Ikuhisa Hamada

The state-of-the-art technology of NOx control

Abstract The TiO 2 -based DeNO x catalyst which is now commercially implemented world-wide is described, emphasizing the importance of the resistance to SO x -poisoning and plugging by particulates. Various NO x reduction technologies are compared and recent trends in catalytic DeNO x installations in Japan are reviewed. For wider applications and to meet the stringent emission requirements, newly developed DeNO x catalysts such as for high-temperature gas turbine exhaust and for simultaneous removal of NO x and CO are also introduced.

A Catalyzed Hydrocarbon Trap Using Metal-impregnated Zeolite for SULEV systems

A catalyzed hydrocarbon (HC) trap aiming at the super-ultra low emission vehicle (SULEV) regulation was developed using a metal-impregnated zeolite. To enhance the adsorption and to raise the desorption temperature for awide range of HC species, the modification of zeolite with certain metals was needed and Ag was found to be the most promising. Using a Ag impregnated zeolite, a three way catalyst was prepared, and its HC purification ability for a model gas simulating cold-start HCs was studied. Its heat resistance was also examined. A vehicle test for a fresh catalyzed HC trap showed that the cold-start HC after the newly developed trap almost reached the SULEV regulation level.

Intergranular stress corrosion cracking behavior of niobium-added Type 308 stainless steel weld overlay metal in a simulated BWR environment

Type 308 stainless steel weld metal as an internal cladding of reactor pressure vessels for boiling water reactors is subject to postweld heat treatment during fabrication and can suffer sensitization depending on carbon and ferrite contents. This sensitization can be avoided by using niobium-added Type 308 weld metal (specified as Type 308 NbL) which was developed for one-layer overlay welding application. In the present study, stress corrosion cracking (SCC) behavior of heat-treated Types 308 and 308NbL weld metals in oxygenated high temperature pure water was evaluated by slow strain rate test and U-bend tests with and without crevice. Every test showed that Type 308NbL weld metals were highly resistant to SCC compared to ordinary Type 308 weld metals. In single U-bend test, one-layer overlay weld metals of Type 308NbL produced by electroslag welding process using wide strip electrodes were crack free over 23,000 h. The U-bend test data of ordinary Type 308 weld metals were successfully analyzed by an SCC reaction model. Using this analysis, the SCC life margin for Type 308NbL over ordinary Type 308 weld metals, expressed as a ratio of respective times to SCC initiation, was estimated to be about 36.