Giovanni Piero Pepe

Online monitoring of alloyed bimetallic nanoparticle formation by optical spectroscopy

An extension of the Mie [Ann. Phys. 25, 377 (1908)] theory for the calculation of optical absorption spectra in bimetallic nanoparticles has been developed. The nanoparticle dielectric function is assumed to be a weighted linear combination of dielectric functions for single particles. Accordingly, analytical expressions for the resonance light absorption frequency, the spectrum maximum value, and the full width at half maximum have been derived, taking into account the interband transitions in the dielectric functions. Experiments have been performed on polymer-embedded Ag∕Au nanoparticles prepared by reducing the presence of poly(vinyl pyrrolidone) at room temperature. Experimental absorption spectra have been compared to numerical curves derived by the model in the case of Ag∕Au systems at different relative compositions, and they are in good agreement. The time dependence of both Ag∕Au nanoparticle size and chemical composition during the growth process has also been investigated.

Ultrasensitive proximity Josephson sensor with kinetic inductance readout

We propose a mesoscopic kinetic-inductance radiation detector based on a long superconductor-normal metal-superconductor Josephson junction. The operation of this proximity Josephson sensor relies on large kinetic inductance variations under irradiation due to the exponential temperature dependence of the critical current. Coupled with a dc superconducting quantum interference device readout, the PJS is able to provide a signal to noise (S/N) ratio up to ∼103 in the terahertz regime if operated as calorimeter, while electrical noise equivalent power as low as ∼7×10−20W∕Hz at 200mK can be achieved in the bolometer operation. The high performance together with the ease of fabrication make this structure attractive as an ultrasensitive cryogenic detector of terahertz electromagnetic radiation.

Thermal hopping and retrapping of a Brownian particle in the tilted periodic potential of a NbN/MgO/NbN Josephson junction

We report on the occurrence of multiple hopping and retrapping of a Brownian particle in a tilted washboard potential. The escape dynamic has been studied experimentally by measuring the switching current distributions as a function of temperature in a moderately damped NbN/MgO/NbN Josephson junction. At low temperatures the second moment of the distribution increases in agreement with calculations based on Kramers thermal activation regime. After a turn-over temperature T*, the shape of the distributions starts changing and width decreases with temperature. We analyze the data through fit of the switching probability and Monte Carlo simulations and we find a good agreement with a model based on a multiple retrapping process.

Quantum crossover in moderately damped epitaxial NbN/MgO/NbN junctions with low critical current density

High quality epitaxial NbN/MgO/NbN Josephson junctions have been realized with MgO barriers up to a thickness of d=1 nm. The junction properties coherently scale with the size of barrier, and low critical current densities down to 3 A/cm

Highly homogeneous YBCO/LSMO nanowires for photoresponse experiments

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Escape dynamics in moderately damped Josephson junctions (Review Article)

have been achieved for larger barriers. In this limit, junctions exhibit macroscopic quantum phenomena for temperatures lower than 90 mK. Measurements and junction parameters support the notion of a possible use of these devices for multiphoton quantum experiments, taking advantage of the fast non equilibrium electron-phonon relaxation times of NbN.

Eddy Current Technique Based on

By using nanolithography and a soft etching procedure, we have realized YBa2Cu3O7-x/La0.7Sr0.3MnO3 (YBCO/LSMO) nanowires, with cross sections down to 100 x 50 nm(2) that ensure the cover age of areas up to 10 x 30 mu m(2). The LSMO layer acts as a capping for YBCO, minimizing the degradation of the superconducting properties taking place during the patterning; moreover, as a ferromagnetic manganite, it is expected to accelerate the relaxation dynamics of quasiparticles in YBCO, making such a system potentially attractive for applications in superconducting ultrafast optoelectronics. The reproducibility of the values of the critical current densities measured in different devices with the same geometry makes our nanowires ideal candidates for photoresponse experiments. First measurements have shown a satisfactory photoresponse from YBCO/LSMO devices.

{\rm HT}_{\rm c}

The Josephson effect is a privileged access to the macroscopic quantum nature of superconductors. We review some ideas and experimental techniques on macroscopic quantum decay phenomena occurring in Josephson structures. The attention is mainly addressed to intermediate levels of dissipation which characterize a large majority of low critical current Josephson devices and are therefore an avoidable consequence of nanotechnology applied more and more to Josephson devices. Phase diffusion phenomena take over thermal activation in some temperature ranges also affecting the transition to macroscopic quantum tunneling, enriching the phase diagram mostly defined by the Josephson energy, the temperature and the level of dissipation.

-SQUID and GMR Sensors for Non-Destructive Evaluation of Fiber/Metal Laminates

In this work we present non-destructive evaluation measurements on fiber/metal laminate specimen by using eddy current techniques employing HTc SQUID (superconductive quantum interference device) and giant magneto-resistive (GMR) sensors. Our aim is to compare the performance and the capability of HTc SQUID and GMR sensors to detect the presence of damage inside FML composite materials. Experimental results concerning the detection of artificial defects in aeronautical structures with high magnetic sensitivity by using HTc SQUID, and with high spatial resolution using GMR, will be presented and discussed.

Structural health monitoring of materials by high critical temperature SQUID

Abstract Nowadays, tailoring the material properties is essential for advanced product design in engineering systems. The need to provide key information about micro- and macro-structural behaviour of materials, without destructively sectioning the sample, has spurred the development of nondestructive evaluation methodologies. These techniques are required during material production, quality testing of components during manufacturing, and in-service inspection of structural integrity. To ensure the highest possible operational safety along with an economic efficiency, it is necessary to carry out inspections with a high sensitivity and a proven reliability. Due to its unparalleled magnetic field sensitivity over a wide frequency range and large dynamic range, SQUID-based nondestructive evaluation has unique advantages for materials and structures characterization. We will present an overview of eddy-current nondestructive analysis utilizing high T c SQUIDs with an emphasis on examples relevant to the aeronautical industry. These include the detection of deep-lying defects in multi-layer structures of Al–Ti alloys and damage of extremely lightweight graphite/epoxy composites. Both of these can be successfully treated by this approach where conventional electromagnetic probes often fail. In addition some results based on the volume integral formulation, successfully developed to simulate the response of the system to different type of flaws in Al-alloy planar structures and to solve the inverse electromagnetic problem, will be shown.