H. E. Revercomb

Solar and thermal radiation in the Venus atmosphere

Attention is given to the solar and thermal radiation fields of Venus. Direct measurements and the results of numerical models based on direct measurements are presented. Radiation outside the atmosphere is considered with emphasis placed on global energy budget parameters, spectral and angular dependences, spatial distribution, and temporal variations of solar and thermal radiation. Radiation fluxes inside the atmosphere below 90 km are also considered with attention given to the solar flux at the surface, solar and thermal radiation fluxes from 100 km to the surface, and radiative heating and cooling below 100 km.

First Sounding Results from VAS-D

First results are presented from an experiment to sound the atmospheres temperature and moisture distribution from a geostationary satellite. Sounding inferences in clear and partially cloudy conditions have the anticipated accuracy and horizontal and vertical resolutions. Most important is the preliminary indication that small but significant temporal variations of atmospheric temperature and moisture can be observed by the geostationary satellite sounder. Quantitative assessment of the accuracy and meteorological utility of this new sounding capability must await the accumulation of results over the coming months.

Net thermal radiation in the atmosphere of Venus

Abstract The four entry probes of the Pioneer Venus mission measured the radiative net flux in the atmosphere of Venus at latitudes of 60°N, 31°S, 27°S, and 4°N. The three higher latitude probes carried instruments (small probe net flux radiometers; SNFR) with external sensors. The measured SNFR net fluxes are too large below the clouds, but an error source and correction scheme have been found (H. E. Revercomb, L. A. Sromovsky, and V. E. Suomi, 1982, Icarus 52, 279–300) . The near-equatorial probe carried an infrared radiometer (LIR) which viewed the atmosphere through a window in the probe. The LIR measurements are reasonable in the clouds, but increase to physically unreasonable levels shortly below the clouds. The probable error source and a correction procedure are identified. Three main conclusions can be drawn from comparisons of the four corrected flux profiles with radiative transfer calculations: (1) thermal net fluxes for the sounder probe do not require a reduction in the Mode 3 number density as has been suggested by O. B. Toon, B. Ragent, D. Colburn, J. Blamont, and C. Cot (1984, Icarus 57, 143–160) , but the probe measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2–5 × 10−5 near 60°, 2–5 × 10−4 near 30°, and 5 × 10−4 near the equator. The suggested latitudinal variation of IR cooling is consistent with descending motions at high latitudes, and it is speculated that it could provide an important additional drive for the general circulation.

Preliminary Results of the Pioneer Venus Small Probe Net Flux Radiometer Experiment

Net radiation measurements in the atmosphere of Venus indicate that the bulk of the atmosphere is radiatively cooling at high latitudes and heating at low latitudes. Similarity of features observed by all three probes indicate planetwide stratification. Flux variations within the clouds provide evidence of significant differences in cloud structure. A feature of unusually large opacity found near 60 kilometers at the north probe site is probably related to the unique circulation regime revealed by ultraviolet and infrared imagery. A stable layer between the cloud bottoms and about 35 kilometers contains several features in the flux profiles probably resulting from large-scale compositional stratifications rather than clouds. In the layer below 35 kilometers unexpectedly large fluxes were observed.

Pioneer Venus Small Probes Net Flux Radiometer Experiment

The University of Wisconsin net flux experiment on the Pioneer Venus mission investigated the distribution of radiative energy deposition and loss which drives atmospheric circulation on Venus. The instrument used an external sensor and a novel method of chopping to measure the net flux of solar and planetary radiation during descent through the thick Venus atmosphere. The sensor, consisting of a high temperature flux plate detector and protective diamond windows, was designed to make accurate flux measurements while exposed to the severe Venus environment.

Statistical-mechanical theory of passive transport through semipermeable membranes

The first general multicomponent equations for transport through semipermeable membranes are derived from basic statistical-mechanical principles. The procedure follows that used earlier for open membranes, but semipermeability is modelled mathematically by the introduction of external forces on the impermeant species. Gases are treated first in order to clarify the problems involved, but the final results apply to general nonideal solutions of any concentration. The mixed-solvent effect is treated rigorously, and a mixed-solvent osmotic pressure is defined. A useful specific identification of so-called osmotic flow is given, along with a demonstration that such an identification cannot be unique. Results are obtained both for discontinuous membrane models, and for a continuous model.

Reassessment of net radiation measurements in the atmosphere of Venus

Abstract Net radiative flux measurements by instruments on the Pioneer Venus Day, North, and Night probes are too large below 30 km to be consistent with present estimates of atmospheric opacity. We evaluate the only known mechanisms which could potentially have caused significant errors in the deep atmosphere, namely, (1) radiation field perturbations behind each probe due to its thermal wake, (2) cloud particle deposition on the sensor windows, and (3) thermal perturbations within the radiation sensor produced by gas flow through the sensor window retainers. Thermal analysis of the wake effect shows that temperature perturbations are not large enough to produce significant flux perturbations when gas opacity and sensor field-of-view characteristics are taken into account. The particle deposition effect is rejected because it requires a signature in the measured radiation profile which is not observed. The absence of such a feature also implies that mode 3 cloud particles are either not sulfuric acid or are far less numerous than previously reported. We find that the third mechanism is the most likely source of the large net flux measurements. However, this error is not sufficiently constrained by laboratory data to allow rigorous corrections to the measured flux profiles. If we use radiative transfer calculations to constrain the fluxes at 14 km and limited laboratory data to estimate the altitude dependence of the error, then we obtain a plausible set of corrected flux profiles which are roughly consistent with reasonable H2O mixing ratios below the clouds.

Temperature structure in the lower atmosphere of Venus - New results derived from Pioneer Venus entry probe measurements

Abstract The interpretation of unexpected characteristics of Pioneer Venus temperature measurements, and of the large difference between these and the Venera results, is aided by new Venus temperature profiles derived from engineering measurements of the Pioneer Venus Small-Probe Net Flux Radiometer (SNFR) instruments. To facilitate correction of a temperature-dependent radiometric response, these instruments monitored the temperatures of their deployed radiation detectors. The accurate calibration of the temperature sensors, and their strong thermal coupling to the atmosphere, make it possible to deduce atmospheric temperatures within 2°K (at most altitudes) using a simple two-component thermal model to account for lag effects. These independent temperature profiles generally confirm to high accuracy, the small-probe results of A. Seiff, D. B. Kirk, R. E. Young, R. C. Blanchard, J. T. Findlay, G. M. Kelly, and S. C. Sommer (1980a, J. Geophys. Res. 85, pp. 7903–7933) concerning vertical structure and horizontal contrast in the lower atmosphere, although the stable layer below 25 km is found to be slightly more stable (by about 0.4°K/km) and absolute temperatures are an average of 2°K higher. The measured Day-Night thermal contrast is compatible with predicted responses to the diurnal variation in solar heating, except near the cloud base, where 3–5°K differences may be due to thermal radiative heating differences associated with different cloud opacities. Temperature contrasts between latitudes 30 and 60° are roughly consistent with cyclostrophic balance. But pressure and temperature measurements by the Pioneer Venus Sounder probe at 4° latitude, when compared to Small-probe results, imply unreasonably large equatorward accelerations of 100 (m/sec)/day. Poleward accelerations compatible with cyclostrophic balance can be obtained if Sounder-probe temperatures are increased by a scale-factor correction reaching 6–7°K at 13 km.

Bounds for thermodynamic Green's functions from the application of path integral methods

Symanziks inequalities for thermodynamic Greens functions are applied to correlation functions occurring in the quantum statistical mechanics of dilute gases. The application is based on the use of the constant‐force Greens function. The results are compared with the results of classical path approximations. The Greens function inequality corresponding to the Feynman‐Hibbs partition function inequality is derived and discussed. Applications to a model of hydrogen vapor and to the statistical mechanics of the hydrogen atom are presented.

Thermal net flux measurements on the pioneer Venus entry probes

Abstract Corrected thermal net radiation measurements from the four Pioneer Venus entry probes at latitudes of 60°N, 31°S, 27°S, and 4°N are presented. Three main conclusions can be drawn from comparisons of the corrected fluxes with radiative transfer calculations: (1) sounder probe net fluxes are consistent with the number density of large cloud particles (mode 3) measured on the same probe, but the IR measurements as a whole are most consistent with a significantly reduced mode 3 contribution to the cloud opacity; (2) at all probe sites, the fluxes imply that the upper cloud contains a yet undetected source of IR opacity; and (3) beneath the clouds the fluxes at a given altitude increase with latitude, suggesting greater IR cooling below the clouds at high latitudes and water vapor mixing ratios of about 2–5×10 −5 near 60°, 2–5×10 −4 near 30°, and >5×10 −4 near the equator.