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Electrochimica Acta | 1977

Thermodynamic studies of Hydrobromic acid in acetonewater mixtures (10, 30 and 50 wt-%) from electromotive force measurements

Ivica Mekjavić; Ivo Tominić

Abstract The emf of the cell: Pd,H 2 (g)/HBr(m), x wt-% acetonewater mixture/AgBr,Ag was measured with x = 10, 30 and 50 at temperatures 15, 25 and 35°C in the molality range for HBr from 0.003 to 0.1 mol kg −1 . From these data the standard potentials for Ag|AgBr electrode are obtained, and used in calculations of: (a) the standard thermodynamic quantities for the cell reaction and the reaction of HBr formation, (b) the mean activity coefficients of HBr, (c) the primary medium effect, and (d) the standard thermodynamic quantities for transfer of HBr from water to the acetonewater mixed solvents. On the basis of the values obtained under (d), the spontaneity of transfer the process for HBr is discussed, the acid—base properties of mixed solvents and their structure.


Electrochimica Acta | 1980

Thermodynamic properties of hydrobromic acid in 5 wt% 1-butanol-water, and 5 wt% 2-methyl-1-propanol-water-mixture from emf measurements

Ivica Mekjavić; Ivo Tominić

Abstract From the electromotive force measurements of the cell Pt (or Pd), H 2 (g)|HBr(m), 5 wt% alcohol-water mixture|AgBrAg for different m in the temperature range from 288.15 to 308.15 K, the standard potential of AgAgBr electrode has been determined in the mixture where alcohol was 1-butanol and 2-methyl-1-propanol. The standard thermodynamic quantities for cell reaction and for HBr formation, the activity coefficients of HBr, and the standard thermodynamic quantities for the transfer of HBr from water to mixed solvents have been evaluated. The transfer functions were compared with those for water mixtures of other isomeric butanols as well as for the mixture with small proportions of other alcohols.


Croatica Chemica Acta | 2005

Thermodynamics of the Association Reaction of Li+ and Br- Ions in 2-Butanol + Water Mixtures from Conductivity Measurements

Vesna Sokol; Ivo Tominić; Renato Tomaš; Marija Višić


Acta Chimica Slovenica | 2009

Conductometric Study of Ammonium Bromide in 2-Butanol + Water Mixtures

Vesna Sokol; Renato Tomaš; Ivo Tominić


Journal of Solution Chemistry | 2006

Conductometric Study of Potassium Bromide in 2-Butanol + Water Mixtures

Vesna Sokol; Renato Tomaš; Marija Višić; Ivo Tominić


Croatica Chemica Acta | 2001

Determination of Stability Constants of Chlorocadmium Complexes in Water from Electromotive Force Measurements

Renato Tomaš; Marija Višić; Ivo Tominić; Vesna Sokol


Journal of Solution Chemistry | 2005

Thermodynamic Study of Cadmium Chloride in Aqueous Mixtures of 2-Butanol from Potential Difference Measurements

Renato Tomaš; Ivo Tominić; Marija Višić; Vesna Sokol


Journal of Solution Chemistry | 2004

Thermodynamics of cadmium chloride in 2-butanone + water mixtures (5, 10, and 15 mass%) from electromotive force measurements

Renato Tomaš; Ivo Tominić; Marija Višić; Vesna Sokol


Acta Chimica Slovenica | 2008

Thermodynamics of the Association Reaction of RbBr in Binary Mixtures of 2-Butanol and Water from 288.15 to 308.15 K

Vesna Sokol; Renato Tomaš; Ivo Tominić


Croatica Chemica Acta | 2004

Investigation of the Complex Forming Reactions of Cd2+ and Cl- Ions in 2-Butanone + Water Mixtures by Direct Potentiometry

Renato Tomaš; Ivo Tominić; Vesna Sokol; Višić; Marija

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