J. Hollandt

Traceability in Fluorometry: Part II. Spectral Fluorescence Standards

The need for the traceable characterization of fluorescence instruments is emphasized from a chemist’s point of view, focusing on spectral fluorescence standards for the determination of the wavelength- and polarization-dependent relative spectral responsivity and relative spectral irradiance of fluorescence measuring systems, respectively. In a first step, major sources of error of fluorescence measurements and instrument calibration are revealed to underline the importance of this issue and to illustrate advantages and disadvantages of physical and chemical transfer standards for generation of spectral correction curves. Secondly, examples for sets of traceable chemical emission and excitation standards are shown that cover a broad spectral region and simple procedures for the determination of corrected emission spectra with acceptable uncertainties are presented. With proper consideration of the respective measurement principle and geometry, these dye-based characterization procedures can be not only applied to spectrofluorometers but also to other types of fluorescence measuring systems and even to Raman spectrometers.

Radiometric characterization of a Penning discharge in the vacuum ultraviolet

We present a Penning discharge as a possible radiometric transfer standard source in the vacuum UV, primarily in the spectral region below 20 nm. Following the concept of Finley et al., we have designed a Penning source using NdFeB permanent magnets. Emphasis was put on simple operation, quick electrode exchangeability, and easy source readjustment. The radiant intensities of the emission lines from different ionization stages of both buffer gas atoms and atoms sputtered from the cathodes have been studied in various discharge conditions. For selected Al and buffer gas emission lines we determined the absolute radiant intensities by a comparison with the calculable spectral radiant power of the Berlin Electron Storage Ring. A comparison with data from our hollow-cathode transfer standard source is given.

HIGH-CURRENT HOLLOW-CATHODE SOURCE AS A RADIANT INTENSITY STANDARD IN THE 40-125-NM WAVELENGTH RANGE

The radiant intensity of VUV emission lines of a high-current hollow-cathode source has been determined for the 40-125-nm spectral range. The source is operated at a constant current of 1 A with an aluminum cathode. Different rare gases are alternatively used as the buffer gas at pressures of ~100 Pa. The radiant intensity has been determined by comparison with the calculable spectral radiant flux of the electron storage ring BESSY. Radiant intensities of the emission lines are in the 7-1400-µW/sr range. The long-term reproducibility of the radiant intensity of the source is within ±10% (2σ value). The systematic uncertainty of the radiometric calibration is better than 9% (√32σ value).

Source and detector calibration in the UV and VUV at BESSY II

After the shutdown of the BESSY?I electron storage ring, PTBs two normal-incidence monochromator beamlines for the calibration of radiation sources and detectors in the wavelength range from 40?nm to 400?nm were transferred to PTBs new radiometry laboratory at BESSY?II. In this paper, the beamlines and their properties are briefly described. First results for the calibration of secondary source standards and detector standards at BESSY?II are shown and demonstrate the successful re-establishment of the measurement capabilities. In the ultraviolet, calibration of deuterium lamps?was reproduced within 1% and of silicon trap photodetectors within 0.2%.

Radiometric calibration of the telescope and ultraviolet spectrometer SUMER on SOHO

The prelaunch spectral-sensitivity calibration of the solar spectrometer SUMER (Solar Ultraviolet Measurements of Emitted Radiation) is described. SUMER is part of the payload of the Solar and Heliospheric Observatory (SOHO), which begins its scientific mission in 1996. The instrument consists of a telescope and a spectrometer capable of taking spatially and spectrally highly resolved images of the Sun in a spectral range from 50 to 161 nm. The pointing capabilities, the dynamic range, and the sensitivity of the instrument allow measurements both on the solar disk and above the limb as great as two solar radii. To determine plasma temperatures and densities in the solar atmosphere, the instrument needs an absolute spectral-sensitivity calibration. Here we describe the prelaunch calibration of the full instrument, which utilizes a radiometric transfer-standard source. The transfer standard was based on a high-current hollow-cathode discharge source. It had been calibrated in the laboratory for vacuum UV radiometry of the Physikalisch-Technische Bundesanstalt by use of the calculable spectral photon flux of the Berlin electron storage ring for synchrotron radiation (BESSY)-a primary radiometric source standard.

Optical methods for power measurement of terahertz radiation

Precision power measurements of terahertz (THz) radiation are required to establish metrological applications in the THz spectral range. However, traceability to the International System of Units (SI) has been missing in the THz region in the past. The Physikalisch-Technische Bundesanstalt (PTB), as the national metrology institute of Germany, determines the spectral responsivity of detectors for THz radiation by using two complementary optical methods: source- and detector-based radiometry. Both approaches have been successfully prototyped, and a pyroelectric THz detector with a well-defined aperture is used to verify the consistency of the two independent calibration methods. These primary investigations led to the design of a new measurement facility for the determination of THz radiant power and the responsivity calibration of THz detectors traceable to the SI.

Traceability in Fluorometry - Part I: Physical Standards

The inter-instrument, inter-laboratory, and long-term comparability of fluorescence data requires the correction of the measured emission and excitation spectra for the wavelength- and polarization-dependent spectral irradiance of the excitation channel at the sample position and the spectral responsivity of the emission channel employing procedures that guarantee traceability to the respective primary standards. In this respect the traceability chain of fluorometry is discussed from a radiometrist’s point of view. This involves, in a first step, the realization of the spectral radiance scale, based on the blackbody radiator and electron storage ring, and the spectral responsivity scale, based on the cryogenic radiometer and their control via key comparisons of the national metrology institutes. In a second step, the characterization including state-of-the art uncertainties of the respective source and detector transfer standards such as tungsten strip lamps, integrating sphere radiators, and trap detectors used to disseminate these radiometric quantities to users of spectroscopic techniques is presented.

INTERCALIBRATION OF SUMER AND CDS ON SOHO. I. SUMER DETECTOR A AND CDS NIS

The results of an intercalibration between the extreme ultraviolet spectrometers Coronal Diagnostic Spectrometer (CDS) and Solar Ultraviolet Measurements of Emitted Radiation (SUMER) onboard the Solar and Heliospheric Observatory (SOHO) are presented. During the joint observing program Intercal_01, CDS and SUMER were pointed at the same locations in quiet Sun areas and observed in the same wavelength bands located around the spectral lines He i 584 A, Mg x 609 A, and Mg x 624 A. The data sets analyzed here consist of raster images recorded by the CDS normal-incidence spectrometer and SUMER detector A and span the time from March 1996 to August 1996. Effects of the different spatial and spectral resolutions of both instruments have been investigated and taken into account in the analysis. We find that CDS measures generally a 30% higher intensity than SUMER in the He i 584-A line, while it measures 9% and 17% higher intensities in Mg x 609 A and Mg x 624 A, respectively. Both instruments show very good temporal correlation and stability, indicating that solar variations dominate over changes in instrumental sensitivity. Our analysis also provides in-flight estimates of the CDS spatial point-spread functions.

First Results of Tide SUMER Telescope and Spectrometer on SOHO

SUMER — the Solar Ultraviolet Measurements of the Emitted Radiation instrument on the Solar and Reliospheric Observatory (SORO) — observed its first light on January 24, 1996, and subsequently obtained a detailed spectrum with detector B in the wavelength range from 660 to 1490 A (in first order) inside and above the limb in the north polar coronal hole. Using detector A of the instrument, this range was later extended to 1610 A. The second-order spectra of detectors A and B cover 330 to 805 A and are superimposed on the first-order spectra. Many more features and areas of the Sun and their spectra have been observed since, including coronal holes, polar plumes and active regions. The atoms and ions emitting this radiation exist at temperatures below 2 × 106 K and are thus ideally suited to investigate the solar transition region where the temperature increases from chromospheric to coronal values. SUMER can also be operated in a manner such that it makes images or spectroheliograms of different sizes in selected spectral lines. A detailed line profile with spectral resolution elements between 22 and 45 mA is produced for each line at each spatial location along the slit. From the line width, intensity and wavelength position we are able to deduce temperature, density, and velocity of the emitting atoms and ions for each emission line and spatial element in the spectroheliogram. Because of the high spectral resolution and low noise of SUMER, we have been able to detect faint lines not previously observed and, in addition, to determine their spectral profiles. SUMER has already recorded over 2000 extreme ultraviolet emission lines and many identifications have been made on the disk and in the corona.

The determination of the uncertainties of spectral emissivity measurements in air at the PTB

The instrumentation of the Physikalisch-Technische Bundesanstalt (PTB) for the measurement of the directional spectral emissivity in air in the temperature range from 80 °C to 400 °C and wavelength range from 4 µm to 40 µm and the subsequent procedures for data evaluation are described. Special emphasis is placed on the calculation of the uncertainty of the directional spectral emissivity and of the uncertainty of the sample surface temperature. For samples with typical emissivities of about 0.6, absolute expanded uncertainties (k = 2) of 0.01 can be reached at a surface temperature of 200 °C in the spectral range from 5 µm to 40 µm. However, it is also shown that—due to the complex dependence of the uncertainty on the sample and the conditions of measurement—general statements about the uncertainty cannot be given. The uncertainty of the emissivity has to be calculated for each individual case of sample and temperature.