Guang-Nan Luo

Investigating behaviours of hydrogen in a tungsten grain boundary by first principles: from dissolution and diffusion to a trapping mechanism

We have investigated the dissolution, segregation and diffusion of hydrogen (H) in a tungsten (W) grain boundary (GB) using a first-principles method in order to understand the GB trapping mechanism of H. Optimal charge density plays an essential role in such a GB trapping mechanism. Dissolution and segregation of H are directly associated with the optimal charge density, which can be reflected by the H solution and segregation energy sequence for the different interstitial sites. To occupy the optimal-charge-density site, H can be easily trapped by the W GB with the solution and segregation energy of −0.23 eV and −1.11 eV, respectively. Kinetically, such a trapping is easier to realize due to the much lower diffusion barrier of 0.13–0.16 eV from the bulk to the GB in comparison with the segregation energy, suggesting that it is quite difficult for the trapped H to escape out of the GB. However, the GB can hold no more than 2 H atoms because the isosurface of optimal charge density almost disappears with the second H atom in, leading to the conclusion that H2 molecule and thus H bubble cannot form in the W GB. Taking into account the lower vacancy formation energy in the GB as compared with the bulk, we propose that the experimentally observed H bubble formation in the W GB should be via a vacancy trapping mechanism.

Microstructure dependence of deuterium retention and blistering in the near-surface region of tungsten exposed to high flux deuterium plasmas of 38 eV at 315 K

Four kinds of tungsten samples were exposed to 76 eV D-2(+) ions (38 eV D-1) at a flux of 10(22) D m(-2) s(-1). For plasma exposure at 315 K, blistering occurred more significantly on the unrecrystallized and single crystal W samples than the partially and fully recrystallized W samples. The un-recrystallized W sample showed the largest retention ratio at the same fluence. For samples exposed to higher fluences (up to 10(27) D m(-2)), the phenomena of bursting release of deuterium and blister bursting were clearly observed. Preliminary positron annihilation measurements indicated that the vacancy concentration in the near-surface region of tungsten increased after the deuterium plasma exposure. The results of electron back-scattering diffraction showed a strong dependence of blistering upon grain orientation, suggesting the possibility of alleviating blistering by selective texturing of tungsten for future fusion reactors.

Approaches towards long-pulse divertor operations on EAST by active control of plasma–wall interactions

The Experimental Advanced Superconducting Tokamak (EAST) has demonstrated, for the first time, long-pulse divertor plasmas over 400 s, entirely driven by lower hybrid current drive (LHCD), and further extended high-confinement plasmas, i.e. H-modes, over 30 s with predominantly LHCD and advanced lithium wall conditioning. Many new and exciting physics results have been obtained in the quest for long-pulse operations. The key findings are as follows: (1) access to H-modes in EAST favours the divertor configuration with the ion ∇B drift directed away from the dominant X-point; (2) divertor asymmetry during edge-localized modes (ELMs) also appears to be dependent on the toroidal field direction, with preferential particle flow opposite to the ion ∇B drift; (3) LHCD induces a striated heat flux (SHF), enhancing heat deposition away from the strike point, and the degree of SHF can be modified by supersonic molecule beam injection; (4) the long-pulse H-modes in EAST exhibit a confinement quality between type-I and type-III ELMy H-modes, with H98(y,2) ~ 0.9, similar to type-II ELMy H-modes.

Dissolving, trapping and detrapping mechanisms of hydrogen in bcc and fcc transition metals

First-principles calculations are performed to investigate the dissolving, trapping and detrapping of H in six bcc (V, Nb, Ta, Cr, Mo, W) and six fcc (Ni, Pd, Pt, Cu, Ag, Au) metals. We find that the zero-point vibrations do not change the site-preference order of H at interstitial sites in these metals except Pt. One vacancy could trap a maximum of 4 H atoms in Au and Pt, 6 H atoms in V, Nb, Ta, Cr, Ni, Pd, Cu and Ag, and 12 H atoms in Mo and W. The zero-point vibrations never change the maximum number of H atoms trapped in a single vacancy in these metals. By calculating the formation energy of vacancy-H (Vac-Hn) complex, the superabundant vacancy in V, Nb, Ta, Pd and Ni is demonstrated to be much more easily formed than in the other metals, which has been found in many metals including Pd, Ni and Nb experimentally. Besides, we find that it is most energetically favorable to form Vac-H1 complex in Pt, Cu, Ag and Au, Vac-H4 in Cr, Mo and W, and Vac-H6 in V, Nb, Ta, Pd and Ni. At last, we examine the detr...

Overview of plasma-facing materials and components for EAST

By the end of September 2006, the engineering commissioning of the Experimental Advanced Superconducting Tokamak (EAST) was completed and the first H2 plasma was achieved with stainless steel as the plasma-facing material (PFM). In the following phases, with gradual increase in the heating power, the EAST divertor targets have to handle expected heat loads up to ~10 MW m−2. The PFMs to be employed include doped graphite and W coatings. The former will be used to cover the whole plasma-facing surface in the first phase, and then the latter applied to replace the graphite tiles gradually in the second phase, and finally a whole W plasma-facing surface will be expected. Graphite has been studied for many years and contributed greatly to the HT-7 to achieve long pulses of some 100 s. The W coatings are being developed and the latest R&D development is reported in the paper.

Characterizations of power loads on divertor targets for type-I, compound and small ELMs in the EAST superconducting tokamak

The Experimental Advanced Superconducting Tokamak (EAST) has recently achieved a variety of H-mode regimes with different edge-localized mode (ELM) dynamics, including type-I ELMs, compound ELMs, which are manifested by the onset of a large spike followed by a sequence of small spikes on Dα emissions, usual type-III ELMs, and very small ELMs. This newly observed very small ELMy H-mode appears to be similar to the type-II ELMy H-mode, with higher repetition frequency (~1 kHz) and lower amplitude than the type-III ELMy H-mode, exhibiting an intermediate confinement level between type-I and type-III ELMy H-modes. The energy loss and divertor power load are systematically characterized for these different ELMy H-modes to provide a physics basis for the next-step high-power long-pulse operations in EAST. Both type-I and compound ELMs exhibit good confinement (H98(y,2) ~ 1). A significant loss of the plasma stored energy occurs at the onset of type-I ELMs (~8%) and compound ELMs (~5%), while no noticeable change in the plasma stored energy is observed for the small ELMs, including both type-III ELMs and very small ELMs. The peak heat flux on divertor targets for type-I ELMs currently achieved in EAST is about 10 MW m−2, as determined from the divertor-embedded triple Langmuir probe system with high time resolution. As expected, type-III ELMs lead to much smaller divertor power loads with a peak heat flux of about 2 MW m−2. Peak power loads for compound ELMs are between those for type-I and type-III ELMs. It is remarkable that the new very small ELMy H-modes exhibit even lower target power deposition than type-III ELMs, with the peak heat flux generally below 1 MW m−2. These very small ELMs are usually accompanied by broadband fluctuations with frequencies ranging from 20 to 50 kHz, which may promote particle and power exhaust throughout the very small ELMy H-mode regime.

Particle and power deposition on divertor targets in EAST H-mode plasmas

The effects of edge-localized modes (ELMs) on divertor particle and heat fluxes were investigated for the first time in the Experimental Advanced Superconducting Tokamak (EAST). The experiments were carried out with both double null and lower single null divertor configurations, and comparisons were made between the H-mode plasmas with lower hybrid current drive (LHCD) and those with combined ion cyclotron resonance heating (ICRH). The particle and heat flux profiles between and during ELMs were obtained from Langmuir triple-probe arrays embedded in the divertor target plates. And isolated ELMs were chosen for analysis in order to reduce the uncertainty resulting from the influence of fast electrons on Langmuir triple-probe evaluation during ELMs. The power deposition obtained from Langmuir triple probes was consistent with that from the divertor infra-red camera during an ELM-free period. It was demonstrated that ELM-induced radial transport predominantly originated from the low-field side region, in good agreement with the ballooning-like transport model and experimental results of other tokamaks. ELMs significantly enhanced the divertor particle and heat fluxes, without significantly broadening the SOL width and plasma-wetted area on the divertor target in both LHCD and LHCD + ICRH H-modes, thus posing a great challenge for the next-step high-power, long-pulse operation in EAST. Increasing the divertor-wetted area was also observed to reduce the peak heat flux and particle recycling at the divertor target, hence facilitating long-pulse H-mode operation. The particle and heat flux profiles during ELMs appeared to exhibit multiple peak structures, and were analysed in terms of the behaviour of ELM filaments and the flux tubes induced by modified magnetic topology during ELMs.

Extraordinary high ductility/strength of the interface designed bulk W-ZrC alloy plate at relatively low temperature

The refractory tungsten alloys with high ductility/strength/plasticity are highly desirable for a wide range of critical applications. Here we report an interface design strategy that achieves 8.5 mm thick W-0.5 wt. %ZrC alloy plates with a flexural strength of 2.5 GPa and a strain of 3% at room temperature (RT) and ductile-to-brittle transition temperature of about 100 °C. The tensile strength is about 991 MPa at RT and 582 MPa at 500 °C, as well as total elongation is about 1.1% at RT and as large as 41% at 500 °C, respectively. In addition, the W-ZrC alloy plate can sustain 3.3 MJ/m2 thermal load without any cracks. This processing route offers the special coherent interfaces of grain/phase boundaries (GB/PBs) and the diminishing O impurity at GBs, which significantly strengthens GB/PBs and thereby enhances the ductility/strength/plasticity of W alloy. The design thought can be used in the future to prepare new alloys with higher ductility/strength.

Mechanical properties and microstructural change of W-Y2O3 alloy under helium irradiation.

A wet-chemical method combined with spark plasma sintering was used to prepare a W–Y2O3 alloy. High-temperature tensile tests and nano-indentation microhardness tests were used to characterize the mechanical properties of the alloy. After He-ion irradiation, fuzz and He bubbles were observed on the irradiated surface. The irradiation embrittlement was reflected by the crack indentations formed during the microhardness tests. A phase transformation from α-W to γ-W was investigated by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Polycrystallization and amorphization were also observed in the irradiation damage layer. The W materials tended to exhibit lattice distortion, amorphization, polycrystallization and phase transformation under He-ion irradiation. The transformation mechanism predicted by the atomic lattice model was consistent with the available experimental observations. These findings clarify the mechanism of the structural transition of W under ion irradiation and provide a clue for identifying materials with greater irradiation resistance.

Scaling of divertor power footprint width in RF-heated type-III ELMy H-mode on the EAST superconducting tokamak

Dedicated experiments for the scaling of divertor power footprint width have been performed in the ITER-relevant radiofrequency (RF)-heated H-mode scheme under the lower single null, double null and upper single null divertor configurations in the Experimental Advanced Superconducting Tokamak (EAST) under lithium wall coating conditioning. A strong inverse scaling of the edge localized mode (ELM)-averaged power fall-off width with the plasma current (equivalently the poloidal field) has been demonstrated for the attached type-III ELMy H-mode as λq ∝ I −1.05 p by various heat flux diagnostics including the divertor Langmuir probes (LPs), infra-red (IR) thermograph and reciprocating LPs on the low-field side. The IR camera and divertor LP measurements show that λq,IR ≈ λq,div-LPs/1.3 = 1.15B −1.25 p,omp , in good agreement with the multi-machine scaling trend during the inter-ELM phase between type-I ELMs or ELM-free enhanced Dα (EDA). H-mode. However, the magnitude is nearly doubled, which may be attributed to the different operation scenarios or heating schemes in EAST, i.e., dominated by electron heating. It is also shown that the type-III ELMs only broaden the power fall-off width slightly, and the ELM-averaged width is representative for the inter-ELM period. Furthermore, the inverse Ip (Bp) scaling appears to be independent of the divertor configurations in EAST. The divertor power footprint integral width, fall-off width and dissipation width derived from EAST IR camera measurements follow the relation, λint ∼ λq +1.64S, yielding λ EAST = (1.39±0.03)λ EAST +(0.97±0.35) mm. Detailed analysis of these three characteristic widths was carried out to shed more light on their extrapolation to ITER.