Gitte Blicher-Mathiesen

Sampling of herbicides in streams during flood events

In stream water xenobiotics usually occur as pulses in connection with floods caused by surface run-off and tile drainage following precipitation events. In streams located in small agricultural catchments we monitored herbicide concentrations during flood events by applying an intensive sampling programme of ½ h intervals for 7 h. In contrast to grab sampling under non-flood conditions, clearly elevated concentrations were recorded during the floods, and pulses varying in occurrence, duration and concentration were recorded. Pulses of recently applied herbicides were the most prominent, but also agricultural herbicides used in previous seasons caused pulses in the streams. Asynchronism of chemographs may be related to the characteristics of the compounds as well as their transport pathways and transformation in compartments between the source and the point of sampling in the stream. Thus, the occurrence of chemographs is difficult to predict, which ought to be taken into account when designing a sampling strategy. Even though the chemographs of herbicides and their transformation products (glyphosate and aminomethylphosphonic acid (AMPA) as well as terbuthylazine and desethylterbuthylazine) seem to be synchronous, their occurrence may still be difficult to predict. It is evident that grab sampling under non-flood conditions yields insufficient information on the dynamics of occurrence of herbicides in stream water, both with respect to environmental effects and the calculation of the load to a recipient. In conclusion, the design of a sampling strategy regarding herbicides in stream waters should adequately consider the aim of the investigation.

The combined effects of fertilizer reduction on high risk areas and increased fertilization on low risk areas, investigated using the SWAT model for a Danish catchment

Some agricultural areas lose considerably more than the average amounts of nutrients to waterways (high risk areas, HRAs) and others considerably less than the average (low risk areas, LRAs). These areas are of great interest when river catchment managers seek to both reduce nutrient loads to lakes and marine areas and to allow intensive agriculture. If HRAs were farmed with decreased inputs of fertilizers the environmental benefit would be larger here than from any other areas, and if LRAs were farmed with increased fertilizer use it could be done here causing less environmental damage than at any other areas. If both these changes were applied within the same catchment they might counter balance each other and give the possibility of intensified farming without causing environmental deterioration. We used the semi-distributed SWAT model to identify both HRAs and LRAs in an intensely farmed lowland catchment in Denmark. These areas are classified as the 10% of the agricultural area leaching, respectively, the most and the least nitrogen. Two scenarios were run for HRAs (reduced fertilizer input by 20%) and LRAs (increased fertilizer input by 20%) separately and two were run where both HRAs and LRAs were included. The scenario results showed that the HRA scenario yielded a decrease (3.3%) in nitrate river load at the catchment scale and that the LRA scenario yielded only a small increase (0.9%). The combined scenarios showed an overall decrease in river nitrate load (2.2%).

Successful reduction of diffuse nitrogen emissions at catchment scale: example from the pilot River Odense, Denmark

Land-based total nitrogen (N) loadings to Danish coastal waters have been markedly reduced since 2000. This has been achieved by general measures reducing discharges from all point sources and N leaching from farmed land supplemented with more local and targeted mitigation measures such as restoration of wetlands to increase the catchment-specific N retention. In the catchment of River Odense, restoration of wetlands has been extensive. Thus, in the major gauged catchment (485 km(2)) eleven wetlands (860 ha) have been restored since 2000. A comparison of data on N concentrations and loss from a gauging station in the River Odense with data from a control catchment (772 km(2)), in which a significantly less intensive wetland restoration programme has been undertaken, showed an excess downward trend in N, amounting to 124 t N yr(-1), which can be ascribed to the intensive wetland restoration programme carried out in the River Odense catchment. In total, the N load in the River Odense has been reduced by 377 t N yr(-1) (39%) since 2000. The observed downward trend is supported by monitoring data from two wetlands restored in 2001 and 2004 in the River Odense catchment.

Temporal trends in phosphorus concentrations and losses from agricultural catchments in the Nordic and Baltic countries

This paper in a uniform manner examines temporal trends in phosphorus (P) concentrations and losses from small and well-monitored agricultural catchments in the Nordic and Baltic countries. Thirty-four catchments (range 0.1–33 km2) in Norway (8), Denmark (5), Sweden (8), Finland (4), Estonia (3), Latvia (3) and Lithuania (3) were selected for the study. The time series ranged from 10 (2002–2011) to 21 years (1989–2009). The monthly P concentration and loss time series were tested for significant monotone trends (p < 0.05; two-sided test) using the partial Mann–Kendall test with stream discharge as an explanatory variable. The results show a large variation in concentrations and losses of total phosphorus (TP) among the 34 studied catchments, where the long-term mean annual losses varied from 0.09 to 7.5 kg TP ha−1. In addition, a large interannual variability in losses within catchments was found with up to a factor of 23 between years within the same catchment. Six catchments showed downward temporal trends in the TP loss time series. One upward trend in TP losses was detected in a catchment in south-west Sweden. Eight downward trends were detected in the TP concentration time series. Overall, our results show (1) a huge variability in mean P losses and concentrations among catchments, (2) a huge temporal variability in losses within catchments and (3) few detectable changes in P losses and concentrations over the study period. The results showcase the need for implementation of mitigation strategies towards reduced P losses from agricultural landscapes in the Nordic/Baltic Sea region in order to improve P water quality and ecology in surface waters.

Environmental Impacts—Freshwater Biogeochemistry

Climate change effects on freshwater biogeochemistry and riverine loads of biogenic elements to the Baltic Sea are not straight forward and are difficult to distinguish from other human drivers such as atmospheric deposition, forest and wetland management , eutrophication and hydrological alterations. Eutrophication is by far the most well-known factor affecting the biogeochemistry of the receiving waters in the various sub-basins of the Baltic Sea. However, the present literature review reveals that climate change is a compounding factor for all major drivers of freshwater biogeochemistry discussed here, although evidence is still often based on short-term and/or small-scale studies.