H. A. A. Sidek

Dielectric and ultrasonic properties of rubber wood. Effect of moisture content grain direction and frequency

Dielectric properties of rubber wood have been studied at low and microwave frequencies with different moisture content and grain direction. The ultrasonic properties were studied with pulsed longitudinal waves of frequency 45 kHz, Two anisotropic directions have been considered for this study — parallel and perpendicular to grain. The low frequencies were of 0.01, 0.1, L0, 10 and 100 Hz and microwave frequencies were of 1, 2.45, 6, 8, 10, 14 and 17 GHz. The moisture content affected the dielectric constant and dielectric loss factor both at low and microwave frequencies? The moisture content above 30% showed little influence on dielectric properties whereas it increases linearly from 0 to 30% in both the grain directions at low frequencies. A continuous increase of dielectric properties was obtained with the increase of moisture content at microwave frequencies and the trend becomes concave upward. Dielectric properties increase as the frequencies increase except dielectric loss factor at microwave frequencies where reverse trends were observed. Little change of dielectric loss factor was obtained at frequencies above 6 GHz. The parallel to grain direction showed higher dielectric constant and dielectric loss factor compared to perpendicular to grain direction. This dielectric anisotropy of wood may be attributed due to the microscopic, macroscopic molecular as well as chemical constituents of wood. Ultrasonic properties were also affected considerably by the moisture content and grain direction. The dried wood showed higher ultrasonic velocity and elastic stiffness constant compared to green wood. The parallel to grain direction exhibits higher ultrasonic velocity and elastic stiffness constant than perpendicular to grain.ZusammenfassungDie dielektrischen Eigenschaften von Hevea brasiliensis wurden bei niedriger und Mikrowellenfrequenz sowie unterschiedlichen Feuchten und Faserrrichtungen untersucht. Die Ultraschalleigenschaften wurden mit gepulsten Longitudinalwellen von 45 kHz bestimmt. Beide Bestimmungen erfolgten parallel und senkrecht zur Faser. Als niedrige Frequenzen wurden 0,01, 0,1, 1,0, 10 und 100 Hz eingesetzt, im Mikrowellenbereich 1, 2, 4, 5, 6, 8, 10, 14 und 17 GHz. Die Feuchte beeinflußt die Dielektrizitätskonstante und den Verlustfaktor in beiden Frequenzbereichen. Zwischen 0 und 30% Feuchte steigt die Dielektrizitätskonstante bei niedrigen Frequenzen linear

Optical Properties of Ternary TeO2-B2O3-ZnO Glass System

A series of ternary tellurite based glasses [(TeO2)70 (B203)30]100–x [ZnO]x glasses with different compositions of ZnO (x= 5 to 30 wt.% in steps of 5 wt.%) have been synthesized by melt quenching method. The role of ZnO to the glasses structure was studied by IR spectroscopy. FTIR spectra revealed broad, weak and strong absorption bands in the investigated range of wavenumber from 280–4000 cm−1 which associated with their corresponding bond modes of vibration and the glass structure. The indirect optical band gap and the direct optical band gap are in the range 2.08–3.12 and 1.54–2.36 eV, respectively. A decrease in the values of energy band gap Eg may come down to the reason that the non-bridging oxygen ion content increases with increasing ZnO content and shifting the band edge to lower energies. The optical band gap and Urbach energies were calculated from the absorption spectra measured between 190 and 900 nm at room temperature. The refractive index, n of the glasses change from 1.84–2.00 while the molar refractivities decrease from 13.06 to 12.00 with the increase of ZnO in mol%.

The Effect of Remelting on the Physical Properties of Borotellurite Glass Doped with Manganese

A systematic set of borotellurite glasses doped with manganese (1–x) [(B2O3)0.3(TeO2)0.7]-xMnO, with x = 0.1, 0.2, 0.3 and 0.4 mol%, were successfully synthesized by using a conventional melt and quench-casting technique. In this study, the remelting effect of the glass samples on their microstructure was investigated through density measurement and FT-IR spectra and evaluated by XRD techniques. Initial experimental results from XRD evaluation show that there are two distinct phases of glassy and crystallite microstructure due to the existence of peaks in the sample. The different physical behaviors of the studied glasses were closely related to the concentration of manganese in each phase. FTIR spectra revealed that the addition of manganese oxide contributes the transformation of TeO4 trigonal bipyramids with bridging oxygen (BO) to TeO3 trigonal pyramids with non-bridging oxygen (NBO).

Effect of ZnO on the Thermal Properties of Tellurite Glass

Systematic series of binary zinc tellurite glasses in the form (where to 0.4 with an interval of 0.05 mole fraction) have been successfully prepared via conventional melt cast-quenching technique. Their density was determined by Archimedes method with acetone as buoyant liquid. The thermal expansion coefficient of each zinc tellurite glasses was measured using L75D1250 dilatometer, while their glass transition temperature () was determined by the SETARAM Labsys DTA/6 differential thermogravimetric analysis at a heating rate of 20 K min−1. The acoustic Debye temperature and the softening temperature () were estimated based on the longitudinal () and shear ultrasonic () wave velocities propagated in each glass sample. For ultrasonic velocity measurement of the glass sample, MATEC MBS 8000 Ultrasonic Data Acquisition System was used. All measurements were taken at 10 MHz frequency and at room temperature. All the thermal properties of such binary tellurite glasses were measured as a function of ZnO composition. The composition dependence was discussed in terms of ZnO modifiers that were expected to change the thermal properties of tellurite glasses. Experimental results show their density, and the thermal expansion coefficient increases as more ZnO content is added to the tellurite glass network, while their glass transition, Debye temperature, and the softening temperature decrease due to a change in the coordination number (CN) of the network forming atoms and the destruction of the network structure brought about by the formation of some nonbridging oxygen (NBO) atoms.

Effect of AlF3 on the density and elastic properties of zinc tellurite glass systems

This paper presents the results of the physical and elastic properties of the ternary zinc oxyfluoro tellurite glass system. Systematic series of glasses (AlF3)x(ZnO)y(TeO2)z with x = 0–19, y = 0–20 and z = 80, 85, 90 mol% were synthesized by the conventional rapid melt quenching technique. The composition dependence of the physical, mainly density and molar volume, and elastic properties is discussed in term of the AlF3 modifiers addition that are expected to produce quite substantial changes in their physical properties. The absence of any crystalline peaks in the X-ray diffraction (XRD) patterns of the present glass samples indicates the amorphous nature. The addition of AlF3 lowered the values of the densities in ternary oxyfluorotellurite glass systems. The longitudinal and transverse ultrasonic waves propagated in each glass sample were measured using a MBS8020 ultrasonic data acquisition system. All the velocity data were taken at 5 MHz frequency and room temperature. The longitudinal modulus (L), shear modulus (G), Young’s modulus (E), bulk modulus (K) and Poisson’s ratio (σ) are obtained from both velocities data and their respective density. Experimental data shows the density and elastic moduli of each AlF3-ZnO-TeO2 series are found strongly depend upon the glass composition. The addition of AlF3 modifiers into the zinc tellurite causes substantial changes in their density, molar volume as well as their elastic properties.

Effect of Concurrent ZnO Addition and AlF3 Reduction on the Elastic Properties of Tellurite Based Glass System

New ternary zinc oxyfluorotellurite (ZOFT) with the composition --, where ; ; , has been successfully prepared by the conventional rapid melt quenching technique. Density, molar volume, and glass transition temperature have been assessed for each ZOFT glass sample. The longitudinal and transverse ultrasonic waves propagated in each glass sample were measured using a MBS8020 ultrasonic data acquisition system at 5 MHz frequency and room temperature. The longitudinal modulus (), shear modulus (), Young’s modulus (), bulk modulus (), and Poisson’s ratio () are assessed from both velocity data and their respective density. The compositional dependence of the ultrasonic velocities and related parameters are discussed to understand the rigidity and compactness of the glass system studied.