, further evidence for contemporaneity. The paleomagnetic pole derived from all 25 diabase units is at lat 68° N., long 242° E., with α 95 = 5°, in close agreement with other Mesozoic paleomagnetic poles from the African continent. A mean paleomagnetic pole for northwest Africa has been calculated using these data and published paleomagnetic directions from 19 other intrusive rock units that have similar radiometric ages in Morocco and Sierra Leone. This pole is compared with another paleomagnetic pole calculated from published data from 16 localities in igneous rocks of latest Triassic to earliest Jurassic age distributed from Nova Scotia to Pennsylvania. The comparison shows that, with the African and North American continents in their present positions, the two poles differ by 44° of arc, but when the continents are restored to the predrift configuration proposed by Bullard and others (1965), the angular difference diminishes to 3°. This coincidence of paleomagnetic poles provides an earliest limit of 180 ± 10 m.y. for the separation of Africa from North America.

Petrography and K-Ar Ages of Dredged Volcanic Rocks from the Western Hawaiian Ridge and the Southern Emperor Seamount Chain

Alkalic basalt dredged from Yuryaku Seamount in the southernmost Emperor Seamount chain and from the western Hawaiian Ridge at Pearl and Hermes Reef and at two unnamed seamounts 160 and 380 km west of Midway is similar to the alkalic basalt that caps the volcanoes in the Hawaiian Islands. Conventional and 40 Ar/ 39 Ar K-Ar analyses give best weighted mean ages of 42.3 ± 1.6 m.y. for Yuryaku Seamount, 27.3 ± 0.4 m.y. and 26.7 ± 0.5 m.y. for the two unnamed seamounts, and 20.1 ± 0.5 m.y. for the volcano that forms Pearl and Hermes Reef. The data show that the age of the Hawaiian-Emperor bend is about 41 to 43 m.y. Although the volcanoes in the Hawaiian-Emperor chain generally increase in age to the north and west of the island of Hawaii, the measured age-distance relations along the chain are not linear in detail. A phonolite, possibly a differentiated member of a posterosional nephelinic suite and the first found on the Hawaiian Ridge, was recovered from Pearl and Hermes Reef. Samples of analcime tephrite recovered from the unnamed seamount 380 km west of Midway may also be derived from a posterosional nephelinic suite.

A test of the40Ar/39Ar age spectrum technique on some terrestrial materials

Abstract 40 Ar/ 39 Ar age spectra were determined for 10 terrestrial rock and mineral samples whose geologic history is known from independent evidence. The spectra for six mineral and whole rock samples, including biotite, feldspar, hornblende, muscovite, and granodiorite, that have experienced post-crystallization heating did not reveal the age of crystallization in any obvious way. Minima in the spectra, however, give reasonable maximum ages for reheating and high-temperature maxima can be interpreted as minimum crystallization ages. High-temperature ages of microcline and albite that have not been reheated are approximately 10% younger than the known crystallization age. Apparently there are no domains in these feldspars that have retained radiogenic 40 Ar quantitatively. Spectra from two diabase samples that contain significant quantities of excess argon might mistakenly be interpreted as spectra from reheated samples and do not give the age of emplacement. The 40 Ar/ 39 Ar age spectrum technique may be a potentially valuable tool for the study of geologic areas with complex histories, but the interpretation of age spectra from terrestrial samples seems to be more difficult than suggested by some previous studies.