Isabelle Cherchneff

The Chemistry of Population III Supernova Ejecta. II. The Nucleation of Molecular Clusters as a Diagnostic for Dust in the Early Universe

We study the formation of molecular precursors to dust in the ejecta of Population III supernovae (Pop. III SNe) using a chemical kinetic approach to follow the evolution of small dust cluster abundances from day 100 to day 1000 after explosion. Our work focuses on zero-metallicity 20 M sun and 170 M sun progenitors, and we consider fully macroscopically mixed and unmixed ejecta. The dust precursors comprise molecular chains, rings, and small clusters of chemical composition relevant to the initial elemental composition of the ejecta under study. The nucleation stage for small silica, metal oxides and sulfides, pure metal, and carbon clusters is described with a new chemical reaction network highly relevant to the kinetic description of dust formation in hot circumstellar environments. We consider the effect of the pressure dependence of critical nucleation rates and test the impact of microscopically mixed He + on carbon dust formation. Two cases of metal depletion on silica clusters (full and no depletion) are considered to derive upper limits to the amounts of dust produced in SN ejecta at 1000 days, while the chemical composition of clusters gives a prescription for the type of dust formed in Pop. III SNe. We show that the cluster mass produced in the fully mixed ejecta of a 170 M sun progenitor is ~ 25 M sun whereas its 20 M sun counterpart forms ~ 0.16 M sun of clusters. The unmixed ejecta of a 170 M sun progenitor SN synthesize ~5.6 M sun of small clusters, while its 20 M sun counterpart produces ~0.103 M sun . Our results point to smaller amounts of dust formed in the ejecta of Pop. III SNe by a factor of ~ 5 compared to values derived by previous studies, and to different dust chemical compositions. Such deviations result from some erroneous assumptions made, the inappropriate use of classical nucleation theory to model dust formation, and the omission of the synthesis of molecules in SN ejecta. We also find that the unmixed ejecta of massive Pop. III SNe chiefly form silica and/or silicates, and pure silicon grains whereas their lower mass counterparts form a dust mixture dominated by silica and/or silicates, pure silicon, and iron sulfides. Amorphous carbon can only condense via the nucleation of carbon chains and rings characteristic of the synthesis of fullerenes when the ejecta carbon-rich zone is deprived of He + . The first dust enrichment to the primordial gas in the early universe from Pop. III massive SN comprises primarily pure silicon, silica, and silicates. If carbon dust is present at redshift z > 6, alternative dust sources must be considered.

THE ORIGIN OF DUST IN THE EARLY UNIVERSE: PROBING THE STAR FORMATION HISTORY OF GALAXIES BY THEIR DUST CONTENT

In this talk I will describe the origin of dust in the early universe. I will be presenting observations of the spectral energy distribution of the galaxy J1148+5251, and present estimates of the dust mass in this high redshift (z=6.4) object. I will then discuss the origin of this dust, and the role of SN and AGB stars as dust sources, and the effect of SNRs on the destruction of dust in the interstellar medium of this galaxy.

The Chemistry of Population III Supernova Ejecta. I. Formation of Molecules in the Early Universe

We study the formation and destruction of molecules in the ejecta of Population III supernovae (SNe) using a chemical kinetic approach to follow the evolution of molecular abundances from day 100 to day 1000 after explosion. The chemical species included range from simple di-atomic molecules to more complex dust precursor species. All relevant chemical processes that are unique to the SN environment are considered. Our work focuses on zero-metallicity progenitors with masses of 20, 170, and 270 Msun, and we study the effect of different levels of heavy element mixing and the inward diffusion of hydrogen on the ejecta chemistry. We show that the ejecta chemistry does not reach a steady state within the relevant time-span for molecule formation. The primary species formed are O2, CO, SiS, and SO. The SiO, formed as early as 200 days after explosion, is rapidly depleted by the formation of silica molecular precursors in the ejecta. The rapid conversion of CO to C2 and its thermal fractionation at temperatures above 5000 K allow for the formation of carbon chains in the oxygen-rich zone of the unmixed models, providing an important pathway for the formation of carbon dust in hot environments where the C/O ratio is less than 1. We show that the fully-mixed ejecta of a 170 Msun progenitor synthesizes 11.3 Mun of molecules whereas 20 Msun and 270 Msun progenitors produce 0.78, and 3.2 Msun of molecules, respectively. The admixing of 10 % of hydrogen into the fully-mixed ejecta of the 170 Msun progenitor increases its molecular yield to ~ 47Msun. The unmixed ejecta of a 170 Msun progenitor supernova without hydrogen penetration synthesizes ~37 Msun of molecules, whereas its 20 Msun counterpart produces ~ 1.2 Msun. Finally, we discuss the cosmological implication of molecule formation by Pop. III SNe in the early universe.

The formation of cyanopolyyne molecules in IRC + 10216

Molecule formation in the outer envelope of the carbon-rich star IRC + 10216 is investigated, with special emphasis on the chemistry of the cyanopolyynes HC(i)N (i = 3, 5, 7). Basic elements of the photochemical model of Glassgold et al. (1986) are revised. A dust model suitable to IRC + 10216 is used for which the extinction properties in the far-UV are those of 500 A amorphous carbon particles. A new chemical route to the formation of large cyanopolyynes is proposed, based on reactions of the radicals C3N and C5N with acetylene, and shown to be efficient. Our results agree qualitatively with observations of the spatial distributions of HCN, CN, HC3N, and C3N, but the calculated column densities of the higher-order cyanopolyynes appear to be too small. The amount of the allenic radical HC2N produced by molecular ion reactions with atomic N agrees with recent observations.

The formation of carbon chain molecules in IRC +10216

A schematic model for the synthesis of chain molecules (both cyanopolyynes and polyacetylenes) is developed for the C-rich AGB star IRC +10216. The key processes are neutral reactions of photoproduced CN and C 2 H radicals with acetylene and other hydrocarbons, shown to be fast in recent low-temperature laboratory experiments. Abundance calculations based on our photochemical model of the envelope demonstrate that the chains are efficiently produced in the outer circumstellar envelope, in accord with abundance distributions deduced from maps made at millimeter wavelengths. The results extend the scope of the photochemical model to an important class of species observed in the envelope of IRC +10216

The inner wind of IRC+10216 revisited: new exotic chemistry and diagnostic for dust condensation in carbon stars

Aims: We model the chemistry of the inner wind of the carbon star IRC+10216 and consider the effects of periodic shocks induced by the stellar pulsation on the gas to follow the non-equilibrium chemistry in the shocked gas layers. We consider a very complete set of chemical families, including hydrocarbons and aromatics, hydrides, halogens, and phosphorous-bearing species. Our derived abundances are compared to those for the latest observational data from large surveys and the Herschel telescope. Methods: A semi-analytical formalism based on parameterised fluid equations is used to describe the gas density, velocity, and temperature from 1 R ⋆ to 5 R ⋆ . The chemistry is described using a chemical kinetic network of reactions and a set of stiff, ordinary, coupled differential equations is solved. Results: The shocks induce an active non-equilibrium chemistry in the dust formation zone of IRC+10216 where the collision destruction of CO in the post-shock gas triggers the formation of O-bearing species such as H 2 O and SiO. Most of the modelled molecular abundances agree very well with the latest values derived from Herschel data on IRC+10216. The hydrides form a family of abundant species that are expelled into the intermediate envelope. In particular, HF traps all the atomic fluorine in the dust formation zone. The halogens are also abundant and their chemistry is independent of the C/O ratio of the star. Therefore, HCl and other Cl-bearing species should also be present in the inner wind of O-rich AGB or supergiant stars. We identify a specific region ranging from 2.5 R ⋆ to 4 R ⋆ , where polycyclic aromatic hydrocarbons form and grow. The estimated carbon dust-to-gas mass ratio derived from the mass of aromatics formed ranges from 1.2 × 10 -3 to 5.8 × 10 -3 and agrees well with existing values deduced from observations. This aromatic formation region is situated outside hot layers where SiC 2 is produced as a bi-product of silicon carbide dust synthesis. The MgS grains can form from the gas phase but in lower quantities than those necessary to reproduce the strength of the 30 μm emission band. Finally, we predict that some molecular lines will show a flux variation with pulsation phase and time (e.g., H 2 O), while other species will not (e.g., CO). These variations merely reflect the non-equilibrium chemistry that destroys and reforms molecules over a pulsation period in the shocked gas of the dust formation zone.

Polycyclic aromatic hydrocarbons and molecular equilibria in carbon-rich stars

Thermal equilibrium (TE) molecular concentrations are computed for several carbon-rich elemental compositions and various total gas pressures. Such calculations may be used to estimate the molecular abundances in a carbon-rich stellar photosphere and its vicinity. The six elements and seventy molecules considered include observed molecules and radicals, polycyclic aromatic hydrocarbons (PAHs) up to the size of coronene, long-chain hydrocarbons, the cyanopolyyne group, and complex ring compounds. The thermodynamic data used are from the recent literature or are estimated. Condensations of graphite, silicon carbide, and quartz are also considered

Condensation of dust in the ejecta of Type II-P supernovae

Aims: We study the production of dust in Type II-P supernova by coupling the gas-phase chemistry to the dust nucleation and condensation phases. We consider two supernova progenitor masses with homogeneous and clumpy ejecta to assess the chemical type and quantity of dust that forms. Grain size distributions are derived as a function of post-explosion time. Methods: The chemistry of the gas phase and the simultaneous formation of dust clusters are described by a chemical network. The formation of key species (CO, SiO) and dust clusters of silicates, alumina, silica, metal carbides and sulphides, pure metals, and amorphous carbon is considered. The master equations describing the chemistry of the nucleation phase are coupled to a dust condensation formalism based on Brownian coagulation. Results: Type II-P supernovae produce dust grains of various chemical compositions and size distributions as a function of time. The grain size distributions gain in complexity with time, are slewed towards large grains, and differ from the usual MRN power-law distribution used for interstellar dust. Gas density enhancements in the form of clumps strongly affect the dust chemical composition and the grain size distributions. Silicates and pure metallic grains are highly dependent on clumpiness. Specifically, clumpy ejecta produce grains over 0.1 micron, and the final dust mass reaches 0.14 Msun. Conversely, carbon and alumina dust masses are controlled by the mass yields of alumina and carbon in the zones where the dust is produced. Several dust components form in the ejecta and the total dust mass gradually builds up over a time span of 3 to 5 years post-outburst. This gradual growth provides a possible explanation for the discrepancy between the small dust masses formed at early post-explosion times and the high dust masses derived from recent observations of supernova remnants.

Infrared emission from a polycyclic aromatic hydrocarbon (PAH) excited by ultraviolet laser

The infrared fluorescence spectrum from the C-H stretch modes of vibrationally excited azulene (C10H8), a PAH was measured in the laboratory. PAHs are candidates as carriers of the unidentified infrared emission bands that are observed in many astronomical objects associated with dust and ultraviolet light. In the present experiment, gas phase azulene was excited with light from a 308 nm pulsed laser, and the infrared emission spectrum was time-resolved and wavelength-resolved. Moreover, the infrared absorption spectrum of gas phase azulene was obtained using an FTIR spectrometer. The laboratory emission spectrum resembles observed infrared emission spectra from the interstellar medium, providing support for the hypothesis that PAHs are the responsible carriers. The azulene C-H stretch emission spectrum is more asymmetric than the absorption spectrum, probably due to anharmonicity of levels higher than nu = 1. 36 refs.

Water in IRC+10216: a genuine formation process by shock-induced chemistry in the inner wind

Context: The presence of water in the wind of the extreme carbon star IRC+10216 has been confirmed by the Herschel telescope. The regions where the high-J H 2 O lines have been detected are close to the star at radii r ≤ 15 R star . Aims: We investigate the formation of water and related molecules in the periodically-shocked inner layers of IRC+10216 where dust also forms and accelerates the wind. Methods: We describe the molecular formation by a chemical kinetic network involving carbon-and oxygen-based molecules. We then apply this network to the physical conditions pertaining to the dust-formation zone which experiences the passage of pulsation-driven shocks between 1 and 5 R star . We solve for a system of stiff, coupled, ordinary, and differential equations. Results: Non-equilibrium chemistry prevails in the dust-formation zone. H 2 O forms quickly above the photosphere from the synthesis of hydroxyl OH induced by the thermal fragmentation of CO in the hot post-shock gas. The derived abundance with respect to H 2 at 5 R star is 1.4 × 10 -7 , which excellently agrees with the values derived from Herschel observations. The non-equilibrium formation process of water will be active whatever the stellar C/O ratio, and H 2 O should then be present in the wind acceleration zone of all stars on the Asymptotic Giant Branch.