Gregory A. Wandless

Composition of the earth's upper mantle. I - Siderophile trace elements in ultramafic nodules

Seven siderophile elements (Au, Ge, Ir, Ni, Pd, Os, Re) were determined by radiochemical neutron activation analysis in 19 ultramafic rocks, which are spinel lherzollites-xenoliths from North and Central America, Hawaii and Australia, and garnet Iherzolitexenoliths from Lesotho. Abundances of the platinum metals are very uniform in spinel lherzolites averaging 3.4 ± 1.2 ppb Os, 3.7 ± 1.1 ppb Ir, and 4.6 ± 2.0 ppb Pd. Sheared garnet lherzolite PHN 1611 has similar abundances of these elements, but in 4 granulated garnet lherzolites, abundances are more variable. In all samples, the Pt metals retain cosmic ( Cl-chondrite) ratios. Abundances of Au and Re vary more than those of Pt metals, but the Au/Re ratio remains close to the cosmic value. The fact that higher values of Au and Re approach cosmic proportions with respect to the Pt metals, suggests that Au and Re have been depleted in some ultramafic rocks from an initially chondrite-like pattern equivalent to about 0.01 of Cl chondrite abundances. The relative enrichment of Au and Re in crustal rocks is apparently the result of crust—mantle fractionation and does not require a special circumstance of core—mantle partitioning. Abundances of moderately volatile elements Ni, Co and Ge are very uniform in all rocks, and are much higher than those of the highly siderophile elements Au, Ir, Pd, Os and Re. When normalized to Cl chondrites, abundances of Ni and Co are nearly identical, averaging 0.20 ± 0.02 and 0.22 ± 0.02, respectively; but Ge is only 0.027 ± 0.004. The low abundance of Ge relative to Ni and Co is apparently a reflection of the general depletion of volatile elements in the Earth. The moderately siderophile elements cannot be derived from the same source as the highly siderophile elements because of the marked difference in Cl chondrite-normalized abundances and patterns. We suggest that most of the Ni, Co and Ge were enriched in the silicate by the partial oxidation of pre-existing volatile-poor Fe-Ni, whereas the corresponding highly siderophile elements remained sequestered by the surviving metal. The highly siderophile elements may have been introduced by a population of ~103 large (~1022 g) planetisimals, similar to those forming the lunar mare basins.

Rare earth element distribution in some hydrothermal minerals: evidence for crystallographic control

Rare earth element (REE) abundances were measured by neutron activation analysis in anhydrite (CaSO4), barite (BaSO4), siderite (FeCO3) and galena (PbS). A simple crystal-chemical model qualitatively describes the relative affinities for REE substitution in anhydrite, barite, and siderite. When normalized to ‘crustal’ abundances (as an approximation to the hydrothermal fluid REE pattern), log REE abundance is a surprisingly linear function of (ionic radius of major cation—ionic radius of REE)2 for the three hydrothermal minerals, individually and collectively. An important exception, however, is Eu, which is anomalously enriched in barite and depleted in siderite relative to REE of neighboring atomic number and trivalent ionic radius. In principle, REE analyses of suitable pairs of co-existing hydrothermal minerals, combined with appropriate experimental data, could yield both the REE content and the temperature of the parental hydrothermal fluid. The REE have only very weak chalcophilic tendencies, and this is reflected by the very low abundances in galena—La, 0.6 ppb; Sm, 0.06 ppb; the remainder are below detection limits.

Contribution of metapelitic sediments to the composition, heat production, and seismic velocity of the lower crust of southern New Mexico, U.S.A.

Abstract Granulite xenoliths erupted at Kilbourne Hole maar were recently extracted from the lower crust of southern New Mexico. Garnet- and sillimanite-bearing quartzofeldspathic xenoliths had pelitic protoliths and were probably emplaced in the lower crust by tectonic underplating at a lower Proterozoic subduction zone. Thus the Kilbourne Hole metapelitic xenoliths illustrate the potential role of tectonosedimentary processes at convergent margins in determining the ultimate composition of the crust. Average P-wave velocities for metapelitic xenoliths from Kilbourne Hole are ∼ 7 km/s at 6 kbar, like those of mafic metagabbros and anorthosites. However, in contrast to mafic lithologies, the major element composition of the representative pelitic paragneiss (RPP) described in this paper is relatively siliceous and like that of average upper crust. Except for depletions of U and Cs, the trace element characteristics of the RPP are like those of pelitic sediments and are 3–10 times higher than those typically estimated for the lower crust. The heat production of the RPP is high (1.0 μW/m3) as are those of many granulite- and amphibolite-grade metapelites. In general, portions of the lower crust in which sediments are present may be high in light ion lithophile and rare earth element abundances, heat production, δ18O, and87Sr/86Sr. Moreover, the high Pb contents and unradiogenic Pb isotope signatures of metapelites provide an important reservoir for unradiogenic Pb in the earth as a whole.

Shallow marine response to global climate change during the Paleocene‐Eocene Thermal Maximum, Salisbury Embayment, USA

The Paleocene-Eocene Thermal Maximum (PETM) was an interval of extreme warmth that caused disruption of marine and terrestrial ecosystems on a global scale. Here we examine the sediments, flora and fauna from an expanded section at Mattawoman Creek-Billingsley Road (MCBR) in Maryland and explore the impact of warming at a nearshore shallow marine (30-100 m water depth) site in the Salisbury Embayment. Observations indicate that, at the onset of the PETM, the site abruptly shifted from an open-marine to prodelta setting with increased terrestrial and fresh water input. Changes in microfossil biota suggest stratification of the water column and low oxygen bottom water conditions in the earliest Eocene. Formation of authigenic carbonate through microbial diagenesis produced an unusually large bulk carbon isotope shift, while the magnitude of the corresponding signal from benthic foraminifera is similar to that at other marine sites. This proves that the landward increase in the magnitude of the carbon isotope excursion measured in bulk sediment is not due to a near instantaneous release of 12C-enriched CO2. We conclude that the MCBR site records nearshore marine response to global climate change that can be used as an analog for modern coastal response to global warming.