J. Saavedra

The Pampean Orogeny of the southern proto-Andes: Cambrian continental collision in the Sierras de Cordoba

Abstract A detailed study of the pre-Silurian geology of the Sierras de Córdoba, Eastern Sierras Pampeanas, is used to define the sequence of magmatic and metamorphic events during the Pampean orogeny. This primarily involved Early to Mid-Cambrian subduction and terrane collision at the western margin of Gondwana during the amalgamation of the super-continent. Evidence for this is based principally on new information concerning (a) regional mapping and field relations, (b) analysis of the structures, deformational history and meta-morphic evolution and (c) geochronology and geochemistry of the igneous and metamorphic rocks. The main events recognized are (1) Late Proterozoic break-up of Rodinia (Nd model ages of 1500 ± 200 Ma, inherited zircons 800–1400 Ma), (2) development of an Early Cam-brian passive margin sequence (Puncoviscana Formation and equivalents), (3) emplacement of metaluminous calc-alkaline granitoids (G1a, dated at 530 ± 3 Ma) as a result of NE-directed subduction, (4) crustal thickening, ophiolite obduction, compression and high-grade metamorphism (M2: 8.6±0.8 kbar, 810 ± 50°C, c.525 Ma) related to collision, and culmina-ting in (5) isothermal uplift and widespread low-P anatexis (M3, 4.0±0.5 kbar, 715 ± 15°C, c.520 Ma). The last event is responsible for the linked generation of highly peraluminous granites (G1b) and cordieritites. Subsequent emplacement into the accreted terrane of Ordovician trondhjemite-tonalites (500-470 Ma) and dextral wrench shear are interpreted as inner cordilleran counterparts of the Famatinian arc, which developed to the west along the newly-formed proto-Andean margin.

Early evolution of the Proto-Andean margin of South America

From a detailed study of a 500 km transect in the Sierras Pampeanas, central-west Argentina, two pre-Silurian tectono-magmatic episodes are recognized and defined, each culminating in micro-continental collisions against the proto-Andean margin of Gondwana. The Pampean orogeny started in Early Cambrian time with short-lived subduction, indicated by ca. 535 Ma calc-alkaline granitoids. Following Pampean terrane collision, burial to granulite facies conditions (ca. 9 kbar) generated widespread migmatites and ca. 520 Ma highly peraluminous granites in the Eastern Sierras Pampeanas. After brief quiescence, a second major episode, the Famatinian orogeny, started with subduction ca. 490 Ma, forming a wide continental arc and ensialic backarc basin. This heralded the approach of Laurentia to Gondwana, during which the Precordillera terrane separated from the southern Appalachian region, finally colliding with Gondwana in Silurian–Devonian time.

The Famatinian magmatic arc in the central Sierras Pampeanas: an Early to Mid-Ordovician continental arc on the Gondwana margin

Abstract A new multi-disciplinary study of the central Sierras Pampeanas encompasses fieldwork, petrography, metamorphic and micro-structural analysis, geochemistry and geochronology. Remnants of a low-to-medium grade metasedimentary sequence, which also occurs in the Sierras de Córdoba to the east, are considered regionally equivalent to the Puncoviscana Formation; a ?mid-Cambrian Rb-Sr whole-rock isochron of 513 ± 31 Ma probably dates their main metamorphism. The predominant granitoids of the Los Llanos-Ulapes batholith constitute a calc-alkaline suite representative of the Famatinian subduction-related magmatic arc. The main granodiorite phase of the batholith is associated with an S2 fabric and shear zone formation, and was emplaced late during the deformational history of the metasediments. Conventional and SHRIMP U-Pb zircon dating yielded a combined age of 490 ± 5 Ma. Younger monzogranites gave Rb-Sr whole-rock ages of 470–450 Ma, typical of granites in the Sierra de Famatina, but geochemical continuity with the main granodiorite suite raises the possibility that these are partially reset ages. A minor cordierite granite phase is ascribed to local anatexis caused by heat from the granodiorites. All the calc-alkaline rocks of the Los Llanos-Ulapes batholith have high initial 87Sr/86Sr (0.7075–0.7105) and low ɛNdt (−4.6 to −6.3), inherited from lower crust. Sm-Nd model ages of 1600–1700 Ma indicate that the underlying crust is identical to that beneath the foreland to the east. This part of the Famatinian arc was thus a continental magmatic arc and was established significantly before the arrival of the allochthonous Precordillera terrane in mid-Ordovician times.

Involvement of the Argentine Precordillera terrane in the Famatinian mobile belt: U-Pb SHRIMP and metamorphic evidence from the Sierra de Pie de Palo

New data suggest that the eastern margin of the Argentine Precordillera terrane comprises Grenvillian basement and a sedimentary cover derived from it that were together affected by Middle Ordovician deformation and metamorphism during accretion to the Gondwana margin. The basement first underwent low pressure/temperature ( P/T ) type metamorphism, reaching high-grade migmatitic conditions in places (686 ± 40 MPa, 790 ± 17 °C), comparable to the Grenvillian M2 metamorphism of the supposed Laurentian counterpart of the terrane. The second metamorphism, recognized in the cover sequence, is of Famatinian age and took place under higher P/T conditions, following a clockwise P-T path (baric peak: 1300 ± 100 Mpa, 600 ± 50 °C). Low-U zircon overgrew detrital Grenvillian cores as pressure fell from its peak, and yields U-Pb SHRIMP ages of ca. 460 Ma. This is interpreted as the age of ductile thrusting coincident with early uplift; initial accretion to Gondwana must have occurred before this. The absence of late Neoproterozoic detrital zircons is consistent with a Laurentian origin of the Argentine Precordillera terrane.

New SHRIMP U-Pb data from the Famatina Complex: constraining Early-Mid Ordovician Famatinian magmatism in the Sierras Pampeanas, Argentina

New SHRIMP U-Pb zircon ages are reported for igneous and sedimentary rocks of the Famatina Complex, constraining the age of the magmatism and the ensialic basins. Together with whole-rock and isotope geochemistry for the igneous rocks from the complex, these ages indicate that the voluminous parental magmas of metaluminous composition were derived by partial melting of an older lithosphere without significant asthenospheric contribution. This magmatism was initiated in the Early Ordovician (481 Ma). During the Mid-Late Ordovician, the magmatism ceased (463 Ma), resulting in a short-lived (no more than ~20 Ma) and relatively narrow (~100-150 km) magmatic belt, in contrast to the long-lived cordilleran magmatism of the Andes. The exhumation rate of the Famatina Complex was considerably high and the erosional stripping and deposition of Ordovician sediments occurred soon after of the emplacement of the igneous source rocks during the Early to mid-Ordovician. During the upper Mid Ordovician the clastic contribution was mainly derived from plutonic rocks. Magmatism was completely extinguished in the Mid Ordovician and the sedimentary basins closed in the early Late Ordovician.

Emplacement, petrological and magnetic susceptibility characteristics of diverse magmatic epidote-bearing granitoid rocks in Brazil, Argentina and Chile

Magmatic epidote mEp -bearing granitoids from five Neoproterozoic tectonostratigraphic terranes in Northeastern NE . Brazil, Early Palaeozoic calc-alkalic granitoids in Northwestern NW Argentina and from three batholiths in Chile have been studied. The elongated shape of some of these plutons suggests that magmas filled fractures and that dyking was probably the major mechanism of emplacement. Textures reveal that, in many cases, epidote underwent partial dissolution by host magma and, in these cases, may have survived dissolution by relatively rapid upward transport by the host magma. In plutons where such a mechanism is not evident, unevenly distributed epidote at outcrop scale is armoured by biotite or near-solidus K-feldspar aggregates, which probably grew much faster than epidote dissolution, preventing complete resorption of epidote by the melt. Al-in-hornblende barometry indicates that, in most cases, amphibole crystallized at PG 5 kbar. Kyanite-bearing thermal aureoles surrounding plutons that intruded low-grade metamorphic rocks in NE Brazil support pluton emplacement at intermediate to high pressure. mEp show overall chemical variation from 20 to 30 mol% mole . . percent pistacite Ps and can be grouped into two compositional ranges: Ps and Ps . The highest Ps contents are 20 - 24 27 - 30 in epidotes of plutons in which hornblende solidified under P- 5 kbar. The percentage of corrosion of individual epidote crystals included in plagioclase in high-K calc-alkalic granitoids in NE Brazil, emplaced at 5-7 kbar pressure, yielded estimates of magma transport rate from 70 to 350 m year y1 . Most of these plutons lack Fe-Ti oxide minerals and Fe q3 is . mostly associated with the epidote structure. Consequently, magnetic susceptibility MS in the Neoproterozoic granitoids in NE Brazil, as well as Early Palaeozoic plutons in Argentina and Late Palaeozoic plutons in Chile, is usually low

Grenvillian massif-type anorthosites in the Sierras Pampeanas

We report the discovery of massif-type anorthosites in the Andean basement of the Western Sierras Pampeanas of Argentina. U–Pb zircon dating (by sensitive high-resolution ion microprobe) of a cogenetic gabbronorite dyke yields ages of 1070 ± 41 Ma for igneous emplacement and 431 ± 40 Ma for metamorphism. These anorthosites are petrologically and geochemically comparable with those of the Grenville province of Laurentia. Palaeogeographical reconstructions of Rodinia at 1.0–1.1 Ga suggest that the Sierras Pampeanas anorthosites were part of a large anorthosite province in the late Mesoproterozoic.

Environmental geochemistry of recent volcanic ashes from the Southern Andes

Environmental context Explosive volcanic eruptions may have significant environmental repercussions for many Earth system cycles, particularly the water cycle. We investigate the potential contribution to local geochemical fluxes through water of five historical eruptions that occurred over a 20-year period in the Southern Andes. In all five cases, the major potentially toxic trace elements were arsenic, copper, fluoride, molybdenum, nickel, lead and zinc. Abstract The potential contribution to the local geochemical balance of five historical eruptions that occurred during the 20th Century has been investigated in the Southern Volcanic Zone (SVZ) of the Andean volcanic arc of South America (Lonquimay 1988, Hudson 1991, Copahue 2000, Llaima 2008, Chaiten 2008). These ashes were characterised by SEMEDX and XRD, and their potential released geochemical fluxes were examined using water and nitric acid batch leaching tests. Leachates were analysed by ICP-OES, ICP-MS and ISE. The major contents removed correspond to SO42– and Cl–. The potential toxic trace element (PTTE) content was highly variable among the ash samples following this order: Chaiten > Copahue > Hudson > Llaima > Lonquimay. The trace elements with significant load in water batch leaching tests include Fe > F > B > P > Zn > As > Mn > Sr > Ba > Ti > Cu > Ni > Li > Rb > Co > Cr > Cd > Sb. Some of these elements (As, Cu, F, Mo, Ni, Pb and Zn) are included in the drinking water guidelines due to their potential toxicity and must be especially monitored in the environmental assessment of these ashfall deposits.

Environmental geochemistry of ancient volcanic ashes.

Volcanic ashes from the Puna and surrounding Andean areas in northern Argentina show that sometimes volcanic ash deposits are very well preserved (up to several million years) and can remain a potential hazard for the environment in a similar way as current deposits. Eight ashes have been characterized by SEM-EDX and DRX, and their potential released geochemical fluxes were examined by using water and nitric acid batches, which are analyzed by ICP-OES, ICP-MS and ISE (F). Results demonstrate that water batch system is better medium than nitric acid for this study. The high and fast reactivity of these ancient ashes is mainly associated with their high content in glass. The order of magnitude of released contents of implied elements is consistent among the samples, i.e., Al>B>Fe>Zn>F>P>Mn>Ba>Sr>Li>Ti>Rb>Cu>Ni>Sb>Pb>As>Cr>V. Ash-water interaction, although infrequent in arid regions such as the Puna Region in northern Argentina, introduces rapid changes in the geochemical fluxes of elements and pH and may constitute a potential hazard for the environment. In fact, many of these elements are included in the drinking water guidelines due to their potential toxicity and may constitute potential hazards for the environment and human health.

Las Orogénesis del Paleozoico Inferior en el margen protoandino de América del Sur, Sierras Pampeanas, Argentina.

El margen proto-andino de Gondwana ha sido el escenario de al menos dos orogenesis desde el desmembramiento del supercontinente Rodinia al final del Neoprotrozoico, hasta el reagrupamiento de las masas continentales en Pangea al final del Carbonifero. Ambas orogenesis van precedidas de un periodo de apertura oceanica y sedimentacion en margenes pasivos y culminan en subduccion oceanica con desarrollo de arcos-magmaticos de tipo cordillerano y colision de tipo continente-continente. La primera, orogenesis Pampeana, tiene lugar en el Cambrico, en un intervalo de tiempo relativamente pequeno (535-520 Ma: etapas de subduccion-arco magmatico y colision), y culmina con la acrecion ortogonal de un pequeno terreno continental (terreno Pampeano) de naturaleza semiautoctona. Por el contrario, la orogenesis Famatiniana, tiene lugar en un periodo de tiempo mas dilatado, durante el Ordovicico y Silurico (499-435 Ma). Durante esta orogenesis tuvo lugar la acrecion de un terreno exotico a Gondwana, el terreno Precordillera (460 Ma). Este terreno esta constituido por un basamento grenvilliano (aprox. 1.1Ga) y una cubierta sedimentaria de plataforma carbonatada de edad Cambrico-Ordovicico. La acrecion al margen de Gondwana fue probablemente oblicua, y el margen oriental del terreno Precordillera fue afectado por fuerte deformacion y metamorfismo regional. El basamento de los cinturones andinos del Paleozoico Superior y Mesozoico situados al oeste de la Precordillera, parece estar constituido tambien por rocas metamorficas grenvillianas; con lo cual, gran parte de los Andes centrales entre los 26oS y 34oS se encuentra asentado sobre terrenos aloctonos. En cualquier caso, la paleogeografia de las masas continentales involucradas en la colision de los terrenos exoticos durante el Paleozoico Inferior no se conoce bien todavia.