Jeroen Van Stappen

A Pore-Scale Study of Fracture Dynamics in Rock Using X-ray Micro-CT Under Ambient Freeze–Thaw Cycling

Freeze-thaw cycling stresses many environments which include porous media such as soil, rock and concrete. Climate change can expose new regions and subject others to a changing freeze-thaw frequency. Therefore, understanding and predicting the effect of freeze-thaw cycles is important in environmental science, the built environment and cultural heritage preservation. In this paper, we explore the possibilities of state-of-the-art micro-CT in studying the pore scale dynamics related to freezing and thawing. The experiments show the development of a fracture network in a porous limestone when cooling to -9.7 °C, at which an exothermal temperature peak is a proxy for ice crystallization. The dynamics of the fracture network are visualized with a time frame of 80 s. Theoretical assumptions predict that crystallization in these experiments occurs in pores of 6-20.1 nm under transient conditions. Here, the crystallization-induced stress exceeds rock strength when the local crystal fraction in the pores is 4.3%. The location of fractures is strongly related to preferential water uptake paths and rock texture, which are visually identified. Laboratory, continuous X-ray micro-CT scanning opens new perspectives for the pore-scale study of ice crystallization in porous media as well as for environmental processes related to freeze-thaw fracturing.

Laminar gypsum crust on lede stone: microspatial characterization and laboratory acid weathering

Gypsum crusts are typical decay forms on limestone in polluted urban environments. Their origin and relation to the stone facies have been thoroughly investigated in the past three decades. Here, we present the combined use of novel techniques for a microspatial structural, chemical and mechanical characterization of a laminar black gypsum crust on a sandy limestone. These techniques include i.a. X-ray computed microtomography, X-ray Fluorescence micromapping, permeability mapping and the scratch test. They reveal the typical architecture of a laminar gypsum crust, with an outer opaque layer, a subsurface gypsum crystallization layer and a deeper cracked zone passing irregularly into the sound stone. Gypsum crystallization is mostly restricted to an irregular outer zone with an average thickness of 500µm, while cracks are found deeper within the rock. These cracks decrease the rock strength to more than 27.5mm below the surface. Because of their surface parallel orientation and thickness of >10-100µm, they create the potential for surface scaling. This is shown by a laboratory acid test where the crack network extensively developed due to further exposure to an SO2 environment. The use of novel techniques opens potential for the study of different decay forms and can be used for stone diagnosis with regards to conservation studies.

Investigating the relative permeability behavior of microporosity-rich carbonates and tight sandstones with multiscale pore network models

The relative permeability behavior of rocks with wide ranges of pore sizes is in many cases still poorly understood, and is difficult to model at the pore scale. In this work, we investigate the capillary pressure and relative permeability behavior of three outcrop carbonates and two tight reservoir sandstones with wide, multi-modal pore size distributions. To examine how the drainage and imbibition properties of these complex rock types are influenced by the connectivity of macropores to each other and to zones with unresolved small-scale porosity, we apply a previously presented micro-computed-tomography-based multi-scale pore network model Bultreys et al. [2015b, 2016b] to these samples. The sensitivity to the properties of the small-scale porosity is studied by performing simulations with different artificial sphere-packing-based networks as a proxy for these pores. Finally, the mixed-wet water flooding behavior of the samples is investigated, assuming different wettability distributions for the micro-and macroporosity. While this work is not an attempt to perform predictive modeling, it seeks to qualitatively explain the behavior of the investigated samples and illustrates some of the most recent developments in multi-scale pore network modeling.

Motion compensated micro-CT reconstruction for in-situ analysis of dynamic processes

This work presents a framework to exploit the synergy between Digital Volume Correlation (DVC) and iterative CT reconstruction to enhance the quality of high-resolution dynamic X-ray CT (4D-µCT) and obtain quantitative results from the acquired dataset in the form of 3D strain maps which can be directly correlated to the material properties. Furthermore, we show that the developed framework is capable of strongly reducing motion artifacts even in a dataset containing a single 360° rotation.