W. T. Kasprzak

The abundances of constituents of Titan's atmosphere from the GCMS instrument on the Huygens probe.

Saturns largest moon, Titan, remains an enigma, explored only by remote sensing from Earth, and by the Voyager and Cassini spacecraft. The most puzzling aspects include the origin of the molecular nitrogen and methane in its atmosphere, and the mechanism(s) by which methane is maintained in the face of rapid destruction by photolysis. The Huygens probe, launched from the Cassini spacecraft, has made the first direct observations of the satellites surface and lower atmosphere. Here we report direct atmospheric measurements from the Gas Chromatograph Mass Spectrometer (GCMS), including altitude profiles of the constituents, isotopic ratios and trace species (including organic compounds). The primary constituents were confirmed to be nitrogen and methane. Noble gases other than argon were not detected. The argon includes primordial 36Ar, and the radiogenic isotope 40Ar, providing an important constraint on the outgassing history of Titan. Trace organic species, including cyanogen and ethane, were found in surface measurements.

Cassini ion and neutral mass spectrometer: Enceladus plume composition and structure

The Cassini spacecraft passed within 168.2 kilometers of the surface above the southern hemisphere at 19:55:22 universal time coordinated on 14 July 2005 during its closest approach to Enceladus. Before and after this time, a substantial atmospheric plume and coma were observed, detectable in the Ion and Neutral Mass Spectrometer (INMS) data set out to a distance of over 4000 kilometers from Enceladus. INMS data indicate that the atmospheric plume and coma are dominated by water, with significant amounts of carbon dioxide, an unidentified species with a mass-to-charge ratio of 28 daltons (either carbon monoxide or molecular nitrogen), and methane. Trace quantities (<1%) of acetylene and propane also appear to be present. Ammonia is present at a level that does not exceed 0.5%. The radial and angular distributions of the gas density near the closest approach, as well as other independent evidence, suggest a significant contribution to the plume from a source centered near the south polar cap, as distinct from a separately measured more uniform and possibly global source observed on the outbound leg of the flyby.

The composition of the Jovian atmosphere as determined by the Galileo probe mass spectrometer

The Galileo probe mass spectrometer determined the composition of the Jovian atmosphere for species with masses between 2 and 150 amu from 0.5 to 21.1 bars. This paper presents the results of analysis of some of the constituents detected: H2, He, Ne, Ar, Kr, Xe, CH4, NH3, H2O, H2S, C2 and C3 nonmethane hydrocarbons, and possibly PH3 and Cl. 4He/H2 in the Jovian atmosphere was measured to be 0.157 +/- 0.030. 13C/C12 was found to be 0.0108 +/- 0.0005, and D/H and 3He/4He were measured. Ne was depleted, < or = 0.13 times solar, Ar < or = 1.7 solar, Kr < or = 5 solar, and Xe < or = 5 solar. CH4 has a constant mixing ratio of (2.1 +/- 0.4) x 10(-3) (12C, 2.9 solar), where the mixing ratio is relative to H2. Upper limits to the H2O mixing ratio rose from 8 x 10(-7) at pressures <3.8 bars to (5.6 +/- 2.5) x 10(-5) (16O, 0.033 +/- 0.015 solar) at 11.7 bars and, provisionally, about an order of magnitude larger at 18.7 bars. The mixing ratio of H2S was <10(-6) at pressures less than 3.8 bars but rose from about 0.7 x 10(-5) at 8.7 bars to about 7.7 x 10(-5) (32S, 2.5 solar) above 15 bars. Only very large upper limits to the NH3 mixing ratio have been set at present. If PH3 and Cl were present, their mixing ratios also increased with pressure. Species were detected at mass peaks appropriate for C2 and C3 hydrocarbons. It is not yet clear which of these were atmospheric constituents and which were instrumentally generated. These measurements imply (1) fractionation of 4He, (2) a local, altitude-dependent depletion of condensables, probably because the probe entered the descending arm of a circulation cell, (3) that icy planetesimals made significant contributions to the volatile inventory, and (4) a moderate decrease in D/H but no detectable change in (D + 3He)/H in this part of the galaxy during the past 4.6 Gyr.

The Galileo probe mass spectrometer: composition of Jupiter's atmosphere.

The composition of the jovian atmosphere from 0.5 to 21 bars along the descent trajectory was determined by a quadrupole mass spectrometer on the Galileo probe. The mixing ratio of He (helium) to H2 (hydrogen), 0.156, is close to the solar ratio. The abundances of methane, water, argon, neon, and hydrogen sulfide were measured; krypton and xenon were detected. As measured in the jovian atmosphere, the amount of carbon is 2.9 times the solar abundance relative to H2, the amount of sulfur is greater than the solar abundance, and the amount of oxygen is much less than the solar abundance. The neon abundance compared with that of hydrogen is about an order of magnitude less than the solar abundance. Isotopic ratios of carbon and the noble gases are consistent with solar values. The measured ratio of deuterium to hydrogen (D/H) of (5 ± 2) × 10−5 indicates that this ratio is greater in solar-system hydrogen than in local interstellar hydrogen, and the 3He/4He ratio of (1.1 ± 0.2) × 10−4 provides a new value for protosolar (solar nebula) helium isotopes. Together, the D/H and 3He/4He ratios are consistent with conversion in the sun of protosolar deuterium to present-day 3He.

Venus upper atmosphere neutral gas composition - First observations of the diurnal variations

Measurements of the composition, temperature, and diurnal variations of the major neutral constituents in the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus orbiter. Concentrations of carbon dioxide, carbon monoxide, molecular nitrogen, atomic oxygen, and helium are presented, in addition to an empirical model of the data. The concentrations of the heavy gases, carbon dioxide, carbon monoxide, and molecular nitrogen, rapidly decrease from the evening terminator toward the nightside; the concentration of atomic oxygen remains nearly constant and the helium concentration increases, an indication of a nightside bulge. The kinetic temperature inferred from scale heights drops rapidly from 230 K at the terminator to 130 K at a solar zenith angle of 120�, and to 112 K at the antisolar point.

Diurnal variations of Titan's ionosphere

of � 700 cm �3 below � 1300 km. Such a plateau is a combined result of significant depletion of light ions and modest depletion of heavy ones on Titan’s nightside. We propose that the distinctions between the diurnal variations of light and heavy ions are associated with their different chemical loss pathways, with the former primarily through ‘‘fast’’ ion-neutral chemistry and the latter through ‘‘slow’’ electron dissociative recombination. The strong correlation between the observed night-to-day ion density ratios and the associated ion lifetimes suggests a scenario in which the ions created on Titan’s dayside may survive well to the nightside. The observed asymmetry between the dawn and dusk ion density profiles also supports such an interpretation. We construct a time-dependent ion chemistry model to investigate the effect of ion survival associated with solid body rotation alone as well as superrotating horizontal winds. For long-lived ions, the predicted diurnal variations have similar general characteristics to those observed. However, for short-lived ions, the model densities on the nightside are significantly lower than the observed values. This implies that electron precipitation from Saturn’s magnetosphere may be an additional and important contributor to the densities of the short-lived ions observed on Titan’s nightside.

Venus Upper Atmosphere Neutral Composition: Preliminary Results from the Pioneer Venus Orbiter

Measurements in situ of the neutral composition and temperature of the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus orbiter. The presence of many gases, incluiding the major constituents CO2, CO, N2, O, and He has been confirmed. Carbon dioxide is the most abundant constituent at altitudes below about 155 kilometers in the terminator region. Above this altitude atomic oxygen is the major constituent, with O/CO2 ratios in the upper atmosphere being greater than was commonly expected. Isotope ratios of O and C are close to terrestrial values. The temperature inferred from scale heights above 180 kilometers is about 400 K on the dayside near the evening terminator at a solar zenith angle of about 69�. It decreases to about 230 K when the solar zenith angle is about 90�.

Pioneer Venus Orbiter Neutral Gas Mass Spectrometer Experiment

The Pioneer Venus Orbiter Neutral Mass Spectrometer (ONMS) is designed to measure the vertical and horizontal density variations of the major neutral constituents in the upper atmosphere of Venus. The mass spectrometer sensor includes a retarding potential ion source, hyperbolic quadrupole rod analyzer, and electron multiplier detector. The supporting electronic system consists of hybrid integrated circuits to reduce weight and power. The ONMS instrument was launched aboard the Pioneer Venus Orbiter on May 20, 1978, and turned on in orbit around Venus on December 4, 1978. It has operated flawlessly for over a Venus year (243 earth days) and has returned data of the composition of the major constituents in the Venus atmosphere between the altitudes of 150 and 350 km.

Superthermal >36-eV ions observed in the near-tail region of Venus by the Pioneer Venus Orbiter neutral mass spectrometer

The Pioneer Venus orbiter neutral mass spectrometer (ONMS) has made measurements of >36-eV ions in the altitude range 1300–3700 km for solar zenith angles greater than 120°. The observations cover a time period from late 1982 to 1989. The superthermal ions form part of the near-tail region of Venus termed the ionotail. The ONMS superthermal ions represent only a small fraction (about 0.3%) of the plasma density in the ionotail region. The composition is mainly O+, but He+, N+, (CO+ + N2+), NO+, and O2+ have been identified. CO2+ is very rarely observed in this region, and H+ is not measured. The average O+ flux is about 105 cm−2 s−1, but higher fluxes from 106 to 108 cm−2 s−1 have been observed about 10% of the time. The directions of the apparent O+ ion flow in the ecliptic plane show predominantly tailward components with a smaller number of nontailward components. Since the energy of the superthermal ions is sufficient for planetary escape, the >36-eV O+ escape flux in the ionotail is estimated to be about 105 cm−2 s−1. Other species observed also have enough energy to escape. The O+ flux data show a factor of 2.5 increase from solar minimum to solar maximum implying a photoionization source for these ions. Neither the origin of the >36-eV ions nor the acceleration mechanism is precisely known. The O+ flux observations do not appear to be correlated with the direction of the “cross-tail” magnetic field as might be expected if the ions were due to the asymmetric pickup of newly ionized atmospheric neutrals above the ionopause. The composition of the superthermal ions in the ionotail suggests that their source is most likely the high-altitude nightside ionosphere where O+ and not O2+ is the dominant ion. Transport of superthermal O+ across the terminator to the nightside has been observed, and measurements in the ionotail region at solar minimum near 2000 km show that O+ is mainly superthermal. Much further down the tail, very energetic (0–8 keV) O+ has been observed as it escapes Venus. Conditions in the lower nightside ionosphere have been shown to be consistent with an upward ion flow. Parallel electric fields or J × B forces associated with the convection of the interplanetary magnetic field through or above the ionosphere have been suggested as acceleration mechanisms in the ionotail. Similar mechanisms have been proposed for the tail region of Mars where energetic molecular ions such as O+ have also been observed and may also be appropriate for Titan if the 28-amu species observed is due to H2CN+.

Observations of energetic ions near the Venus ionopause

Abstract Ions (primarily O + ) with spacecraft rest frame energies >40 eV have been observed by the Pioneer Venus Neutral Mass Spectrometer. The signature occurs in about 13% of the 700 orbits examined, primarily near the ionopause and at all solar zenith angles. The energetic ions coincide in location with superthermal ions observed by the Ion Mass Spectrometer and more rarely occur in some of the plasma clouds observed by the Electron Temperature Probe. These observations in conjunction with measurements by the Plasma Wave Instrument near the ionopause suggest that the ions are accelerated out of ionospheric plasma by the shocked solar wind through plasma waveparticle interactions.