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Dive into the research topics where Jessica Nicole Kruichak is active.

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Featured researches published by Jessica Nicole Kruichak.


Scientific Reports | 2017

Model Representations of Kerogen Structures: An Insight from Density Functional Theory Calculations and Spectroscopic Measurements

Philippe F. Weck; Eunja Kim; Yifeng Wang; Jessica Nicole Kruichak; Melissa Marie Mills; Edward N. Matteo; Roland J.-M. Pellenq

Molecular structures of kerogen control hydrocarbon production in unconventional reservoirs. Significant progress has been made in developing model representations of various kerogen structures. These models have been widely used for the prediction of gas adsorption and migration in shale matrix. However, using density functional perturbation theory (DFPT) calculations and vibrational spectroscopic measurements, we here show that a large gap may still remain between the existing model representations and actual kerogen structures, therefore calling for new model development. Using DFPT, we calculated Fourier transform infrared (FTIR) spectra for six most widely used kerogen structure models. The computed spectra were then systematically compared to the FTIR absorption spectra collected for kerogen samples isolated from Mancos, Woodford and Marcellus formations representing a wide range of kerogen origin and maturation conditions. Limited agreement between the model predictions and the measurements highlights that the existing kerogen models may still miss some key features in structural representation. A combination of DFPT calculations with spectroscopic measurements may provide a useful diagnostic tool for assessing the adequacy of a proposed structural model as well as for future model development. This approach may eventually help develop comprehensive infrared (IR)-fingerprints for tracing kerogen evolution.


Environmental Science & Technology | 2017

Redox Transformations of As and Se at the Surfaces of Natural and Synthetic Ferric Nontronites: Role of Structural and Adsorbed Fe(II)

Anastasia Gennadyevna Ilgen; Jessica Nicole Kruichak; Kateryna Artyushkova; Matthew Newville; Chengjun J. Sun

Adsorption and redox transformations on clay mineral surfaces are prevalent in surface environments. We examined the redox reactivity of iron Fe(II)/Fe(III) associated with natural and synthetic ferric nontronites. Specifically, we assessed how Fe(II) residing in the octahedral sheets, or Fe(II) adsorbed at the edge sites alters redox activity of nontronites. To probe the redox activity we used arsenic (As) and selenium (Se). Activation of both synthetic and natural ferric nontronites was observed following the introduction of Fe(II) into predominantly-Fe(III) octahedral sheets or through the adsorption of Fe(II) onto the mineral surface. The oxidation of As(III) to As(V) was observed via catalytic (oxic conditions) and, to a lesser degree, via direct (anoxic conditions) pathways. We provide experimental evidence for electron transfer from As(III) to Fe(III) at the natural and synthetic nontronite surfaces, and illustrate that only a fraction of structural Fe(III) is accessible for redox transformations. We show that As adsorbed onto natural and synthetic nontronites forms identical adsorption complexes, namely inner-sphere binuclear bidentate. We show that the formation of an inner-sphere adsorption complex may be a necessary step for the redox transformation via catalytic or direct oxidation pathways.


Journal of Environmental Radioactivity | 2015

Iodide uptake by negatively charged clay interlayers

Andrew Miller; Jessica Nicole Kruichak; Melissa Marie Mills; Yifeng Wang

Understanding iodide interactions with clay minerals is critical to quantifying risk associated with nuclear waste disposal. Current thought assumes that iodide does not interact directly with clay minerals due to electrical repulsion between the iodide and the negatively charged clay layers. However, a growing body of work indicates a weak interaction between iodide and clays. The goal of this contribution is to report a conceptual model for iodide interaction with clays by considering clay mineral structures and emergent behaviors of chemical species in confined spaces. To approach the problem, a suite of clay minerals was used with varying degrees of isomorphic substitution, chemical composition, and mineral structure. Iodide uptake experiments were completed with each of these minerals in a range of swamping electrolyte identities (NaCl, NaBr, KCl) and concentrations. Iodide uptake behaviors form distinct trends with cation exchange capacity and mineral structure. These trends change substantially with electrolyte composition and concentration, but do not appear to be affected by solution pH. The experimental results suggest that iodide may directly interact with clays by forming ion-pairs (e.g., NaI(aq)) which may concentrate within the interlayer space as well as the thin areas surrounding the clay particle where water behavior is more structured relative to bulk water. Ion pairing and iodide concentration in these zones is probably driven by the reduced dielectric constant of water in confined space and by the relatively high polarizability of the iodide species.


Archive | 2010

Development of a new generation of waste form for entrapment and immobilization of highly volatile and soluble radionuclides.

Mark A. Rodriguez; Denise N. Bencoe; C. Jeffrey Brinker; Andrew Wilson Murphy; Kathleen Caroline Holt; Rigney Turnham; Jessica Nicole Kruichak; Hernesto Tellez; Andrew Miller; Yongliang Xiong; Phillip Isabio Pohl; Nathan W. Ockwig; Yifeng Wang; Huizhen Gao

The United States is now re-assessing its nuclear waste disposal policy and re-evaluating the option of moving away from the current once-through open fuel cycle to a closed fuel cycle. In a closed fuel cycle, used fuels will be reprocessed and useful components such as uranium or transuranics will be recovered for reuse. During this process, a variety of waste streams will be generated. Immobilizing these waste streams into appropriate waste forms for either interim storage or long-term disposal is technically challenging. Highly volatile or soluble radionuclides such as iodine ({sup 129}I) and technetium ({sup 99}Tc) are particularly problematic, because both have long half-lives and can exist as gaseous or anionic species that are highly soluble and poorly sorbed by natural materials. Under the support of Sandia National Laboratories (SNL) Laboratory-Directed Research & Development (LDRD), we have developed a suite of inorganic nanocomposite materials (SNL-NCP) that can effectively entrap various radionuclides, especially for {sup 129}I and {sup 99}Tc. In particular, these materials have high sorption capabilities for iodine gas. After the sorption of radionuclides, these materials can be directly converted into nanostructured waste forms. This new generation of waste forms incorporates radionuclides as nano-scale inclusions in a host matrix and thus effectively relaxes the constraint of crystal structure on waste loadings. Therefore, the new waste forms have an unprecedented flexibility to accommodate a wide range of radionuclides with high waste loadings and low leaching rates. Specifically, we have developed a general route for synthesizing nanoporous metal oxides from inexpensive inorganic precursors. More than 300 materials have been synthesized and characterized with x-ray diffraction (XRD), BET surface area measurements, and transmission electron microscope (TEM). The sorption capabilities of the synthesized materials have been quantified by using stable isotopes I and Re as analogs to {sup 129}I and {sup 99}Tc. The results have confirmed our original finding that nanoporous Al oxide and its derivatives have high I sorption capabilities due to the combined effects of surface chemistry and nanopore confinement. We have developed a suite of techniques for the fixation of radionuclides in metal oxide nanopores. The key to this fixation is to chemically convert a target radionuclide into a less volatile or soluble form. We have developed a technique to convert a radionuclide-loaded nanoporous material into a durable glass-ceramic waste form through calcination. We have shown that mixing a radionuclide-loaded getter material with a Na-silicate solution can effectively seal the nanopores in the material, thus enhancing radionuclide retention during waste form formation. Our leaching tests have demonstrated the existence of an optimal vitrification temperature for the enhancement of waste form durability. Our work also indicates that silver may not be needed for I immobilization and encapsulation.


Chemical Geology | 2017

Synthesis and characterization of redox-active ferric nontronite

A.G. Ilgen; Ravi K. Kukkadapu; D.R. Dunphy; Kateryna Artyushkova; José M. Cerrato; Jessica Nicole Kruichak; M.T. Janish; C.J. Sun; J.M. Argo; R.E. Washington


Archive | 2015

Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials

Yifeng Wang; Andrew Miller; Charles R. Bryan; Jessica Nicole Kruichak


Volume 6A: Thermal-Hydraulics and Safety Analyses | 2018

Injectable Sacrificial Material System to Contain Ex-Vessel Molten Corium in Nuclear Accidents

David Louie; Yifeng Wang; Rekha Ranjana Rao; Alec Kucala; Jessica Nicole Kruichak


Archive | 2017

Shale-brine-CO2 interactions and the long-term stability of shale caprock.

Anastasia Gennadyevna Ilgen; Michael Aman; Joshua David Feldman; Jessica Nicole Kruichak; N. Espinoza; Thomas A. Dewers; Robert Charles Choens


Archive | 2016

Fundamental Study of Disposition and Release of Methane in a Shale Gas Reservoir

Yifeng Wang; Yongliang Xiong; Louise J. Criscenti; Tuan Ahn Ho; Philippe F. Weck; Anastasia G. Ilgen; Edward N. Matteo; Jessica Nicole Kruichak; Melissa Marie Mills; Thomas A. Dewers; Margaret E. Gordon; Yucel Akkutlu


Archive | 2016

Investigation of the Thermal Effects on the Settling Behavior of Clay Mineral Particles.

Jessica Nicole Kruichak; Melissa Marie Mills; Clay Payne; Amanda Christine Sanchez; Edward N. Matteo; Yifeng Wang

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Yifeng Wang

Sandia National Laboratories

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Melissa Marie Mills

Sandia National Laboratories

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Andrew Miller

Sandia National Laboratories

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Edward N. Matteo

Sandia National Laboratories

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Hernesto Tellez

Sandia National Laboratories

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Mark A. Rodriguez

Sandia National Laboratories

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Philippe F. Weck

Sandia National Laboratories

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Thomas A. Dewers

Sandia National Laboratories

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