Hideto Yanagihara
University of Tsukuba
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Featured researches published by Hideto Yanagihara.
Journal of Physics D | 2010
Eiji Kita; Tatsuya Oda; Takeru Kayano; Suguru Sato; Makoto Minagawa; Hideto Yanagihara; Mikio Kishimoto; Chiharu Mitsumata; Shinji Hashimoto; Keiichi Yamada; Nobuhiro Ohkohchi
The use of ferromagnetic nanoparticles for hyperthermia and thermoablation therapies has shown great promise in the field of nanobiomedicine. Even local hyperthermia offers numerous advantages as a novel cancer therapy; however, it requires a remarkably high heating power of more than 1 kW g−1 for heat agents. As a candidate for high heat generation, we focus on ferromagnetic nanoparticles and compare their physical properties with those of superparamagnetic substances. Numerical simulations for ideal single-domain ferromagnetic nanoparticles with cubic and uniaxial magnetic symmetries were carried out and MH curves together with minor loops were obtained. From the simulation, the efficient use of an alternating magnetic field (AMF) having a limited amplitude was discussed. Co-ferrite nanoparticles with various magnitudes of coercive force were produced by co-precipitation and a hydrothermal process. A maximum specific loss power of 420 W g−1 was obtained using an AMF at 117 kHz with H0 = 51.4 kA m−1 (640 Oe). The relaxation behaviour in the ferromagnetic state below the superparamagnetic blocking temperature was examined by Mossbauer spectroscopy.
IEEE Transactions on Magnetics | 2015
A. Hirohata; Hiroaki Sukegawa; Hideto Yanagihara; Igor Zutic; Takeshi Seki; Shigemi Mizukami; Rajasekaran Swaminathan
The Technical Committee of the IEEE Magnetics Society has selected seven research topics to develop their roadmaps, where major developments should be listed alongside expected timelines: 1) hard disk drives; 2) magnetic random access memories; 3) domain-wall devices; 4) permanent magnets; 5) sensors and actuators; 6) magnetic materials; and 7) organic devices. Among them, magnetic materials for spintronic devices have been surveyed as the first exercise. In this roadmap exercise, we have targeted magnetic tunnel and spin-valve junctions as spintronic devices. These can be used, for example, as a cell for a magnetic random access memory and a spin-torque oscillator in their vertical form as well as a spin transistor and a spin Hall device in their lateral form. In these devices, the critical role of magnetic materials is to inject spin-polarized electrons efficiently into a nonmagnet. We have accordingly identified two key properties to be achieved by developing new magnetic materials for future spintronic devices: 1) half-metallicity at room temperature (RT) and 2) perpendicular anisotropy in nanoscale devices at RT. For the first property, five major magnetic materials are selected for their evaluation for future magnetic/spintronic device applications: 1) Heusler alloys; 2) ferrites; 3) rutiles; 4) perovskites; and 5) dilute magnetic semiconductors. These alloys have been reported or predicted to be half-metallic ferromagnets at RT. They possess a bandgap at the Fermi level EF only for its minority spins, achieving 100% spin polarization at EF. We have also evaluated L10 alloys and D022-Mn alloys for the development of a perpendicularly anisotropic ferromagnet with large spin polarization. We have listed several key milestones for each material on their functionality improvements, property achievements, device implementations, and interdisciplinary applications within 35 years time scale. The individual analyses and the projections are discussed in the following sections.
Applied Physics Letters | 2013
Tomohiko Niizeki; Yuji Utsumi; Ryohei Aoyama; Hideto Yanagihara; Jun-ichiro Inoue; Yuichi Yamasaki; Hironori Nakao; Kazuyuki Koike; Eiji Kita
Perpendicular magnetic anisotropy (PMA) of cobalt-ferrite CoxFe3-xO4 (x = 0.75 and 1.0) epitaxial thin films grown on MgO (001) by a reactive magnetron sputtering technique was investigated. The saturation magnetization was found to be 430 emu/cm3 for x = 0.75, which is comparable to that of bulk CoFe2O4 (425 emu/cm3). Torque measurements afforded PMA constants of Kueff=9.0 Merg/cm3 (Ku=10.0 Merg/cm3) and Kueff=9.7 Merg/cm3 for x = 0.75 and 1.0, respectively. The value of Kueff extrapolated using Miyajimas plot was as high as 14.7 Merg/cm3 for x = 1.0. The in-plane four-fold magnetic anisotropy was evaluated to be 1.6 Merg/cm3 for x = 0.75. X-ray diffraction measurement revealed our films to be pseudomorphically strained on MgO (001) with a Poisson ratio of 0.4, leading to a considerable in-plane tensile strain by which the extraordinarily large PMA could be accounted for.
Journal of the Physical Society of Japan | 2006
Hideto Yanagihara; Manabu Hasegawa; Eiji Kita; Yusuke Wakabayashi; Hiroshi Sawa; Kiiti Siratori
We report the structural characterization and transport properties of highly-ordered epitaxial γ-Fe 2 O 3 thin films grown by a pure ozone-assisted molecular beam epitaxy method. X ray diffraction ...
Journal of Applied Physics | 2010
Eiji Kita; Shinji Hashimoto; Takeru Kayano; Makoto Minagawa; Hideto Yanagihara; Mikio Kishimoto; Keiichi Yamada; Tatsuya Oda; Nobuhiro Ohkohchi; Toshiyuki Takagi; Toshiyuki Kanamori; Yoshio Ikehata; Isamu Nagano
Heating characteristics of Fe oxide nanoparticles designed for hyperthermia were examined. Samples with coercive forces from 50 to 280 Oe(codoped magnetite) were produced with a coprecipitation technique following by hydrothermal reaction. The maximum specific loss powers (SLPs) of 420 W/g was obtained at 117 kHz (640 Oe) for a dispersant sample with coercive force of 280 Oe (ATH9D). SLPs measured on dry powder samples at 17 kHz and measured at 117 kHz on dispersant samples were compared. The measured SLP amplitudes are lower for 17 kHz and higher for 117 kHz than those expected from ferromagnetic dc minor loops. For the 117 kHz case, friction of particles in a carrier fluid (similar mechanism to Brown relaxation in superparamagnetic dispersant samples) is considered to contribute to the heating mechanism.
Journal of Physics D | 2013
Hideto Yanagihara; M Myoka; D Isaka; Tomohiko Niizeki; Ko Mibu; Eiji Kita
A selective method for growing high-quality spinel-type epitaxial Fe3O4(0 0 1) or γ-Fe2O3(0 0 1) films was developed using conventional planar-type sputtering by controlling the flow rate of oxygen gas . Although magnetization of the oxide films is close to that of Fe3O4 or γ-Fe2O3 for all , the room-temperature resistivity and the Fe3+ and Fe2.5+ composition ratios of the films are dependent on . The films for and are identified as Fe3O4 and γ-Fe2O3 films, respectively. All the results suggest that Fe3O4 films are obtained only when sputtered in the metal mode, and γ-Fe2O3 films are obtained in the oxide mode.
Journal of Applied Physics | 2011
Hideto Yanagihara; K. Uwabo; Makoto Minagawa; Eiji Kita; Noriyuki Hirota
We report on the magnetic properties of epitaxial cobalt-ferrite films with orientations parallel to [001] and [111] grown by a reactive molecular beam epitaxy method using pure ozone gas as an oxidation agent. Both Mossbauer spectroscopy and magnetization measurement of the CoFe2O4(001) film grown on MgO(001) indicate that the film has perpendicular magnetic anisotropy (PMA) with high coercivity, whereas the film of CoFe2O4(111) grown on α-Al2O3(0001) appears to be paramagnetic. The maximum uniaxial anisotropy energy for CoFe2O4(001) estimated from the magnetization and coercivity at room temperature is ≈3×106 erg/cm3.
Colloids and Surfaces B: Biointerfaces | 2011
Kodai Ujiie; Naoki Kanayama; Kei Asai; Mikio Kishimoto; Yusuke Ohara; Yoshimasa Akashi; Keiichi Yamada; Shinji Hashimoto; Tatsuya Oda; Nobuhiro Ohkohchi; Hideto Yanagihara; Eiji Kita; Masayuki Yamaguchi; Hirofumi Fujii; Yukio Nagasaki
This paper describes the preparation of iron oxide nanoparticles, surface of which was coated with extremely high immobilization stability and relatively higher density of poly(ethylene glycol) (PEG), which are referred to as PEG protected iron oxide nanoparticles (PEG-PIONs). The PEG-PIONs were obtained through alkali coprecipitation of iron salts in the presence of the PEG-poly(4-vinylbenzylphosphonate) block copolymer (PEG-b-PVBP). In this system, PEG-b-PVBP served as a surface coating that was bound to the iron oxide surface via multipoint anchoring of the phosphonate groups in the PVBP segment of PEG-b-PVBP. The binding of PEG-b-PVBP onto the iron oxide nanoparticle surface and the subsequent formation of a PEG brush layer were proved by FT-IR, zeta potential, and thermogravimetric measurements. The surface PEG-chain density of the PEG-PIONs varied depending on the [PEG-b-PVBP]/[iron salts] feed-weight ratio in the coprecipitation reaction. PEG-PIONs prepared at an optimal feed-weight ratio in this study showed a high surface PEG-chain surface density (≈0.8 chainsnm(-2)) and small hydrodynamic diameter (<50 nm). Furthermore, these PEG-PIONs could be dispersed in phosphate-buffered saline (PBS) that contains 10% serum without any change in their hydrodynamic diameters over a period of one week, indicating that PEG-PIONs would provide high dispersion stability under in vivo physiological conditions as well as excellent anti-biofouling properties. In fact we have confirmed the prolong blood circulation time and facilitate tumor accumulation (more than 15% IDg(-1) tumor) of PEG-PIONs without the aid of any target ligand in mouse tumor models. The majority of the PEG-PIONs accumulated in the tumor by 96 h after administration, whereas those in normal tissues were smoothly eliminated by 96 h, proving the enhancement of tumor selectivity in the PEG-PION localization. The results obtained here strongly suggest that originally synthesized PEG-b-PVBP, having multipoint anchoring character by the phosphonate groups, is rational design for improvement in nanoparticle as in vivo application. Two major points, viz., extremely stable anchoring character and dense PEG chains tethered on the nanoparticle surface, worked simultaneously to become PEG-PIONs as an ideal biomedical devices intact for prolonged periods in harsh biological environments.
IEEE Transactions on Magnetics | 2008
Eiji Kita; Hideto Yanagihara; Shinji Hashimoto; Keiichi Yamada; Tatsuya Oda; Mikio Kishimoto; Akira Tasaki
We have fabricated ferromagnetic Fe-oxide nanoparticles as a candidate of hysteresis-loss heating materials used for hyperthermia and thermoablation and examined heating abilities. The coercivities were controlled in a range between 50 Oe and 240 Oe. The temperature-rising characteristics were examined for randomly oriented solid nanoparticles by applying a 17-kHz ac magnetic field with an amplitude up to 550 Oe. A temperature rising rate DeltaT/Deltat was proportional to the square of the peak magnetic field H 0 in the lower H 0 region; however, the relation dose not hold at higher H 0. The maximum loss power was obtained to be 4 W/g, which is smaller than the value expected from the minor loop experiment (13.7 W/g). The reason for small heating capability is discussed.
AIP Advances | 2015
Tomohiko Niizeki; Takashi Kikkawa; Ken-ichi Uchida; Mineto Oka; Kazuya Z. Suzuki; Hideto Yanagihara; Eiji Kita; Eiji Saitoh
The longitudinal spin-Seebeck effect (LSSE) has been investigated in cobalt ferrite (CFO), an exceptionally hard magnetic spinel ferrite. A bilayer of a polycrystalline Pt and an epitaxially-strained CFO(110) exhibiting an in-plane uniaxial anisotropy was prepared by reactive rf sputtering technique. Thermally generated spin voltage in the CFO layer was measured via the inverse spin-Hall effect in the Pt layer. External-magnetic-field (H) dependence of the LSSE voltage (VLSSE) in the Pt/CFO(110) sample with H ∥ [001] was found to exhibit a hysteresis loop with a high squareness ratio and high coercivity, while that with H∥[110] shows a nearly closed loop, reflecting the different anisotropies induced by the epitaxial strain. The magnitude of VLSSE has a linear relationship with the temperature difference (ΔT), giving the relatively large VLSSE /ΔT of about 3 μV/K for CFO(110) which was kept even at zero external field.