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Dive into the research topics where James J. Napier is active.

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Featured researches published by James J. Napier.


Tetrahedron Letters | 1994

A process for the synthesis of β-ketoesters using in-situ generated (trimethylsilyl)malonates

Xui Wang; William T. Monte; James J. Napier; Ameen Ghannam

Abstract (TMS)ethyl malonate can be generated in-situ by treating potassium ethyl malonate with trimethylsilyl chloride and acylated with aliphatic or aromatic acyl imidazoles or chlorides in the presence of DBU to prepare a variety of β-ketoesters. This constitutes a high yield method for preparing β-ketoesters, which also can be extended to the formation of alkylidene malonates.


Journal of The Chemical Society, Chemical Communications | 1981

Rearrangement of a 2-aryloxycyclohex-2-enone. A new enolate Claisen rearrangement?

Arthur G. Schultz; James J. Napier

The base-catalysed rearrangement of the 2-aryl-oxycyclohex-2-enone (3) to the enone (4a) is suggested to occur by an enolate-promoted 3,3-sigmatropic rearrangement of the enolate aryl ether (7)


Journal of the American Chemical Society | 1989

An enantioselective and highly convergent synthesis of (+)-ikarugamycin

Robert K. Boeckman; Charles H. Weidner; Robert B. Perni; James J. Napier


Journal of Organic Chemistry | 1985

Studies directed at a synthesis of the morphine alkaloids. A photochemical approach

Arthur G. Schultz; Robert D. Lucci; James J. Napier; Hideki Kinoshita; Ramanathan Ravichandran; Paul J. Shannon; Ying K. Yee


Journal of Organic Chemistry | 1983

Stereocontrol in the intramolecular Diels-Alder reaction. 5. Preparation of a tetracyclic intermediate for ikarugamycin

Robert K. Boeckman; James J. Napier; Edward W. Thomas; Ronald I. Sato


Journal of Organic Chemistry | 1983

Synthetic applications of heteroatom-directed photoarylation: benzo[b]furan ring construction

Arthur G. Schultz; James J. Napier; Ramanathan Ravichandran


Journal of Organic Chemistry | 1979

Stereospecific benzodihydrofuran photorearrangement

Arthur G. Schultz; James J. Napier; Ronald Lee


Tetrahedron Letters | 1982

On the stereoselectivity of heteroatom directed photoarylation

Arthur G. Schultz; James J. Napier


Journal of the American Chemical Society | 1984

Stereochemistry of benzodihydrofuran-2-carboxylic acid ester photorearrangement

Arthur G. Schultz; James J. Napier; Padmanabhan. Sundararaman


ChemInform | 1984

SYNTHETIC APPLICATIONS OF HETEROATOM-DIRECTED PHOTOARYLATION. BENZO(B)FURAN RING CONSTRUCTION

Arthur G. Schultz; James J. Napier; Ramanathan Ravichandran

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Ramanathan Ravichandran

Rensselaer Polytechnic Institute

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Padmanabhan. Sundararaman

Rensselaer Polytechnic Institute

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