Jennifer McKinley

Comparison of clay mineral stratigraphy to other proxy palaeoclimate indicators in the Mesozoic of NW Europe

This paper reviews the opportunities and pitfalls associated with using clay mineralogical analysis in palaeoclimatic reconstructions. Following this, conjunctive methods of improving the reliability of clay mineralogical analysis are reviewed. The Mesozoic succession of NW Europe is employed as a case study. This demonstrates the relationship between clay mineralogy and palaeoclimate. Proxy analyses may be integrated with clay mineralogical analysis to provide an assessment of aridity–humidity contrasts in the hinterland climate. As an example, the abundance of kaolinite through the Mesozoic shows that, while interpretations may be difficult, the Mesozoic climate of NW Europe was subject to great changes in rates of continental precipitation. We may compare sedimentological (facies, mineralogy, geochemistry) indicators of palaeoprecipitation with palaeotemperature estimates. The integration of clay mineralogical analyses with other sedimentological proxy indicators of palaeoclimate allows differentiation of palaeoclimatic effects from those of sea–level and tectonic change. We may also observe how widespread palaeoclimate changes were; whether they were diachronous or synchronous; how climate, sea level and tectonics interact to control sedimentary facies and what palaeoclimate indicators are reliable.

Use of Variography in Permeability Characterization of Visually Homogeneous Sandstone Reservoirs with Examples from Outcrop Studies

Sandstones of different ages provide economically significant oil, gas, and water reservoirs. In sandstones where heterogeneities are not visually obvious, it is particularly difficult to predict the location of permeability barriers and the scale at which high and low permeability zones occur, yet this is critical in providing information on hydrocarbon reservoir performance. This study uses variogram analysis to investigate spatial variation in permeability in visually homogeneous reservoir sandstone successions. Air permeability measurements were taken using unsteady state probe permeametry following regular grid schemes with centimeter spacing. Spatial variation in permeability was characterized using omnidirectional and directional variograms. This study combines variography with geological interpretation to assess the degree of heterogeneity of permeability in visually homogeneous sandstone successions. Variography indicates spatial dependence and short-range variation at 1 cm grid spacings that is not apparent at a larger 5 cm grid spacing in the visually homogeneous sandstones studied. The range of the models fitted to the variograms provide a potentially important index of spatial variability in permeability for different depositional settings including aeolian, fluvial, shallow marine, and marine/mass- flow turbidite.

Contact Diagenesis: The Effect of an Intrusion on Reservoir Quality in the Triassic Sherwood Sandstone Group, Northern Ireland

ABSTRACT Intrusion of a dolerite sill into clay-bearing, arkosic Triassic Sherwood Group sandstones with moderate porosity (22%) and high but anisotropic permeability (mode 500 md) led to the progressive transformation of precursor diagenetic minerals. In the host rock, locally pore-filling Mg-rich smectite (saponite), quartz, and dolomite, existing in the rock following earlier burial diagenesis, reacted to produce grain-coating flakes of talc at the lowest contact temperatures (130-180°C; based on equilibrium reaction-path and thermal-history calculations). At higher temperatures (200-230°C), talc reacted with calcite to produce an actinolitic amphibole. Close to the intrusion, at temperatures of > 250°C, bundles of acicular needles of actinolite protruding into open pores were produced by a second reaction involving saponite, hematite, and calcite. Framework feldspar minerals (mainly K-feldspars) played little or no part in the reactions because there were no K-Al rich minerals produced by contact diagenesis and because the detrital feldspar grains are essentially unaltered. Thus while equilibrium may have been approached on the intrapore scale ( 10 µm), it was not achieved between grains (e.g., detrital feldspars), pore water, and clays in the pores. Total porosity has been unaffected by the intrusion and consequent mineral reactions, because reactions involved recrystallization of original pore-filling minerals. Despite the contact diagenetic changes in the rock, the permeability of the sandstone remained largely unaffected by intrusion.

Assessing modern ground survey methods and airborne laser scanning for digital terrain modelling: A case study from the Lake District, England

This paper compares the applicability of three ground survey methods for modelling terrain: one man electronic tachymetry (TPS), real time kinematic GPS (GPS), and terrestrial laser scanning (TLS). Vertical accuracy of digital terrain models (DTMs) derived from GPS, TLS and airborne laser scanning (ALS) data is assessed. Point elevations acquired by the four methods represent two sections of a mountainous area in Cumbria, England. They were chosen so that the presence of non-terrain features is constrained to the smallest amount. The vertical accuracy of the DTMs was addressed by subtracting each DTM from TPS point elevations. The error was assessed using exploratory measures including statistics, histograms, and normal probability plots. The results showed that the internal measurement accuracy of TPS, GPS, and TLS was below a centimetre. TPS and GPS can be considered equally applicable alternatives for sampling the terrain in areas accessible on foot. The highest DTM vertical accuracy was achieved with GPS data, both on sloped terrain (RMSE 0.16m) and flat terrain (RMSE 0.02m). TLS surveying was the most efficient overall but veracity of terrain representation was subject to dense vegetation cover. Therefore, the DTM accuracy was the lowest for the sloped area with dense bracken (RMSE 0.52m) although it was the second highest on the flat unobscured terrain (RMSE 0.07m). ALS data represented the sloped terrain more realistically (RMSE 0.23m) than the TLS. However, due to a systematic bias identified on the flat terrain the DTM accuracy was the lowest (RMSE 0.29m) which was above the level stated by the data provider. Error distribution models were more closely approximated by normal distribution defined using median and normalized median absolute deviation which supports the use of the robust measures in DEM error modelling and its propagation.

Comparison of methods used to calculate typical threshold values for potentially toxic elements in soil

The environmental quality of land can be assessed by calculating relevant threshold values, which differentiate between concentrations of elements resulting from geogenic and diffuse anthropogenic sources and concentrations generated by point sources of elements. A simple process allowing the calculation of these typical threshold values (TTVs) was applied across a region of highly complex geology (Northern Ireland) to six elements of interest; arsenic, chromium, copper, lead, nickel and vanadium. Three methods for identifying domains (areas where a readily identifiable factor can be shown to control the concentration of an element) were used: k-means cluster analysis, boxplots and empirical cumulative distribution functions (ECDF). The ECDF method was most efficient at determining areas of both elevated and reduced concentrations and was used to identify domains in this investigation. Two statistical methods for calculating normal background concentrations (NBCs) and upper limits of geochemical baseline variation (ULBLs), currently used in conjunction with legislative regimes in the UK and Finland respectively, were applied within each domain. The NBC methodology was constructed to run within a specific legislative framework, and its use on this soil geochemical data set was influenced by the presence of skewed distributions and outliers. In contrast, the ULBL methodology was found to calculate more appropriate TTVs that were generally more conservative than the NBCs. TTVs indicate what a “typical” concentration of an element would be within a defined geographical area and should be considered alongside the risk that each of the elements pose in these areas to determine potential risk to receptors.

Controls on permeability: implications for stone weathering

Abstract In the light of a well-researched relationship between rock properties and susceptibility of stone to weathering, the role of permeability in weathering is examined. A review of weathering studies indicates the varied use and nature of porosity data, but the paucity of permeability studies in weathering trials. Key factors that control porosity and permeability, depositional characteristics and diagenetic processes are discussed and investigated, with a view to discussing the implications for stone weathering. Results from experimental studies on a range of rock types comprising sandstone, limestone and granite are presented. The relevance of permeability measurement is explored in terms of spatial mapping and quantitative assessment of the deterioration of natural building stone. Increased knowledge and appreciation of the inherited characteristics of a rock is demonstrated to provide valuable insight and a greater understanding of how natural stone heterogeneity is accentuated and exploited by weathering and continued exposure to moisture and salts. Mapping the spatial distribution of permeability provides greater insight into the extent of variability in stone deterioration and presents the possibility of monitoring and predicting the hydraulic properties of stone and how these are modified by weathering processes.

Coupling ground and airborne geophysical data with upscaling techniques for regional groundwater modeling of heterogeneous aquifers: Case study of a sedimentary aquifer intruded by volcanic dykes in Northern Ireland

In highly heterogeneous aquifer systems, conceptualization of regional groundwater flow models frequently results in the generalization or negligence of aquifer heterogeneities, both of which may result in erroneous model outputs. The calculation of equivalence related to hydrogeological parameters and applied to upscaling provides a means of accounting for measurement scale information but at regional scale. In this study, the Permo-Triassic Lagan Valley strategic aquifer in Northern Ireland is observed to be heterogeneous, if not discontinuous, due to subvertical trending low-permeability Tertiary dolerite dykes. Interpretation of ground and aerial magnetic surveys produces a deterministic solution to dyke locations. By measuring relative permeabilities of both the dykes and the sedimentary host rock, equivalent directional permeabilities, that determine anisotropy calculated as a function of dyke density, are obtained. This provides parameters for larger scale equivalent blocks, which can be directly imported to numerical groundwater flow models. Different conceptual models with different degrees of upscaling are numerically tested and results compared to regional flow observations. Simulation results show that the upscaled permeabilities from geophysical data allow one to properly account for the observed spatial variations of groundwater flow, without requiring artificial distribution of aquifer properties. It is also found that an intermediate degree of upscaling, between accounting for mapped field-scale dykes and accounting for one regional anisotropy value (maximum upscaling) provides results the closest to the observations at the regional scale.

Correlation analysis as a tool to investigate the bioaccessibility of nickel, vanadium and zinc in Northern Ireland soils

Correlation analyses were conducted on nickel (Ni), vanadium (V) and zinc (Zn) oral bioaccessible fractions (BAFs) and selected geochemistry parameters to identify specific controls exerted over trace element bioaccessibility. BAFs were determined by previous research using the unified BARGE method. Total trace element concentrations and soil geochemical parameters were analysed as part of the Geological Survey of Northern Ireland Tellus Project. Correlation analysis included Ni, V and Zn BAFs against their total concentrations, pH, estimated soil organic carbon (SOC) and a further eight element oxides. BAF data were divided into three separate generic bedrock classifications of basalt, lithic arenite and mudstone prior to analysis, resulting in an increase in average correlation coefficients between BAFs and geochemical parameters. Sulphur trioxide and SOC, spatially correlated with upland peat soils, exhibited significant positive correlations with all BAFs in gastric and gastro-intestinal digestion phases, with such effects being strongest in the lithic arenite bedrock group. Significant negative relationships with bioaccessible Ni, V and Zn and their associated total concentrations were observed for the basalt group. Major element oxides were associated with reduced oral trace element bioaccessibility, with Al2O3 resulting in the highest number of significant negative correlations followed by Fe2O3. spatial mapping showed that metal oxides were present at reduced levels in peat soils. The findings illustrate how specific geology and soil geochemistry exert controls over trace element bioaccessibility, with soil chemical factors having a stronger influence on BAF results than relative geogenic abundance. In general, higher Ni, V and Zn bioaccessibility is expected in peat soil types.

The effects of lead sources on oral bioaccessibility in soil and implications for contaminated land risk management.

Lead (Pb) is a non-threshold toxin capable of inducing toxic effects at any blood level but availability of soil screening criteria for assessing potential health risks is limited. The oral bioaccessibility of Pb in 163 soil samples was attributed to sources through solubility estimation and domain identification. Samples were extracted following the Unified BARGE Method. Urban, mineralisation, peat and granite domains accounted for elevated Pb concentrations compared to rural samples. High Pb solubility explained moderate-high gastric (G) bioaccessible fractions throughout the study area. Higher maximum G concentrations were measured in urban (97.6 mg kg(-1)) and mineralisation (199.8 mg kg(-1)) domains. Higher average G concentrations occurred in mineralisation (36.4 mg kg(-1)) and granite (36.0 mg kg(-1)) domains. Findings suggest diffuse anthropogenic and widespread geogenic contamination could be capable of presenting health risks, having implications for land management decisions in jurisdictions where guidance advises these forms of pollution should not be regarded as contaminated land.

How useful are databases in environmental and criminal forensics

Abstract Advances in computational and information technologies have facilitated the acquisition of geospatial information for regional and national soil and geology databases. These have been completed for a range of purposes from geological and soil baseline mapping to economic prospecting and land resource assessment, but have become increasingly used for forensic purposes. On the question of provenance of a questioned sample, the geologist or soil scientist will draw invariably on prior expert knowledge and available digital map and database sources in a ‘pseudo Bayesian’ approach. The context of this paper is the debate on whether existing (digital) geology and soil databases are indeed useful and suitable for forensic inferences. Published and new case studies are used to explore issues of completeness, consistency, compatibility and applicability in relation to the use of digital geology and soil databases in environmental and criminal forensics. One key theme that emerges is that, despite an acknowledgement that databases can be neither exhaustive nor precise enough to portray spatial variability at the scene of crime scale, coupled with expert knowledge, they play an invaluable role in providing background or reference material in a criminal investigation. Moreover databases can offer an independent control set of samples.