G.M. Keating

Models of Venus neutral upper atmosphere - Structure and composition

Abstract Models of the Venus neutral upper atmosphere, based on both in-situ and remote sensing measurements, are provided for the height interval from 100 to 3,500 km. The general approach in model formulation was to divide the atmosphere into three regions: 100 to 150 km, 150 to 250 km, and 250 to 3,500 km. Boundary conditions at 150 km are consistent with both drag and mass spectrometer measurements. A paramount consideration was to keep the models simple enough to be used conveniently. Available observations are reviewed. Tables are provided for density, temperature, composition (CO 2 , O, CO, He, N, N 2 , and H), derived quantities, and day-to-day variability as a function of solar zenith angle on the day- and nightsides. Estimates are made of other species, including O 2 and D. Other tables provide corrections for solar activity effects on temperature, composition, and density. For the exosphere, information is provided on the vertical distribution of normal thermal components (H, O, C, and He) as well as the hot components (H, N, C, O) on the day- and nightsides.

Ozone reference models for the middle atmosphere

Data on monthly latitudinal variations in middle-atmosphere vertical ozone profiles are presented, based on extensive Nimbus-7, AE-2, and SME satellite measurements from the period 1978-1982. The coverage of the data sets, the characteristics of the sensors, and the analysis techniques applied are described, and the results are compiled in tables and graphs. These ozone data are intended to supplement the models of the 1986 COSPAR International Reference Atmosphere.

Proposed reference models for ozone

Abstract Ozone reference models are proposed here similar to the Keating and Young 1985 models which were prepared for the new COSPAR International Reference Atmosphere. This paper updates tables provided in the Keating and Young ozone model, giving improved monthly zonal mean total column ozone in 10° latitude increments, improved monthly zonal mean ozone volume mixing ratios (ppmv) from 20 to 0.003 mb in 10° latitude increments, and conversion tables providing ozone vertical structure in other units. Also, a new table is provided giving ozone vertical structure as a function of altitude (from 25 to 80 km), latitude, and month. The models are based on measurements from six contemporary satellite instruments.

Ozone reference models for CIRA

Abstract The ozone reference model which is to be incorporated in the COSPAR International Reference Atmosphere (CIRA) is described and compared with other measurements of the Earths ozone distribution. Ozone vertical structure models from approximately 25 to 90 km are provided combining data from five recent satellite experiments (Nimbus-7 LIMS, Nimbus-7 SBUV, AE-2 SAGE, Solar Mesosphere Explorer (SME) UVS, and SME IR). The results include the latest improvements in the SBUV algorithms using the most recent estimates of ozone cross sections. Also, the latest refinements in SME algorithms are incorporated. These algorithm improvements have improved agreement between the satellite data sets. Standard deviations are provided of monthly zonal means, and an estimate of the interannual variability is given. The models based on satallite data compare well with the Krueger and Minzner mid-latitude model incorporated into the U. S. Standard Atmosphere which is based on rocket and balloon measurements. Other comparisons are shown with Umkehr and more recent balloon data. Models are also provided of total columnar ozone reflecting recent improved estimates of ozone cross section. Information is provided on semiannual and annual variations. Other systematic variations including estimates of diurnal variations in the mesosphere will be included in the CIRA document.

The Response of Ozone to Solar Activity Variations: A Review

Observational evidence and theoretical predictions of the response of ozone to solar variations are reviewed. Short-term solar proton effects, possible effects of galactic cosmic rays modulated by the Sun, and the effects of 27-day solar rotation and 11-year solar cycle variations are discussed. Solar proton effects on HOx chemistry in the mesosphere and NOx chemistry in the stratosphere with resulting catalytic destruction of O3 help validate present day photochemical models. If there is an 11-year solar cycle variation in global ozone, the large dynamical effects at individual locations and the lack of good global coverage of ground based and in situ measurements can disguise it. Recently, with the global coverage of satellites, it has become possible to accurately determine global mean ozone. It has been found that variations in global mean ozone filtered for seasonal variations are highly correlated with variations of the 10.7 cm solar activity index and that global mean ozone responds rapidly to solar activity index variations. Photochemical models indicate that the observed 3% variations in global mean ozone over the solar cycle can be accounted for by solar UV variations which are not inconsistent with recent solar measurements.

IMPROVED REFERENCE MODELS FOR MIDDLE ATMOSPHERE OZONE

Abstract Improvements are provided here for the ozone reference model which is to be incorporated in the COSPAR International Reference Atmosphere (CIRA). The ozone reference model will provide considerable information on the global ozone distribution, including ozone vertical structure as a function of month and latitude from approximately 25 to 90 km, combining data from five recent satellite experiments (Nimbus 7 LIMS, Nimbus 7 SBUV, AE-2 SAGE, Solar Mesosphere Explorer (SME) UVS, and SME IR). The improved models described here use reprocessed AE-2 SAGE data (sunset) and extend the use of SAGE data from 1981 to the period 1981–1983. It is found that these SAGE data agree at all latitudes and months with the ozone reference model within 15 percent and result in modifications in the reference model of less than 4 percent. In the mesosphere, a model of nighttime conditions (= 10 p.m.) has been added using Nimbus 7 LIMS data between pressures of 0.5 mb to 0.05 mb (= 54 to 70 km). Minimum nightside ozone mixing ratios occur at about 0.2 mb (= 61 km). The ratio of nightside LIMS data to dayside (= 3 p.m.) SME data gives diurnal variations as large as a factor of 6 at the highest levels. At 0.1 mb (= 66 km), the night-day diurnal variation can exceed 3 and maximizes during solstice periods near 45 degrees in the summer hemisphere and near the Equator during equinoctial periods. This may largely result from the dayside ozone being more strongly photodissociated by the more directly incident summer Sun at mid latitudes and the equinoctial Sun at the Equator. Comparisons are shown between the ozone reference model and various non-satellite measurements at different levels in the middle atmosphere.

Neutral upper atmospheres of Venus and Mars

Numerous measurements of the neutral upper atmosphere above 100 km have been made from spacecraft over Venus and over Mars. The Venus exospheric temperatures are unexpectedly low (less than 300°K near noon and less than 130°K near midnight). These very low temperatures may be partially caused by collisional excitation of CO2 vibrational states by atomic oxygen and partially by eddy cooling. The Venus atmosphere is unexpectedly insensitive to solar EUV variability. On the other hand, the Martian dayside exospheric temperature varies from 150°K to 400°K over the 11-year solar cycle, where CO2 15-μm cooling may be less effective because of lower atomic oxygen mixing ratios. On Venus, temperature increases with altitude on the dayside (thermosphere), but decreases with altitude from 100 to 150 km on the nightside (cryosphere). However, dayside Martian temperatures near solar minimum for maximum planet-sun distance and low solar activity are essentially isothermal from 40 km to 200 km. During high solar activity, the thermospheric temperatures of Mars sharply increase. The Venus neutral upper atmosphere contains CO2, O, CO, C, N2, N, He, H, D and hot nonthermal H, O, C, and N, while the dayside Mars neutral upper atmosphere contains CO2, O, O2, CO, C, N2, He, H, and Ar. There is evidence on Venus for inhibited day-to-night transport as well as superrotation of the upper atmosphere. Both atmospheres have substantial wave activity. Various theoretical models used to interpret the planetary atmospheric data are discussed.

The Venus atmospheric response to solar cycle variations

Atmospheric drag measurements from the orbital decay of the Pioneer Venus Orbiter and Magellan spacecraft have recently been obtained of the Venus dayside and nightside atmosphere between 130 and 210 km during a period of low solar activity. These new measurements, combined with the earlier Pioneer Venus drag measurements (1978–80) obtained near the maximum of the 11-year solar cycle, have allowed the detection of the detailed response of temperature, atomic oxygen and carbon dioxide to solar variations. We have found a weak but detectable temperature response on the dayside which is in accord with the response predicted by Keating and Bougher when they assumed very strong CO2 radiative cooling resulting from atomic oxygen exciting CO2 into 15 micron emission. This same radiative process may cause strong cooling in the Earths upper atmosphere with the doubling of CO2 in the future. With decreasing solar activity, the O/CO2 ratio in the lower thermosphere is found to decrease, apparently due to decreased photodissociation of CO2 and lower temperatures. The percent decrease in atomic oxygen with decreasing solar activity on the dayside is found to be approximately the same as the percent decreases of atomic oxygen transported to the nightside. A very weak response of nightside temperatures to solar activity variations has also been detected.

Proposed ozone reference models for the middle atmosphere

Since the publication of the last COSPAR International Reference Atmosphere (CIRA 72), large amounts of ozone data acquired from satellites have become available in addition to increasing quantities of rocketsonde, balloonsonde, Dobson, M83, and Umkehr measurements. From the available archived satellite data, models are developed for the new CIRA using 5 satellite experiments (Nimbus 7 SBUV and LIMS, AEM-2 SAGE, and SME IR and UVS) of the monthly latitudinal and altitudinal variations in the ozone mixing ratio in the middle atmosphere. Standard deviations and interannual variations are also quantified. The satellite models are shown to agree well with a previous reference model based on rocket and balloon measurements.

Estimating 11-year solar UV variations using 27-day response as a guide to isolate trends in total column ozone

Abstract The total column ozone response to 11-year solar ultraviolet (UV) variations is estimated here from the observed response to 27-day solar variations adjusted for the theoretical difference between the 27-day response and 11-year response. The estimate is tested by comparing two deta sets where long-term drifts have been removed, the Nimbus 7 TOMS Version 6 total column ozone and the 280 nm core-to-wing ratio (a proxy for solar UV variations). The 365-day running means of data area-weighted between 40°N to 40°S latitude give a 1.9% ozone variation related to the 11-year solar cycle compared with the estimate of 1.8%. Estimates of linear trends were reduced by a factor of 2 by including solar effects. The standard deviation from the empirical model was reduced from 1.0 to 0.6 Dobson Units, by including the quasibiennial oscillation (QBO), but the QBO did not significantly alter trend estimates. Both the ozone responses to 27-day and 11-year solar variations were considerably stronger than predicted by a 2-D theoretical model.