Marvin A. Lanphere

Volcanic and structural evolution of Taupo Volcanic Zone, New Zealand: a review

The Taupo Volcanic Zone (TVZ) in the central North Island is the main focus of young volcanism in New Zealand. Andesitic activity started at c. 2 Ma, joined by voluminous rhyolitic (plus minor basaltic and dacitic) activity from c. 1.6 Ma. The TVZ is c. 300 km long (200 km on land) and up to 60 km wide, as defined by vent positions and caldera structural boundaries. The total volume of TVZ volcanic deposits is uncertain because a sub-volcanic basement has not been identified, but present data suggest bulk volumes of 15–20,000 km3, and that faulted metasediments form most of the immediate subvolcanic basement. Rhyolite (≥15,000 km3 bulk volume, typically 70–77% SiO2) is the dominant magma erupted in the TVZ (mostly as calderaforming ignimbrite eruptions), andesite is an order of magnitude less abundant, and basalt and dacite are minor in volume (< 100 km3 each). The history of the TVZ is here divided into ‘old TVZ’ from 2.0 Ma to 0.34 Ma, and ‘young TVZ’ from 0.34 Ma onwards, separated by the Whakamaru eruptions, which obscured much of the evidence for older activity within the zone. The TVZ shows a pronounced segmentation into northeastern and southwestern andesite-dominated extremities with composite cones and no calderas, and a central 125-km-long rhyolite-dominated segment. Eight rhyolitic caldera centres have so far been identified in the central segment, of which two (Mangakino and Kapenga) are composite features, and more centres will probably be delineated as further data accumulate. These centres account for 34 inferred caldera-forming ignimbrite eruptions, in the c. 1.6-Ma lifetime of the central TVZ. The modern central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c. 0.28 m3 s−1, and available information suggests this has been so for at least the past 0.34 Ma. The rhyolites show no major compositional changes with time, though the extent of magma chamber zonation may have changed with the incoming of rifting and crustal extension in the past c. 0.9 Ma. Within the central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. Between 0.9 and 0.34 Ma, a major episode of uplift affected areas around the TVZ, while at the same time the main focus of activity may have migrated eastwards within the TVZ accompanying rifting along the axis of the zone. The modern TVZ is rifting at rates between 7 and 18 mm a−1 and restoration of the thin (15km) ‘crust’ (Vp ≤ 6.1 km s−1) beneath the central TVZ to its pre-rifting thickness (25 km) implies that rifting at such rates may have begun only at c. 0.9 Ma. The TVZ is a rifted arc, but its longitudinally segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Chronology and dynamics of a large silicic magmatic system: Central Taupo Volcanic Zone, New Zealand

The central Taupo Volcanic Zone in New Zealand is a region of intense Quaternary silicic volcanism accompanying rapid extension of continental crust. At least 34 caldera-forming ignimbrite eruptions have produced a complex sequence of relatively short-lived, nested, and/or overlapping volcanic centers over 1.6 m.y. Silicic volcanism at Taupo is similar to the Yellowstone system in size, longevity, thermal flux, and magma output rate. However, Taupo contrasts with Yellowstone in the exceptionally high frequency, but small size, of caldera-forming eruptions. This contrast reflects the thin, rifted nature of the crust, which precludes the development of long-term magmatic cycles at Taupo. 11 refs., 4 figs., 1 tab.

Identification of excess 40Ar by the 40Ar/39Ar age spectrum technique

Abstract 40 Ar/ 39 Ar incremental heating experiments on igneous plagioclase, biotite, and pyroxene that contain known amounts of excess 40 Ar indicate that saddle-shaped age spectra are diagnostic of excess 40 Ar in igneous minerals as well as in igneous rocks. The minima in the age spectra approach but do not reach the crystallization age. Neither the age spectrum diagram nor the 40 Ar/ 36 Ar versus 39 Ar/ 36 Ar isochron diagram reliably reveal the crystallization age in such samples.

40Ar/39Ar technique of KAr dating: a comparison with the conventional technique

Abstract K-Ar ages have been determined by the 40 Ar/ 39 Ar total fusion technique on 19 terrestrial samples whose conventional K-Ar ages range from 3.4 my to nearly 1700 my. Sample materials included biotite, muscovite, sanidine, adularia, plagioclase, hornblende, actinolite, alunite, dacite, and basalt. For 18 samples there are no significant differences at the 95% confidence level between the K Ar ages obtained by these two techniques; for one sample the difference is 4.3% and is statistically significant. For the neutron doses used in these experiments (≈4 × 10 18 nvt) it appears that corrections for interfering Ca- and K-derived Ar isotopes can be made without significant loss of precision for samples with K/Ca > 1 as young as about 5 × 10 5 yr, and for samples with K/Ca 7 yr. For younger samples the combination of large atmospheric Ar corrections and large corrections for Ca- and K-derived Ar may make the precision of the 40 Ar/ 39 Ar technique less than that of the conventional technique unless the irradiation parameters are adjusted to minimize these corrections.

40Ar/39Ar age spectra of some undisturbed terrestrial samples

Abstract 40 Ar/ 39 Ar age spectra and 40 Ar/ 36 Ar vs 39 Ar/ 36 Ar isochrons were determined by incremental heating for 11 terrestrial rocks and minerals whose geology indicates that they represent essentially undisturbed systems. The samples include muscovite, biotite, hornblende, sanidine, plagioclase, dacite, diabase and basalt and range in age from 40 to 1700 m.y. For each sample, the 40 Ar/ 39 Ar ratios, corrected for atmospheric and neutron-generated argon isotopes, are the same for most of the gas fractions released and the age spectra, which show pronounced plateaus, thus are consistent with models previously proposed for undisturbed samples. Plateau ages and isochron ages calculated using plateau age fractions are concordant and appear to be meaningful estimates of the crystallization and cooling ages of these samples. Seemingly anomalous age spectrum points can be attributed entirely to small amounts of previously unrecognized argon loss and to gas fractions that contain too small (less than 2 per cent) a proportion of the 39 Ar released to be geologically significant. The use of a quantitative abscissa for age spectrum diagrams is recommended so that the size of each gas fraction is readily apparent. Increments containing less than about 4–5 per cent of the total 39 Ar released should be interpreted cautiously. Both the age spectrum and isochron methods of data reduction for incremental heating experiments are worthwhile, as each gives slightly different but complementary information about the sample from the same basic data. Use of a least-squares fit that allows for correlated errors is recommended for 40 Ar/ 36 Ar vs 39 Ar/ 36 Ar isochrons. The results indicate that the 40 Ar/ 39 Ar incremental heating technique can be used to distinguish disturbed from undisturbed rock and mineral systems and will be a valuable geochronological tool in geologically complex terranes.

Episodic caldera volcanism in the Miocene southwestern Nevada volcanic field: Revised stratigraphic framework, 40Ar/39Ar geochronology, and implications for magmatism and extension

The middle Miocene southwestern Nevada volcanic field (SWNVF) is a classic example of a silicic multicaldera volcanic field in the Great Basin. More than six major calderas formed between >15 and 7.5 Ma. The central SWNVF caldera cluster consists of the overlapping Silent Canyon caldera complex, the Claim Canyon caldera, and the Timber Mountain caldera complex, active from 14 to 11.5 Ma and centered on topographic Timber Mountain. Locations of calderas older than the Claim Canyon caldera source of the Tiva Canyon Tuff are uncertain except where verified by drilling. Younger peralkaline calderas (Black Mountain and Stonewall Mountain) formed northwest of the central SWNVF caldera cluster. We summarize major revisions of the SWNVF stratigraphy that provide for correlation of lava flows and small-volume tuffs with the widespread outflow sheets of the SWNVF. New laser fusion 40 Ar/ 39 Ar isotopic ages are used to refine and revise the timing of eruptive activity in the SWNVF. The use of high-sensitivity mass spectrometry allowed analysis of submilligram-sized samples with analytical uncertainties of ∼0.3% (1σ), permitting resolution of age differences as small as 0.07 Ma. These results confirm the revised stratigraphic succession and document a pattern of episodic volcanism in the SWNVF. Major caldera episodes (Belted Range, Crater Flat, Paintbrush, Timber Mountain, and Thirsty Canyon Groups) erupted widespread ash-flow sheets within 100-300 k.y. time spans, and pre- and post-caldera lavas erupted within 100-300 k.y. of the associated ash flows. Peak volcanism in the SWNVF occurred during eruption of the Paintbrush and Timber Mountain Groups, when over 4500 km 3 of metaluminous magma was erupted in two episodes within 1.35 m.y., separated by a 750 k.y. magmatic gap. Peralkaline and metaluminous magmatism in the SWNVF overlapped in time and space. The peralkaline Tub Spring and Grouse Canyon Tuffs erupted early, and the peralkaline Thirsty Canyon Group tuffs and Stonewall Flat Tuff erupted late in the history of the SWNVF, flanking the central, volumetrically dominant peak of metaluminous volcanism. Magma chemistry transitional between peralkaline and metaluminous magmas is indicated by petrographic and chemical data, particularly in the overlapping Grouse Canyon and Area 20 calderas of the Silent Canyon caldera complex. Volcanism in the SWNVF coincided with the Miocene peak of extensional deformation in adjoining parts of the Great Basin. Although regional extension was concurrent with volcanism, it was at a minimum in the central area of the SWNVF, where synvolcanic faulting was dominated by intra-caldera deformation. Significant stratal tilting and paleomagnetically determined dextral shear affected the southwestern margin of the SWNVF between the Paint-brush and Timber Mountain caldera episodes. Larger magnitude detachment faulting in the Bullfrog Hills, southwest of the central SWNVF caldera cluster, followed the climactic Timber Mountain caldera episode. Postvolcanic normal faulting was substantial to the north, east, and south of the central SWNVF caldera cluster, but the central area of peak volcanic activity remained relatively unextended in postvolcanic time. Volcanism and extension in the SWNVF area were broadly concurrent, but SWNVF area were broadly concurrent, but in detail they were episodic in time and not coincident in space

Revised ages for tuffs of the Yellowstone Plateau volcanic field: Assignment of the Huckleberry Ridge Tuff to a new geomagnetic polarity event

40 Ar/ 39 Ar ages were determined on the three major ash-flow tuffs of the Yellowstone Plateau volcanic field in the region of Yellowstone National Park in order to improve the precision of previously determined ages. Total-fusion and incremental- heating ages of sanidine yielded the following mean ages: Huckleberry Ridge Tuff—2.059 ± 0.004 Ma; Mesa Falls Tuff— 1.285 ± 0.004 Ma; and Lava Creek Tuff— 0.639 ± 0.002 Ma. The Huckleberry Ridge Tuff has a transitional magnetic direction and has previously been related to the Reunion Normal- Polarity Subchron. Dating of the Reunion event has been reviewed and its ages have been normalized to a common value for mineral standards. The age of the Huckleberry Ridge Tuff is significantly younger than lava flows of the Reunion event on Re union Island, supporting other evidence for a normal-polarity event younger than the Reunion event.

Distribution and Age of High-Grade Blueschists, Associated Eclogites, and Amphibolites from Oregon and California

Isolated blocks of high-grade blueschist and amphibolite facies metamorphic rocks occur within the Jurassic and Cretaceous eugeosynclinal deposits of the Coast Ranges of southwestern Oregon and California. The blocks range in size from individual rock masses commonly 5 to 1,000 ft in diameter to a few larger masses as much as 7 mi long and 2 mi wide. The high-grade blocks are predominantly basaltic in composition and include glaucophane schists, eclogites, and gneissic rocks of the amphibolite facies. Field relationships indicate that the blocks are closely associated with serpentine, that high-grade blueschist and amphibolite blocks, lower grade blueschists, volcanic rocks, and cherts occupy disturbed zones that may be related to thrusting, and that there is no exposed in situ provenance for the high-grade blueschists, eclogites, and amphibolites. Potassium-argon mineral ages of white mica and actinolite from the blueschists and of hornblende from the amphibolites indicate that these minerals crystallized approximately 150 m.y. ago, but the ages measured on glaucophane from the blueschist blocks are commonly younger. These data suggest that the high-grade blue-schist and amphibolite blocks represent fragments of a cryptic metamorphic terrane of pre-Tithonian age that have been tectonically mixed with younger rocks of the Franciscan Formation in California and Otter Point Formation in Oregon. The younger ages for glaucophane probably reflect metamorphic episodes in which lower grade in situ blueschist facies mineral assemblages were developed in the blocks after their emplacement within the Franciscan Formation. This pre-Tithonian cryptic metamorphic terrane probably developed as a result of interaction between oceanic and continental plates. The occurrence of tectonic blocks of this terrane within melange zones in Oregon and California may be related to later plate interaction.

Precise K-Ar, 40Ar/39Ar, Rb-Sr and U/Pb mineral ages from the 27.5 Ma fish canyon tuff reference standard

The accuracy of ages measured using the 40Ar/39Ar technique is affected by uncertainties in the age of radiation fluence-monitor minerals. At present, there is lack of agreement about the ages of certain minerals used as fluence monitors. The accuracy of the age of a standard may be improved if the age can be measured using different decay schemes. This has been done by measuring ages on minerals from the Oligocene Fish Canyon Tuff (FCT) using the K–Ar, 40Ar/39Ar, Rb–Sr and U/Pb methods. K–Ar and 40Ar/39Ar total fusion ages of sanidine, biotite and hornblende yielded a mean age of 27.57±0.36 Ma. The weighted mean 40Ar/39Ar plateau age of sanidine and biotite is 27.57±0.18 Ma. A biotite–feldspar Rb–Sr isochron yielded an age of 27.44±0.16 Ma. The U–Pb data for zircon are complex because of the presence of Precambrian zircons and inheritance of radiogenic Pb. Zircons with 207Pb/235U<0.4 yielded a discordia line with a lower concordia intercept of 27.52±0.09 Ma. Evaluation of the combined data suggests that the best age for FCT is 27.51 Ma.

The 40Ar/39Ar and K/Ar dating of lavas from the Hilo 1-km core hole, Hawaii Scientific Drilling Project

Mauna Kea lava flows cored in the Hilo hole range in age from <200 ka to about 400 ka based on 40Ar/39Ar incremental heating and K-Ar analyses of 16 groundmass samples and one coexisting plagioclase. The lavas, all subaerially deposited, include a lower section consisting only of tholeiitic basalts and an upper section of interbedded alkalic, transitional tholeiitic, and tholeiitic basalts. The lower section has yielded predominantly complex, discordant 40Ar/39Ar age spectra that result from mobility of 40Ar and perhaps K, the presence of excess 40Ar, and redistribution of 39Ar by recoil. Comparison of K-Ar ages with 40Ar/39Ar integrated ages indicates that some of these samples have also lost 39Ar. Nevertheless, two plateau ages of 391 ± 40 and 400 ± 26 ka from deep in the hole, combined with data from the upper section, show that the tholeiitic section accumulated at an average rate of about 7 to 8 m/kyr and has a mean recurrence interval of 0.5 kyr/flow unit. Samples from the upper section yield relatively precise 40Ar/39Ar plateau and isotope correlation ages of 326 ± 23, 241 ± 5, 232 ± 4, and 199 ± 9 ka for depths of −415.7 m to −299.2 m. Within their uncertainty, these ages define a linear relationship with depth, with an average accumulation rate of 0.9 m/kyr and an average recurrence interval of 4.8 kyr/flow unit. The top of the Mauna Kea sequence at −280 m must be older than the plateau age of 132 ± 32 ka, obtained for the basal Mauna Loa flow in the corehole. The upward decrease in lava accumulation rate is a consequence of the decreasing magma supply available to Mauna Kea as it rode the Pacific plate away from its magma source, the Hawaiian mantle plume. The age-depth relation in the core hole may be used to test and refine models that relate the growth of Mauna Kea to the thermal and compositional structure of the mantle plume.