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Featured researches published by H. M. Buck.


ChemInform | 1973

CNDO/2 and INDO calculations of a reaction pathway for the sigmatropic [1, 5] H-shift in cyclopentadiene

J. R. De Dobbelaere; J.W. de Haan; H. M. Buck; Gj Visser

CNDO/2 and INDO calculations have been carried out in order to construct a suitable model for the activated complex during the reaction. In this reaction model the migrating hydrogen atom moves along an edge of the cyclopentadiene ring. An analysis of this situation suggests a partial electron transfer from the migrating hydrogen to the nascent cyclopentadienyl system. This charge transfer is discussed in terms of aromaticity. The calculated activation enthalpies are 10 kcal/mole (CNDO/2) and 17 kcal/mole (INDO), whereas the experimental value is ca. 24 kcal/mole [1].


Recueil des Travaux Chimiques des Pays-Bas | 2010

Stereospecific reactions of aryl‐substituted acetylenes in strong proton acids, formation of homocyclopropenyl cations

Ae van der Hout-Lodder; H. M. Buck; L.J. Oosterhoff


Journal of the American Chemical Society | 1977

On the mechanism of reductive cleavage of aryl phosphates

Sheldon J. Shafer; W. D. Closson; J. M. F. Van Dijk; Oscar Piepers; H. M. Buck


Recueil des Travaux Chimiques des Pays-Bas | 2010

13C N.M.R. and charge distribution in arylcyclobutenyl cations. Part II

S. A. E. van der Hout‐Lodder; J.W. de Haan; L.J.M. van de Ven; H. M. Buck


Journal of Organic Chemistry | 1984

A new class of chiral detergents. The formation of single micelles from N,N-dimethyl-1-dodecyl-2,4-dimethyl-3-carbamoylpyridinium bromide. A CD study

R.J.E.M. de Weerd; H.M.P.J. van Hal; H. M. Buck


Recueil des Travaux Chimiques des Pays-Bas | 2010

ESR of positive radical ions of triphenylphosphonium methylides: (Short communication)

H. M. Buck; A. H. Huizer; S. J. Oldenburg; P. Schipper


Recueil des Travaux Chimiques des Pays-Bas | 2010

Formation of trimethylcarbonium ion by hydride abstraction from isobutane with pentamethylbenzyl cation

H. M. Buck


The Journal of Physical Chemistry | 1983

Lithium halide and lithium perchlorate binding to phosphates : a multinuclear nuclear magnetic resonance spectroscopic study

J.J.C. van Lier; L.J.M. van de Ven; J.W. de Haan; H. M. Buck


Recueil des Travaux Chimiques des Pays-Bas | 2010

Hydrogen atom transfer from alkanes and aromatic proton complexes to aromatic cations and quinones

H. M. Buck; L.J. Oosterhoff; M.J. v.d. Sluys-v.d. Vlugt; K. G. Verhoeven


The Journal of Physical Chemistry | 1984

Effects of single-stranded n-alkyl amphiphiles on the conformational and dynamic behavior of lecithin sonicated bilayers and micelles studied by 13C NMR : a measure of lipid resistance against disruption of the bilayer orientation

J.W. de Haan; R.J.E.M. de Weerd; L.J.M. van de Ven; H. M. Buck

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J.W. de Haan

Eindhoven University of Technology

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L.J.M. van de Ven

Eindhoven University of Technology

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J. van Dijk

Eindhoven University of Technology

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A. E. Van Der Hout-Lodder

Eindhoven University of Technology

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M.E. van Dommelen

Eindhoven University of Technology

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Pim Schipper

Eindhoven University of Technology

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A. A. Macco

Eindhoven University of Technology

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A. Corvers

Eindhoven University of Technology

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