G. R. Carignan

The abundances of constituents of Titan's atmosphere from the GCMS instrument on the Huygens probe.

Saturns largest moon, Titan, remains an enigma, explored only by remote sensing from Earth, and by the Voyager and Cassini spacecraft. The most puzzling aspects include the origin of the molecular nitrogen and methane in its atmosphere, and the mechanism(s) by which methane is maintained in the face of rapid destruction by photolysis. The Huygens probe, launched from the Cassini spacecraft, has made the first direct observations of the satellites surface and lower atmosphere. Here we report direct atmospheric measurements from the Gas Chromatograph Mass Spectrometer (GCMS), including altitude profiles of the constituents, isotopic ratios and trace species (including organic compounds). The primary constituents were confirmed to be nitrogen and methane. Noble gases other than argon were not detected. The argon includes primordial 36Ar, and the radiogenic isotope 40Ar, providing an important constraint on the outgassing history of Titan. Trace organic species, including cyanogen and ethane, were found in surface measurements.

The Galileo probe mass spectrometer: composition of Jupiter's atmosphere.

The composition of the jovian atmosphere from 0.5 to 21 bars along the descent trajectory was determined by a quadrupole mass spectrometer on the Galileo probe. The mixing ratio of He (helium) to H2 (hydrogen), 0.156, is close to the solar ratio. The abundances of methane, water, argon, neon, and hydrogen sulfide were measured; krypton and xenon were detected. As measured in the jovian atmosphere, the amount of carbon is 2.9 times the solar abundance relative to H2, the amount of sulfur is greater than the solar abundance, and the amount of oxygen is much less than the solar abundance. The neon abundance compared with that of hydrogen is about an order of magnitude less than the solar abundance. Isotopic ratios of carbon and the noble gases are consistent with solar values. The measured ratio of deuterium to hydrogen (D/H) of (5 ± 2) × 10−5 indicates that this ratio is greater in solar-system hydrogen than in local interstellar hydrogen, and the 3He/4He ratio of (1.1 ± 0.2) × 10−4 provides a new value for protosolar (solar nebula) helium isotopes. Together, the D/H and 3He/4He ratios are consistent with conversion in the sun of protosolar deuterium to present-day 3He.

Geomagnetic storm effects in the low‐ to middle‐latitude upper thermosphere

In this paper, we use data from the Dynamics Explorer 2 (DE 2) satellite and a theoretical simulation made by using the National Center for Atmospheric Research thermosphere/ionosphere general circulation model (NCAR-TIGCM) to study storm-induced changes in the structure of the upper thermosphere in the low- to middle-latitude (20°-40°N) region of the winter hemisphere. Our principal results are as follows: (1) The winds associated with the diurnal tide weaken during geomagnetic storms, causing primarily zonally oriented changes in the evening sector, few changes in the middle of the afternoon, a combination of zonal and meridional changes in the late morning region, and mainly meridional changes early in the morning. (2) Decreases in the magnitudes of the horizontal winds associated with the diurnal tide lead to a net downward tendency in the vertical winds blowing through a constant pressure surface. (3) Because of these changes in the vertical wind, there is an increase in compressional heating (or a decrease in cooling through expansion), and thus temperatures in the low- to middle-latitudes of the winter hemisphere increase. (4) Densities of all neutral species increase on a constant height surface, but the pattern of changes in the O/N2 ratio is not well ordered on these surfaces. (5) The pattern of changes in the O/N2 ratio is better ordered on constant pressure surfaces. The increases in this ratio on constant pressure surfaces in the low- to middle-latitude, winter hemisphere are caused by a more downward tendency in the vertical winds that blow through the constant pressure surfaces. Nitrogen-poor air is then advected downward through the pressure surface, increasing the O/N2 ratio. (6) The daytime geographical distribution of the modeled increases in the O/N2 ratio on a constant pressure surface in the low- to middle-latitudes of the winter hemisphere correspond very closely with those of increases in the modeled electron densities at the F2 peak.

Ionospheric storm effects at subauroral latitudes: A case study

An attempt is made to classify ionospheric storm effects at subauroral latitudes according to their presumed origin. The storm of December 7/8, 1982, serves as an example. It is investigated using ionosonde, electron content, and DE 2 satellite data. The following effects are distinguished: (1) positive storm effects caused by traveling atmospheric disturbances, (2) positive storm effects caused by changes in the large-scale thermospheric wind circulation, (3) positive storm effects caused by the expansion of the polar ionization enhancement, (4) negative storm effects caused by perturbations of the neutral gas composition, and (5) negative storm effects caused by the equatorward displacement of the trough region.

Large enhancements in the O/N2 ratio in the evening sector of the winter hemisphere during geomagnetic storms

In this paper, we have looked for enhancements of the O/N2 ratio in data measured by the Dynamics Explorer 2 (DE 2) satellite in the middle latitudes of the winter hemisphere, based on a prediction that was made by the National Center for Atmospheric Research thermosphere/tonosphere general circulation model (NCAR-TIGCM) that such increases occur. The NCAR-TIGCM predicts that these enhancements should be seen throughout the low latitude region and in many middle latitude locations, but that the enhancements in O/N2 are particularly strong in the middle-latitude, evening-to-midnight sector of the winter hemisphere. When this prediction was used to look for these effects in DE 2 NACS (neutral atmosphere composition spectrometer) data, large enhancements in the O/N 2 ratio (-50 to 90%) were seen. These enhancements were observed during the main phase of a storm that occurred on November 24, 1982, and were seen in the same region of the winter hemisphere predicted by the NCAR-TIGCM. They are partially the result of the depletion of N 2 and, as electron loss is dependent on dissociative recombination at F 2 altitudes, they have implications for electron densities in this area. Parcel trajectories, which have been followed through the NCAR-TIGCM history file for this event, show that large O/N2 enhancements occur in this limited region in the winter hemisphere for two reasons. First, these parcels of air are decelerated by the antisunward edge of the ion convection pattern; individual parcels converge and subsidence occurs. Thus molecular-nitrogen-poor air is brought from higher to lower heights. Because neutral parcels that are found a little poleward of the equatorial edge of the eveningside convection pattern are swept inward toward the center of the auroral oval, the enhancements occur only in a very limited range of latitudes. Second, nitrogen-poor air is transported from regions close to the magnetic pole in the winter hemisphere. During geomagnetic storms, enhanced meridional winds are driven by the increased pressure-gradient force that is associated with intensified Joule heating in the auroral oval. These pressure-driven winds decrease rapidly on the dayside beyond the auroral oval where the parcels originate, limiting the region into which the parcels can be transported. Thus these two processes drive values of O/N2 in a limited region of the winter hemisphere, and reinforce only in the evening sector, causing large changes in this region.

Venus upper atmosphere neutral gas composition - First observations of the diurnal variations

Measurements of the composition, temperature, and diurnal variations of the major neutral constituents in the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus orbiter. Concentrations of carbon dioxide, carbon monoxide, molecular nitrogen, atomic oxygen, and helium are presented, in addition to an empirical model of the data. The concentrations of the heavy gases, carbon dioxide, carbon monoxide, and molecular nitrogen, rapidly decrease from the evening terminator toward the nightside; the concentration of atomic oxygen remains nearly constant and the helium concentration increases, an indication of a nightside bulge. The kinetic temperature inferred from scale heights drops rapidly from 230 K at the terminator to 130 K at a solar zenith angle of 120�, and to 112 K at the antisolar point.

Venus Upper Atmosphere Neutral Composition: Preliminary Results from the Pioneer Venus Orbiter

Measurements in situ of the neutral composition and temperature of the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus orbiter. The presence of many gases, incluiding the major constituents CO2, CO, N2, O, and He has been confirmed. Carbon dioxide is the most abundant constituent at altitudes below about 155 kilometers in the terminator region. Above this altitude atomic oxygen is the major constituent, with O/CO2 ratios in the upper atmosphere being greater than was commonly expected. Isotope ratios of O and C are close to terrestrial values. The temperature inferred from scale heights above 180 kilometers is about 400 K on the dayside near the evening terminator at a solar zenith angle of about 69�. It decreases to about 230 K when the solar zenith angle is about 90�.

The Gas Chromatograph Mass Spectrometer for the Huygens Probe

The Gas Chromatograph Mass Spectrometer (GCMS) on the Huygens Probe will measure the chemical composition of Titans atmosphere from 170 km altitude (∼1 hPa) to the surface (∼1500 hPa) and determine the isotope ratios of the major gaseous constituents. The GCMS will also analyze gas samples from the Aerosol Collector Pyrolyser (ACP) and may be able to investigate the composition (including isotope ratios) of several candidate surface materials.The GCMS is a quadrupole mass filter with a secondary electron multiplier detection system and a gas sampling system providing continuous direct atmospheric composition measurements and batch sampling through three gas chromatographic (GC) columns. The mass spectrometer employs five ion sources sequentially feeding the mass analyzer. Three ion sources serve as detectors for the GC columns and two are dedicated to direct atmosphere sampling and ACP gas sampling respectively. The instrument is also equipped with a chemical scrubber cell for noble gas analysis and a sample enrichment cell for selective measurement of high boiling point carbon containing constituents. The mass range is 2 to 141 Dalton and the nominal detection threshold is at a mixing ratio of 10− 8. The data rate available from the Probe system is 885 bit/s. The weight of the instrument is 17.3 kg and the energy required for warm up and 150 minutes of operation is 110 Watt-hours.

The composition, structure, temperature and dynamics of the upper thermosphere in the polar regions during October to December 1981

Abstract During the period October to December 1981, the Dynamics Explorer-2 (DE-2) spacecraft successively observed the South polar and the North polar regions, and recorded the temperature, composition and dynamical structure of the upper thermosphere. In October 1981, perigee was about 310 km altitude, in the vicinity of the South Pole, with the satellite orbit in the 09.00–21.00 L.T. plane. During late November and December, the perigee had precessed to the region of the North Pole, with the spacecraft sampling the upper thermosphere in the 06.00 18.00 L.T. plane. DE-2 observed the meridional wind with a Fabry-Perot interferometer (FPI), the zonal wind with the wind and temperature spectrometer (WATS), the neutral temperature with the FPI, and the neutral atmosphere composition and density with the neutral atmosphere composition spectrometer (NACS). A comparison between the South (summer) Pole and the North (winter) Pole data shows considerable seasonal differences in all neutral atmosphere parameters. The region of the summer pole, under similar geomagnetic and solar activity conditions, and at a level of about 300 km, is about 300 K warmer than that of the winter pole, and the density of atomic oxygen is strongly depleted (and nitrogen enhanced) around the summer pole (compared with the winter pole). Only part of the differences in temperature and composition structure can be related to the seasonal variation of solar insolation, however, and both polar regions display structural variations (with latitude and Universal Time) which are unmistakeable characteristics of strong magnetospheric forcing. The magnitude of the neutral atmosphere perturbations in winds, temperature, density and composition within both summer and winter polar regions all increase with increasing levels of geomagnetic activity. The UCL 3-dimensional time dependent global model has been used to simulate the diurnal, seasonal and geomagnetic response of the neutral thermosphere, attempting to follow the major features of the solar and geomagnetic inputs to the thermosphere which were present during the late 1981 period. In the UCL model, geomagnetic forcing is characterized by semi-empirical models of the polar electric field which show a dependence on the Y component of the Interplanetary Magnetic Field, due to Heppner and Maynard (1983), It is possible to obtain an overall agreement, in both summer and winter hemispheres, with the thermospheric wind structure at high latitudes, and to explain the geomagnetic control of the combined thermal and compositional structure both qualitatively and quantitatively. To obtain such agreement, however, it is essential to enhance the polar ionosphere as a consequence of magnetospheric particle precipitation, reflecting both widespread auroral (kilovolt) electrons, and “soft” cusp and polar cap sources. Geomagnetic forcing of the high latitude thermosphere cannot be explained purely by a polar convective electric field, and the thermal as well as ionising properties of these polar and auroral electron sources are crucial components of the total geomagnetic input.

Galileo Probe Mass Spectrometer experiment

The Galileo Probe Mass Spectrometer (GPMS) is a Probe instrument designed to measure the chemical and isotopic composition including vertical variations of the constituents in the atmosphere of Jupiter. The measurement will be performed by in situ sampling of the ambient atmosphere in the pressure range from approximately 150 mbar to 20 bar. In addition batch sampling will be performed for noble gas composition measurement and isotopic ratio determination and for sensitivity enhancement of non-reactive trace gases.The instrument consists of a gas sampling system which is connected to a quadrupole mass analyzer for molecular weight analysis. In addition two sample enrichment cells and one noble gas analysis cell are part of the sampling system. The mass range of the quadrupole analyzer is from 2 amu to 150 amu. The maximum dynamic range is 108. The detector threshold ranges from 10 ppmv for H2O to 1 ppbv for Kr and Xe. It is dependent on instrument background and ambient gas composition because of spectral interference. The threshold values are lowered through sample enrichment by a factor of 100 to 500 for stable hydrocarbons and by a factor of 10 for noble gases. The gas sampling system and the mass analyzer are sealed and evacuated until the measurement sequence is initiated after the Probe enters into the atmosphere of Jupiter. The instrument weighs 13.2 kg and the average power consumption is 13 W.The instrument follows a sampling sequence of 8192 steps and a sampling rate of two steps per second. The measurement period lasts appropriately 60 min through the nominal pressure and altitude range.