H. Vömel

Characterization and Correction of Relative Humidity Measurements from Vaisala RS80-A Radiosondes at Cold Temperatures

Abstract Radiosonde relative humidity (RH) measurements are known to be unreliable at cold temperatures. This study characterizes radiosonde RH measurements from Vaisala RS80-A thin-film capacitive sensors in the temperature range 0° to −70°C. Sources of measurement error are identified, and two approaches for correcting the errors are presented. The corrections given in this paper apply only to the Vaisala RS80-A sensor, although the RS80-H sensor is briefly discussed for comparison. A temperature-dependent correction factor is derived from statistical analysis of simultaneous RH measurements from RS80-A radiosondes and the NOAA cryogenic frostpoint hygrometer. The mean RS80-A measurement error is shown to be a dry bias that increases with decreasing temperature, and the multiplicative correction factor is about 1.3 at −35°C, 1.6 at −50°C, 2.0 at −60°C, and 2.4 at −70°C. The fractional uncertainty in the mean of corrected measurements, when large datasets are considered statistically, increases from 0.06...

Observations of Near-Zero Ozone Concentrations Over the Convective Pacific: Effects on Air Chemistry

A series of measurements over the equatorial Pacific in March 1993 showed that the volume mixing ratios of ozone were frequently well below 10 nanomoles per mole both in the marine boundary layer (MBL) and between 10 kilometers and the tropopause. These latter unexpected results emphasize the enormous variability of tropical tropospheric ozone and hydroxyl concentrations, which determine the oxidizing efficiency of the troposphere. They also imply a convective short circuit of marine gaseous emissions, such as dimethyl sulfide, between the MBL and the uppermost troposphere, leading, for instance, to sulfate particle formation.

Radiation Dry Bias of the Vaisala RS92 Humidity Sensor

The comparison of simultaneous humidity measurements by the Vaisala RS92 radiosonde and by the Cryogenic Frostpoint Hygrometer (CFH) launched at Alajuela, Costa Rica, during July 2005 reveals a large solar radiation dry bias of the Vaisala RS92 humidity sensor and a minor temperature-dependent calibration error. For soundings launched at solar zenith angles between 10° and 30°, the average dry bias is on the order of 9% at the surface and increases to 50% at 15 km. A simple pressure- and temperature-dependent correction based on the comparison with the CFH can reduce this error to less than 7% at all altitudes up to 15.2 km, which is 700 m below the tropical tropopause. The correction does not depend on relative humidity, but is able to reproduce the relative humidity distribution observed by the CFH.

The evolution of the dehydration in the Antarctic stratospheric vortex

In 1994 an intensive program of balloon-borne frost point measurements was performed at McMurdo, Antarctica. During this program a total of 19 frost point soundings was obtained between February 7 and October 5, which cover a wide range of undisturbed through strongly dehydrated situations. Together with several soundings from South Pole station between 1990 and 1994, they give a comprehensive picture of the general development of the dehydration in the Antarctic stratospheric vortex. The period of dehydration typically starts around the middle of June, and a rapid formation of large particles leads to a fast dehydration of the vortex. The evaporation of falling particles leads to rehydration layers, which have significantly higher water vapor concentrations than the undisturbed stratosphere. Through the formation of these rehydration layers in the early stages of the dehydration we can estimate a particle fall speed of ⅓ km/d and thus a mean particle size of 4 μm. Ice saturation was observed over McMurdo in only two cases and only well after the onset of the dehydration. From the inspection of synoptic maps it then follows that a small cold region inside the vortex seems to be sufficient to dehydrate the entire vortex. Above 20 km the dehydration is completed by the end of July. From the descent of the upper dehydration edge we can estimate a mean descent rate inside the vortex of 1.5 km/month. In McMurdo we observed occasional penetration of the vortex edge in cases where the vortex edge was close to McMurdo, however, these cases seem to have little effect on the bulk of the vortex. A sounding from November 3, 1990, at South Pole shows that the dehydration may persist into November and indicates that there is no significant transport into the vortex throughout winter and early spring.

Chemical depletion of Arctic ozone in winter 1999/2000

During Arctic winters with a cold, stable stratospheric circulation, reactions on the surface of polar stratospheric clouds (PSCs) lead to elevated abundances of chlorine monoxide (ClO) that, in the presence of sunlight, destroy ozone. Here we show that PSCs were more widespread during the 1999/2000 Arctic winter than for any other Arctic winter in the past two decades. We have used three fundamentally different approaches to derive the degree of chemical ozone loss from ozonesonde, balloon, aircraft, and satellite instruments. We show that the ozone losses derived from these different instruments and approaches agree very well, resulting in a high level of confidence in the results. Chemical processes led to a 70% reduction of ozone for a region ∼1 km thick of the lower stratosphere, the largest degree of local loss ever reported for the Arctic. The Match analysis of ozonesonde data shows that the accumulated chemical loss of ozone inside the Arctic vortex totaled 117 ± 14 Dobson units (DU) by the end of winter. This loss, combined with dynamical redistribution of air parcels, resulted in a 88 ± 13 DU reduction in total column ozone compared to the amount that would have been present in the absence of any chemical loss. The chemical loss of ozone throughout the winter was nearly balanced by dynamical resupply of ozone to the vortex, resulting in a relatively constant value of total ozone of 340 ± 50 DU between early January and late March. This observation of nearly constant total ozone in the Arctic vortex is in contrast to the increase of total column ozone between January and March that is observed during most years.

Validation of Aura Microwave Limb Sounder Ozone by ozonesonde and lidar measurements

We present validation studies of MLS version 2.2 upper tropospheric and stratospheric ozone profiles using ozonesonde and lidar data as well as climatological data. Ozone measurements from over 60 ozonesonde stations worldwide and three lidar stations are compared with coincident MLS data. The MLS ozone stratospheric data between 150 and 3 hPa agree well with ozonesonde measurements, within 8% for the global average. MLS values at 215 hPa are biased high compared to ozonesondes by A`20% at middle to high latitude, although there is a lot of variability in this altitude region. Comparisons between MLS and ground-based lidar measurements from Mauna Loa, Hawaii, from the Table Mountain Facility, California, and from the Observatoire de Haute-Provence, France, give very good agreement, within A`5%, for the stratospheric values. The comparisons between MLS and the Table Mountain Facility tropospheric ozone lidar show that MLS data are biased high by A`30% at 215 hPa, consistent with that indicated by the ozonesonde data. We obtain better global average agreement between MLS and ozonesonde partial column values down to 215 hPa, although the average MLS values at low to middle latitudes are higher than the ozonesonde values by up to a few percent. MLS v2.2 ozone data agree better than the MLS v1.5 data with ozonesonde and lidar measurements. MLS tropical data show the wave one longitudinal pattern in the upper troposphere, with similarities to the average distribution from ozonesondes. High upper tropospheric ozone values are also observed by MLS in the tropical Pacific from June to November.

Reference upper-air observations for climate: rationale, progress, and plans.

While the global upper-air observing network has provided useful observations for operational weather forecasting for decades, its measurements lack the accuracy and long-term continuity needed for understanding climate change. Consequently, the scientific community faces uncertainty on key climate issues, such as the nature of temperature trends in the troposphere and stratosphere; the climatology, radiative effects, and hydrological role of water vapor in the upper troposphere and stratosphere; and the vertical profile of changes in atmospheric ozone, aerosols, and other trace constituents. Radiosonde data provide adequate vertical resolution to address these issues, but they have questionable accuracy and time-varying biases due to changing instrumentation and techniques. Although satellite systems provide global coverage, their vertical resolution is sometimes inadequate and they require independent reference observations for sensor and data product validation, and for merging observations from differ...

A trajectory-based estimate of the tropospheric ozone column using the residual method

We estimate the tropospheric column ozone using a forward trajectory model to increase the horizontal resolution of the Aura Microwave Limb Sounder (MLS) derived stratospheric column ozone. Subtracting the MLS stratospheric column from Ozone Monitoring Instrument total column measurements gives the trajectory enhanced tropospheric ozone residual (TTOR). Because of different tropopause definitions, we validate the basic residual technique by computing the 200-hPa-to-surface column and comparing it to the same product from ozonesondes and Tropospheric Emission Spectrometer measurements. Comparisons show good agreement in the tropics and reasonable agreement at middle latitudes, but there is a persistent low bias in the TTOR that may be due to a slight high bias in MLS stratospheric column. With the improved stratospheric column resolution, we note a strong correlation of extratropical tropospheric ozone column anomalies with probable troposphere-stratosphere exchange events or folds. The folds can be identified by their colocation with strong horizontal tropopause gradients. TTOR anomalies due to folds may be mistaken for pollution events since folds often occur in the Atlantic and Pacific pollution corridors. We also compare the 200-hPa-to-surface column with Global Modeling Initiative chemical model estimates of the same quantity. While the tropical comparisons are good, we note that chemical model variations in 200-hPa-to-surface column at middle latitudes are much smaller than seen in the TTOR.

Water vapor control at the tropopause by equatorial Kelvin waves observed over the Galápagos

Soundings of frost-point hygrometers, ozonesondes, and radiosondes at San Cristobal Island (0.9°S, 89.6°W) in September 1998 provide an observational evidence that equatorial Kelvin waves around the tropopause act as a dehydration pump for the stratosphere. During the downward-displacement phase of a Kelvin wave, dry and ozone-rich stratospheric air is transported into the upper troposphere. During the upward-displacement phase, on the other hand, higher specific-humidity air moves up in the tropopause region, but at the same time, this upward motion causes cooling of the air that limits the water vapor amount entering the stratosphere. Also, wave breaking contributes to the irreversible transport of ozone across the tropopause. Considering their omnipresence at the equatorial tropopause, we suggest that Kelvin waves may be one of the important agents for maintaining the dryness of the tropical lower stratosphere.

Evolution of Water Vapor Concentrations and Stratospheric Age of Air in Coupled Chemistry-Climate Model Simulations

Stratospheric water vapor concentrations and age of air are investigated in an ensemble of coupled chemistry-climate model simulations covering the period from 1960 to 2005. Observed greenhouse gas concentrations, halogen concentrations, aerosol amounts, and sea surface temperatures are all specified in the model as time-varying fields. The results are compared with two experiments (time-slice runs) with constant forcings for the years 1960 and 2000, in which the sea surface temperatures are set to the same climatological values, aerosol concentrations are fixed at background levels, while greenhouse gas and halogen concentrations are set to the values for the relevant years. The time-slice runs indicate an increase in stratospheric water vapor from 1960 to 2000 due primarily to methane oxidation. The age of air is found to be significantly less in the year 2000 run than the 1960 run. The transient runs from 1960 to 2005 indicate broadly similar results: an increase in water vapor and a decrease in age of air. However, the results do not change gradually. The age of air decreases significantly only after about 1975, corresponding to the period of ozone reduction. The age of air is related to tropical upwelling, which determines the transport of methane into the stratosphere. Oxidation of increased methane from enhanced tropical upwelling results in higher water vapor amounts. In the model simulations, the rate of increase of stratospheric water vapor during the period of enhanced upwelling is up to twice the long-term mean. The concentration of stratospheric water vapor also increases following volcanic eruptions during the simulations.