Ji-Xiang Hu
Dalian University of Technology
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Publication
Featured researches published by Ji-Xiang Hu.
Chemistry: A European Journal | 2017
Ji-Xiang Hu; Yin-Shan Meng; Liang Zhao; Hai-Lang Zhu; Lei Liu; Qiang Liu; Cheng-Qi Jiao; Tao Liu
Tuning of the spin crossover (SCO) behavior through paramagnetic building blocks with different steric hindrance effects is of great interest in terms of the synergy between SCO and magnetic interactions. Herein, the steric effect of specified FeIII building blocks is modified, from the large Tp* (hydridotris(3,5-dimethylpyrazol-1-yl)borate) analogue to a small Tp (hydrotris(pyrazolyl)borate) derivative; the FeII SCO unit and FeIII paramagnetic ions are incorporated into three well isolated trinuclear complexes featuring thermally induced and light-induced SCO properties. Reanalysis of the structures reveals that π-π stacking interactions play a key role in the thermal hysteresis and anomalous octahedral distortion parameter Σ around the FeII ion. The Tp* ligand showing the largest steric hindrance induces elongated FeII -N bond lengths and bending of the C≡N-FeII angle in 1, as well as having a relatively large electron donor effect, which leads to the lowest thermal transition temperature among the three compounds.
Science China-chemistry | 2016
Wen-Jing Jiang; Yan-Juan Zhang; Cheng-Qi Jiao; Liang Zhao; Ji-Xiang Hu; Jun-Li Wang; Tao Liu
A cyanide-bridged FeIII2CoII double zigzag chain, {[FeIII(bipy)(CN)4]2CoII(btab)2}n [bipy=2,2′-bipyridine, btab=4,4′-(1,3-phenylene)-bis-4H-1,2,4-triazole] (1), was obtained with tetracyanometalate precursors and CoII ions. The chains were further linked by the ditopic btab ligands to a layer. Magnetic property studies demonstrate that 1 shows both metamagnetism with a critical field Hc=400 Oe and single-chain magnet behavior.
Dalton Transactions | 2013
Dapeng Dong; Yan-Juan Zhang; Hui Zheng; Peng-Fei Zhuang; Liang Zhao; Yang Xu; Ji-Xiang Hu; Tao Liu; Chunying Duan
Angewandte Chemie | 2017
Ji-Xiang Hu; Lun Luo; Xiao-Jin Lv; Lei Liu; Qiang Liu; Yi-Kai Yang; Chunying Duan; Yi Luo; Tao Liu
Inorganic Chemistry Communications | 2014
Ji-Xiang Hu; Yan-Juan Zhang; Yang Xu; Peng-Fei Zhuang; Hui Zheng; Liang Zhao; Cheng-Qi Jiao; Tao Liu
Inorganic Chemistry Communications | 2014
Peng-Fei Zhuang; Tao Liu; Hui Zheng; Ji-Xiang Hu; Xian-Hui Xie; Ling-Xiang Ren; Wen-Qiang Li; Cheng He; Chunying Duan
Inorganic Chemistry Communications | 2014
Peng-Fei Zhuang; Lun Luo; Tao Liu; Yi Luo; Xian-Hui Xie; Hui Zheng; Liang Zhao; Cheng-Qi Jiao; Jun-Li Wang; Ji-Xiang Hu; Cheng He; Chunying Duan
National Science Review | 2018
Cheng-Qi Jiao; Wen-Jing Jiang; Yin-Shan Meng; Wen Wen; Liang Zhao; Jun-Li Wang; Ji-Xiang Hu; Gagik G. Gurzadyan; Chun-Ying Duan; Tao Liu
Inorganic Chemistry Communications | 2016
Liang Zhao; Yan-Juan Zhang; Ji-Xiang Hu; Cheng-Qi Jiao; Jun-Li Wang; Chunying Duan; Tao Liu
Inorganic Chemistry Communications | 2015
Liang Zhao; Tao Liu; Peng-Fei Zhuang; Hui Zheng; Cheng-Qi Jiao; Ji-Xiang Hu; Jun-Li Wang; Ling-Xiang Ren; Cheng He; Chunying Duan