Ibon Santiago

Strongly interacting isotopic Bose-Fermi mixture immersed in a Fermi sea

We have created a triply quantum-degenerate mixture of bosonic {sup 41}K and two fermionic species {sup 40}K and {sup 6}Li. The boson is shown to be an efficient coolant for the two fermions, spurring hopes for the observation of fermionic superfluids with imbalanced masses. We observe multiple heteronuclear Feshbach resonances, in particular a wide s-wave resonance for the combination {sup 41}K-{sup 40}K, opening up studies of strongly interacting isotopic Bose-Fermi mixtures. For large imbalance in the local densities of different species, we enter the polaronic regime of dressed impurities immersed in a bosonic or fermionic bath.

Quantum degenerate Bose-Fermi mixture of chemically different atomic species with widely tunable interactions

We have created a quantum degenerate Bose-Fermi mixture of 23Na and 40K with widely tunable interactions via broad interspecies Feshbach resonances. Twenty Feshbach resonances between 23Na and 40K were identified. The large and negative triplet background scattering length between 23Na and 40K causes a sharp enhancement of the fermion density in the presence of a Bose condensate. As explained via the asymptotic bound-state model (ABM), this strong background scattering leads to a series of wide Feshbach resonances observed at low magnetic fields. Our work opens up the prospect to create chemically stable, fermionic ground state molecules of 23Na-40K where strong, long-range dipolar interactions will set the dominant energy scale.

Nanocarbon and nanodiamond for high performance phenolics sensing

Phenolic compounds are pollutants of major concern, and effective monitoring is essential to reduce exposure. Electrochemical sensors offer rapid and accurate detection of phenols but suffer from two main shortcomings preventing their widespread use: electrode fouling and signal interference from co-existing isomers. Here we demonstrate a potential solution based on environmentally friendly and biocompatible carbon nanomaterials to detect monophenols (phenol and cresol) and biphenols (hydroquinone and catechol). Electrode fouling is tackled in two ways: by introducing electrochemically resistant nanodiamond electrodes and by developing single-use nanocarbon electrodes. We provide a comprehensive analysis of the electrochemical performance of three distinct carbon materials (graphene, nanodiamond and nanocarbon). Nanocarbon exhibits the lowest detection limit below 10−8 M, and one order of magnitude higher sensitivity than the other carbon nanomaterials. We detect co-existing phenol isomers with nanocarbon electrodes and apply it in river water and green tea samples, which may pave the way towards low-cost industrial scale monitoring of phenolic compounds.Carbon materials, in particular graphene-like materials, are well studied as electrochemical phenol sensors. Here, the authors fabricate nanodiamond and amorphous nanocarbon-modified electrodes and assess their sensitivity and durability for phenol compound sensing applications.