Giorgio Pariani

Photochromic Electret: A New Tool for Light Energy Harvesting.

In this paper, a photochromic electret for light energy harvesting is proposed and discussed. Such electret directly converts the photon energy into electric energy thanks to a polarization modulation caused by the photochromic reaction, which leads to a change in dipole moment. Theoretical concepts on which the photochromic electret is based are considered with an estimation of the effectiveness as a function of material properties. Finally, an electret based on a photochromic diarylethene is shown with the photoelectric characterization as a proof of concept device.

Kinetics of photochromic conversion at the solid state: quantum yield of dithienylethene-based films.

Quantum yield is one of the most important properties of photochromic systems. Unfortunately, a lack of data at the solid state exists, because measurements are intrinsically not straightforward. A kinetic model describing the conversion of the photoactive species is reported and both analytic and numeric solutions are provided according to relevant cases. The model is then applied to measure the quantum yield of dithienylethene-based polymers; the ring-opening quantum yield is measured for different laser beam profiles (i.e., Gaussian and uniform) and at different wavelengths, showing an increased value with increasing photon energy.

Diarylethene-based photochromic polyurethanes for multistate optical memories

Photochromic polyurethanes (PPUs) are synthesised by reaction between a diarylethene end-capped with hydroxyl groups and an aliphatic diisocyanate. In situpolymerisation provides amorphous films with remarkable optical properties. The possibility to vary the amount and the chemical structure of the photochromic monomer without affecting the reactivity of the polymerization allows one to tune in a wide range the optical properties of these films. In addition, different diarylethenes can be mixed together to give copolymers which may find application as photochromic layers for multistate optical memories. A setup for a non-destructive readout based on Raman signal is proposed.

Modeling absorbance-modulation optical lithography in photochromic films

A kinetic model describing the conversion of a photochromic layer under complex illumination conditions is applied to absorbance-modulation optical lithography to determine the influence of the material characteristics on the confinement to subdiffraction dimensions of the transmitted dose. We show that the most important parameters are the intensity ratio between the confining and writing beams, the overall absorption at the writing wavelength, the relative absorption coefficients, and the photoreaction quantum yields at the two wavelengths. As the confining beam ultimately determines the transferred dose pattern, we conclude that the modulation of the writing beam is not strictly necessary to produce subwavelength apertures.

The common path of SOXS (Son of X-Shooter)

Son of X-Shooter (SOXS) will be a high-efficiency spectrograph with a mean Resolution-Slit product of 4500 (goal 5000) over the entire band capable of simultaneously observing the complete spectral range 350-2000 nm. It consists of three scientific arms (the UV-VIS Spectrograph, the NIR Spectrograph and the Acquisition Camera) connected by the Common Path system to the NTT and the Calibration Unit. The Common Path is the backbone of the instrument and the interface to the NTT Nasmyth focus flange. The light coming from the focus of the telescope is split by the common path optics into the two different optical paths in order to feed the two spectrographs and the acquisition camera. The instrument project went through the Preliminary Design Review in 2017 and is currently in Final Design Phase (with FDR in July 2018). This paper outlines the status of the Common Path system and is accompanied by a series of contributions describing the SOXS design and properties after the instrument Preliminary Design Review.

Materials for VPHGs: practical considerations in the case of astronomical instrumentation

Volume Phase Holographic Gratings are interesting dispersing elements for astronomical instrumentation. An important point, in the realization of the grating, is the choice of the holographic material. Dichromated Gelatines (DCGs) are the best candidate, but they show some drawback especially regarding their water sensitivity and the complex developing process required to enhance their performances. New holographic materials are becoming interesting, such as photopolymers and photochromic materials. An exhaustive review of these classes of materials will be reported and their performances compared to those of DCGs, focusing mainly to the astronomical instrumentation field.

The assembly integration and test activities for the new SOXS instrument at NTT

Son Of X-Shooter (SOXS) is the new instrument for the ESO 3.5 m New Technology Telescope (NTT) in La Silla site (Chile) devised for the spectroscopic follow-up of transient sources. SOXS is composed by two medium resolution spectrographs able to cover the 350-2000 nm interval. An Acquisition Camera will provide a light imaging capability in the visible band. We present the procedure foreseen for the Assembly, Integration and Test activities (AIT) of SOXS that will be carried out at sub-systems level at various consortium partner premises and at system level both in Europe and Chile.

The mechanical design of SOXS for the NTT

SOXS (Son of X-shooter) is a wide band, medium resolution spectrograph for the ESO NTT with a first light expected in early 2021. The instrument will be composed by five semi-independent subsystems: a pre-slit Common Path (CP), an Acquisition Camera (AC), a Calibration Unit (CU), the NIR spectrograph, and the UV-VIS spectrograph. In this paper, we present the mechanical design of the subsystems, the kinematic mounts developed to simplify the final integration procedure and the maintenance. The concept of the CP and NIR optomechanical mounts developed for a simple pre- alignment procedure and for the thermal compensation of reflective and refractive elements will be shown.

The acquisition camera system for SOXS at NTT

SOXS (Son of X-Shooter) will be the new medium resolution (R~4500 for a 1 arcsec slit), high-efficiency, wide band spectrograph for the ESO-NTT telescope on La Silla. It will be able to cover simultaneously optical and NIR bands (350-2000nm) using two different arms and a pre-slit Common Path feeding system. SOXS will provide an unique facility to follow up any kind of transient event with the best possible response time in addition to high efficiency and availability. Furthermore, a Calibration Unit and an Acquisition Camera System with all the necessary relay optics will be connected to the Common Path sub-system. The Acquisition Camera, working in optical regime, will be primarily focused on target acquisition and secondary guiding, but will also provide an imaging mode for scientific photometry. In this work we give an overview of the Acquisition Camera System for SOXS with all the different functionalities. The optical and mechanical design of the system are also presented together with the preliminary performances in terms of optical quality, throughput, magnitude limits and photometric properties.

Optical design of the SOXS spectrograph for ESO NTT

An overview of the optical design for the SOXS spectrograph is presented. SOXS (Son Of X-Shooter) is the new wideband, medium resolution (R>4500) spectrograph for the ESO 3.58m NTT telescope expected to start observations in 2021 at La Silla. The spectroscopic capabilities of SOXS are assured by two different arms. The UV-VIS (350-850 nm) arm is based on a novel concept that adopts the use of 4 ion-etched high efficiency transmission gratings. The NIR (800- 2000 nm) arm adopts the ‘4C’ design (Collimator Correction of Camera Chromatism) successfully applied in X-Shooter. Other optical sub-systems are the imaging Acquisition Camera, the Calibration Unit and a pre-slit Common Path. We describe the optical design of the five sub-systems and report their performance in terms of spectral format, throughput and optical quality. This work is part of a series of contributions1-9 describing the SOXS design and properties as it is about to face the Final Design Review.