Hèctor Monclús

Biological nutrient removal in an MBR treating municipal wastewater with special focus on biological phosphorus removal

The performance of an MBR pilot plant for biological nutrient removal was evaluated during 210days of operation. The set point values for the internal recycles were determined in advance with the use of an optimisation spreadsheet based on the ASM2d model to optimise the simultaneous removal of C, N and P. The biological nutrient removal (BNR) efficiencies were high from the start of operation with COD and N removal efficiencies of 92+/-6% and 89+/-7, respectively. During the course of the experiment P removal efficiencies increased and finally a P-removal efficiency of 92% was achieved. The activity of poly-phosphate accumulating organisms (PAOs) and denitrifying poly-phosphate accumulating organisms (DPAOs) increased and the specific phosphate accumulation rates after 150days of operation amounted to 13.6mgPg(-1)VSSh(-1) and 5.6mgPg(-1)VSSh(-1), for PAOs and DPAOs, respectively.

Removal of microbial indicators from municipal wastewater by a membrane bioreactor (MBR).

The impact of removable and irremovable fouling on the retention of viral and bacterial indicators by the submerged microfiltration membrane in an MBR pilot plant was evaluated. Escherichia coli, sulphite-reducing Clostridium spores, somatic coliphages and F-specific RNA bacteriophages were used as indicators. The membrane demonstrated almost complete removal of E. coli and sulphite-reducing Clostridium spores. However, there was no correlation with membrane fouling. The phage removal varied in accordance with the irremovable fouling, rising from 2.6 to 5.6 log(10) units as the irremovable fouling increased (measured by the change in the transmembrane pressure). In contrast, removable fouling did not have any effect on the retention of viruses by the membrane. These results indicate that irremovable membrane fouling may affect the removal efficiency of MBRs and, therefore, their capacity to ensure the required microbiological standards for the permeate achieved.

Nitrogen removal from landfill leachate using the SBR technology

Landfill leachate is a concern in the wastewater field due to its toxicity, high ammonium and low biodegradable organic matter concentrations. The aim of this paper is to study the reliability of landfill leachate treatment using Sequencing Batch Reactor (SBR) technology for biological nitrogen removal. During the study the SBR pilot plant treated successfully 0.48 kg N·m−3 d−1 of urban landfill leachate. Furthermore, high nitrogen removal efficiencies (80%, on average) have been achieved by the operational conditions applied (step‐feed strategy and alternating anoxic‐aerobic conditions).

Towards integrated operation of membrane bioreactors: effects of aeration on biological and filtration performance.

Two experimental studies evaluated the effect of aerobic and membrane aeration changes on sludge properties, biological nutrient removal and filtration processes in a pilot plant membrane bioreactor. The optimal operating conditions were found at an aerobic dissolved oxygen set-point (DO) of 0.5 mg O2 L(-1) and a membrane specific aeration demand (SADm) of 1 m h(-1), where membrane aeration can be used for nitrification. Under these conditions, a total flow reduction of 42% was achieved (75% energy reduction) without compromising nutrient removal efficiencies, maintaining sludge characteristics and controlled filtration. Below these optimal operating conditions, the nutrient removal efficiency was reduced, increasing 20% for soluble microbial products, 14% for capillarity suction time and reducing a 15% for filterability. Below this DO set-point, fouling increased with a transmembrane pressure 75% higher. SADm below 1 m h(-1) doubled the values of transmembrane pressure, without recovery after achieving the initial conditions.

Criticality of flux and aeration for a hollow fiber membrane bioreactor

A three-element microfiltration (MF) hollow fiber (HF) membrane module has been evaluated for treating municipal wastewater by an immersed membrane bioreactor (iMBR) based on a pilot-scale plant. The flux-step method, classically used to identify the critical flux, was compared with an aeration-step method conducted at the identified critical flux of 14.5 l m−2 h−1. It was found that the permeability of the central element was found to be higher, since the air stream imparted to the end elements was dissipated because there is no channel formed by the proximity of the neighboring elements. The aeration-step trials revealed the critical specific aeration demand for both intermittent and continuous aeration regimes to be lower than that applied to the critical flux-step experiments. This implies that the operating conditions identified for critical flux-step experiment are over conservative, corroborating results from previous reports, and that aeration stepping presents a more representative method for identifying sustainable operating conditions.

Knowledge-based control module for start-up of flat sheet MBRs

In start-up periods low MLSS concentration may lead to fouling phenomena and uncommon frequency of chemical cleanings using membrane bioreactors. A knowledge-based control module for the optimisation of start-up procedures in membrane bioreactors is presented and validated in this paper. The main objective of the control module is to accelerate the growth of MLSS and the achievement of the design flux while minimising the fouling phenomenon during start-up periods. The module was validated in a pilot-scale membrane bioreactor with the University of Cape Town configuration and submerged flat sheet microfiltration membranes. The knowledge of the control system was represented as a decision tree before being implemented. A fully satisfactory start-up, both for the filtration and the biological phase, was obtained in 20 days, saving time and preserving the membrane integrity.

Effect of cycle changes on simultaneous biological nutrient removal in a sequencing batch reactor (SBR)

The destabilization of a microbial population is sometimes hard to solve when different biological reactions are coupled in the same reactor as in sequencing batch reactors (SBRs). This paper will try to guide through practical experiences the recovery of simultaneous nitrogen and phosphorus removal in an SBR after increasing the demand of wastewater treatment by taking advantage of its flexibility. The results demonstrate that the length of phases and the optimization of influent distribution are key factors in stabilizing the system for long‐term periods with high nutrient removal (88%, 93% and 99% of carbon, nitrogen and phosphorus, respectively). In order to recover a biological nutrient removal (BNR) system, different interactions such as simultaneous nitrification and denitrification and also phosphorus removal must be taken into account. As a general conclusion, it can be stated there is no such thing as a perfect SBR operation, and that much will depend on the state of the BNR system. Hence, the SBR operating strategy must be based on a dynamic cycle definition in line with process efficiency.

Optimizing chemical conditioning for odour removal of undigested sewage sludge in drying processes

Emission of odours during the thermal drying in sludge handling processes is one of the main sources of odour problems in wastewater treatment plants. The objective of this work was to assess the use of the response surface methodology as a technique to optimize the chemical conditioning process of undigested sewage sludges, in order to improve the dewaterability, and to reduce the odour emissions during the thermal drying of the sludge. Synergistic effects between inorganic conditioners (iron chloride and calcium oxide) were observed in terms of sulphur emissions and odour reduction. The developed quadratic models indicated that optimizing the conditioners dosage is possible to increase a 70% the dewaterability, reducing a 50% and 54% the emission of odour and volatile sulphur compounds respectively. The optimization of the conditioning process was validated experimentally.

On-line estimation of suspended solids in biological reactors of WWTPs using a Kalman observer

The total amount of solids in Wastewater Treatment Plants (WWTPs) and their distribution among the different elements and lines play a crucial role in the stability, performance and operational costs of the process. However, an accurate prediction of the evolution of solids concentration in the different elements of a WWTP is not a straightforward task. This paper presents the design, development and validation of a generic Kalman observer for the on-line estimation of solids concentration in the tank reactors of WWTPs. The proposed observer is based on the fact that the information about the evolution of the total amount of solids in the plant can be supplied by the available on-line Suspended Solids (SS) analysers, while their distribution can be simultaneously estimated from the hydraulic pattern of the plant. The proposed observer has been applied to the on-line estimation of SS in the reactors of a pilot-scale Membrane Bio-Reactor (MBR). The results obtained have shown that the experimental information supplied by a sole on-line SS analyser located in the first reactor of the pilot plant, in combination with updated information about internal flow rates data, has been able to give a reasonable estimation of the evolution of the SS concentration in all the tanks.

Fate of NDMA precursors through an MBR-NF pilot plant for urban wastewater reclamation and the effect of changing aeration conditions.

The removal of N-nitrosodimethylamine (NDMA) formation potential through a membrane bioreactor (MBR) coupled to a nanofiltration (NF) pilot plant that treats urban wastewater is investigated. The results are compared to the fate of the individual NDMA precursors detected: azithromycin, citalopram, erythromycin, clarithromycin, ranitidine, venlafaxine and its metabolite o-desmethylvenlafaxine. Specifically, the effect of dissolved oxygen in the aerobic chamber of the MBR pilot plant on the removal of NDMA formation potential (FP) and individual precursors is studied. During normal aerobic operation, implying a fully nitrifying system, the MBR was able to reduce NDMA precursors above 94%, however this removal percentage was reduced to values as low as 72% when changing the conditions to minimize nitrification. Removal decreased also for azithromycin (68-59%), citalopram (31-17%), venlafaxine (35-15%) and erythromycin (61-16%) on average during nitrifying versus non-nitrifying conditions. The removal of clarithromycin, o-desmethylvenlafaxine and ranitidine could not be correlated with the nitrification inhibition, as it varied greatly during the experiment time. The MBR pilot plant is coupled to a nanofiltration (NF) system and the results on the rejection of both, NDMA FP and individual precursors, through this system was above 90%. Finally, results obtained for the MBR pilot plant are compared to the percentage of removal by a conventional full scale biological wastewater treatment plant (WWTP) fed with the same influent. During aerobic operation, the removal of NDMA FP by the MBR pilot plant was similar to the full scale WWTP.