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Dive into the research topics where Gerardo S. Bodner is active.

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Featured researches published by Gerardo S. Bodner.


Journal of the American Chemical Society | 1983

Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction

William A. Kiel; Gong Yu Lin; Gerardo S. Bodner; J. A. Gladysz

The regioselectivity and stereochemistry of these reactions are examined. Structures are evaluated with NMR. 4 figures, 4 tables.


Journal of the American Chemical Society | 1983

Regiospecific and stereospecific reactions of Ph/sub 3/C/sup +/PF/sub 6//sup -/ with rhenium alkyls (eta-C/sub 5/H/sub 5/)Re(NO)(PPh/sub 3/)(R). cap alpha. - vs. beta. -hydride abstraction

William A. Kiel; Gong-Yu Lin; Gerardo S. Bodner; J. A. Gladysz

The regioselectivity and stereochemistry of these reactions are examined. Structures are evaluated with NMR. 4 figures, 4 tables.


Journal of the American Chemical Society | 1987

Synthesis, structure, and alkylation of chiral vinylrhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(CX:CHR) (X = H, OCH3). A mechanistic study of 1,3-asymmetric induction from rhenium to carbon

Gerardo S. Bodner; Danny E. Smith; William G. Hatton; Poh Choo Heah; Savas. Georgiou; Arnold L. Rheingold; Steven J. Geib; John P. Hutchinson; J. A. Gladysz


Journal of the American Chemical Society | 1987

New mechanistic probes of hydride abstraction from rhenium-alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) by Ph3C+ PF6-. Evidence for initial electron transfer

Gerardo S. Bodner; J. A. Gladysz; Merete Folmer Nielsen; Vernon D. Parker


Organometallics | 1990

Synthesis, structure, and reactivity of chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)PPh3)(H2C:CHR)]+ X-

Gerardo S. Bodner; Tang Sheng Peng; Atta M. Arif; J. A. Gladysz


Organometallics | 1991

Mechanism of isomerization of rhenium alkylidene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(:CRCHR'R'')]+X- to alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(RHC:CR'R'')]+X-: an organometallic Wagner-Meerwein-type rearrangement

Christophe Roger; Gerardo S. Bodner; William G. Hatton; J. A. Gladysz


Journal of the American Chemical Society | 1987

New method for the activation of metal-bound methyl groups. Oxidative disproportionation to coordinated ethylene and methane

Mats Tilset; Gerardo S. Bodner; Dwayne R. Senn; J. A. Gladysz; Vernon D. Parker


Organometallics | 1987

Crystallographic and theoretical analyses of the structures of rhenium formyl and acyl complexes of the formula (.eta.5-C5H5)Re(NO)(PR3)(COR')

Gerardo S. Bodner; Alan T. Patton; Danny E. Smith; Savas. Georgiou; Wilson Tam; Wai Kwok Wong; Charles E. Strouse; J. A. Gladysz


Organometallics | 1990

Synthesis, structure, and reactivity of the chiral rhenium phenyl complex (.eta.5-C5H5)Re(NO)(PPh3)(C6H5)

Sename K. Agbossou; Gerardo S. Bodner; Alan T. Patton; J. A. Gladysz


Journal of the American Chemical Society | 1988

Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+

Gerardo S. Bodner; Jesus M. Fernandez; Atta M. Arif; J. A. Gladysz

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Vernon D. Parker

Norwegian Institute of Technology

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