Howard Herzig

Reflectance and durability of Ag mirrors coated with thin layers of Al 2 O 3 plus reactively deposited silicon oxide

A technique for producing adherent and well-protected front surface Ag mirrors with an evaporated Al(2)O(3) + SiO(x) overcoat and an evaporated Al(2)O(3) underlayer is described. A thin Al(2)O(3) layer promotes adhesion between the Ag film and its substrate. The optimum thickness of each outer layer necessary to give good adhesion and protection to the Ag surface with minimal loss in reflectance due to ir absorption was found to be about 300 A for the Al(2)O(3) layer and between 1000 A and 2000 A for the SiO(x) film. Ag surfaces coated in this fashion retained a normal incidence reflectance in excess of 95% over the wavelength region from 450 nm to the far ir, even when exposed to harsh sulfide and humidity environments. Calculations demonstrate the advantage of using protected front surface Ag in comparison to more durable metal reflectors, such as Al or Rh, in terms of high reflectance and low visible region polarization. However, a very pronouncedrestrahlen reflectance and absorption effect in the thicker SiO(x) film is responsible for a calculated drop in reflectance from 98.5% to about 65% at lambda = 8.1 mum and 45 degrees incidence for the Ag + Al(2)O(3) + SiO(x) coating.

Normal incidence reflectance of ion beam deposited SiC films in the EUV

Results are presented from an experimental investigation of the normal-incidence reflectance at 58.4, 92.0, and 121.6 nm wavelength of 30- and 80-nm-thick SiC films produced by ion-beam deposition on unheated 5 x 5-cm microscope slides. The films were deposited in the 2-m evaporator described by Bradford et al. (1969) with chamber base pressure 1 microtorr, operating pressure 40 microtorr, and a 50-62-mA 750-eV Ar ion beam; the reflectance measurements were obtained in the reflector-monochromator system described by Osantowski (1974). Reflectances of over 30 percent were found at 92 and 121.6 nm, almost equal to those of polished CVD films of SiC and degrading only slightly after aging for 4 months. It is suggested that ion-beam deposition may be the best low-temperature technique for coating EUV optics for space astronomy.

Long-duration orbital effects on optical coating materials

We flew specimens of eight different optical coating materials in low earth orbit as part of the Long Duration Exposure Facility manifest to determine their ability to withstand exposure to the residual atomic O and other environmental effects at those altitudes. We included samples of Al, Au, Ir, Os, Pt, Al + MgF(2), Al + SiO(x), and chemical-vapor-deposited SiC, representing reflective optical applications from the vacuum ultraviolet through the visible portions of the spectrum. We found that the majority of the materials suffered sufficient reflectance degradation to warrant careful consideration in the design of future space-flight instrumentation.

Optical coating technology for the EUV

Abstract Advances in optical coating and materials technology have been one of the key motivators for the development of missions such as the Far Ultraviolet Spectroscopic Explorer recently selected by NASA for an Explorer class mission in the mid 1990s. We review the performance of a range of candidate coatings for normal incidence and glancing incidence applications, and discuss strengths and problem areas for their use in space. The importance of recent developments in multilayer films, chemical vapor deposited SiC (CVD-SiC) mirrors, and SiC films are discussed in the context of EUV instrumentation design. For example, the choice of optical coatings is a design driver for the selection of the average glancing angle for the FUSE telescope, and impacts efficiency, short wavelength cut-off, and physical size.

Low earth orbit environmental effects on osmium and related optical thin-film coatings

A number of samples of optical thin film materials were flown on Shuttle flight STS-8 as part of an experiment to evaluate their interaction with residual atomic oxygen in low earth orbit. Osmium was selected because of its usefulness as a reflective optical coating for far-UV instruments and for confirmation of results from previous Shuttle flights in which such coatings disappeared. Reflectance data and photographic evidence are presented to support the hypothesis that the osmium disappearance is due to reaction with oxygen to form a volatile oxide. Platinum and iridium, which were included for comparison, fared much better.

Auger spectroscopic examination of MgF 2 -coated Al mirrors before and after uv irradiation

Freshly prepared samples of evaporated Al + 250 A of MgF(2) on glass were subjected to analysis by Auger electron spectroscopy coupled with surface erosion by Ar+ ion bombardment before and after uv irradiation. The analysis identified C and 0 on the mirror surfaces prior to irradiation and the addition of Si after uv irradiation in vacuum. The relative amounts of photolyzed surface contaminants were proportional to the observed decrease in mirror reflectance at 1216 A. The Auger analysis confirmed that a very thin layer of surface contamination and not bulk photolysis in the MgF(2) film was responsible for the irradiation induced reflectance loss.

Effects of Space Shuttle flight on the reflectance characteristics of diffusers in the near-infrared, visible, and ultraviolet regions

Many remote sensing instruments employ diffuse targets for calibration. These targets usually consist of diftusers with high Lambertian characteristics illuminated by a calibrated irradiance source. There is increasing interest in conducting in-orbit radiance calibration checks of remote sensing instruments using sunlight reflected off a diffuser. We report on the effects of space flight on the reflectance properties of polytetrafluoroethylene (PTFE) and aluminum diffuser samples flown on three Space Shuttle flights. These experiments showed good stability of both diffuser types in the visible and near infrared but experienced measurable degradation in the ultraviolet. Degradation varied from flight to flight and seemed to be related to different levels of contamination experienced on the three flights.

Variability in the vacuum-ultraviolet transmittance of magnesium fluoride windows

In the course of the development of a domed magnesium fluoride detector window for the Space Telescope Imaging Spectrograph, slated to be a second-generation instrument aboard the Hubble Space Telescope, sample window materials from various commercial sources displayed a wide variability in vacuum ultraviolet transmittance. As a result a test program was undertaken in cooperation with the supplier of a prototype domed window to maximize transmittance. Results of the program have provided clues to the causes of the variations experienced, and they point to careful selection of raw materials and strict process control to achieve optimization.

Broadband reflectance coatings for vacuum ultraviolet application

An experimental investigation has obtained results indicating that neither LaF3 nor LiYF4 are acceptable alternatives to MgF2 as coatings for vacuum-deposited aluminum mirrors from which high UV reflectance down to 1150 A is required. Nevertheless, LaF3 may prove useful in those specialized applications in which the suppression of lower wavelength emissions, such as the 1216-A hydrogen line, is desirable.

Vacuum deposition of iridium on large astronomical mirrors for use in the far UV.

An iridium coating has been deposited by electron-beam evaporation on a 0.91-m mirror which serves as the telescope primary of a sounding rocket instrument for far-UV spectrometry. The evaporation was carried out by applying 8 kV at 400 mA to the electron gun. Zone refined Ir of 99.99% purity was used, and the electron beam was electromagnetically swept over the surface of the evaporant. Under these conditions, deposition rates of 0.55 A/sec were achieved. The reflectance distribution achieved at a wavelength of 584 A was extremely uniform; the mean reflectance was 21.2% with a standard deviation of only 0.3%. This represents a substantial improvement over Al + MgF2 and Al + LiF coatings for applications involving multiple reflections and weak signals, as might be expected in a high-resolution spectrograph studying distant celestial objects.